Original title: Oxidation Mechanisms of Diflunisal on Glassy Carbon Electrode
Authors: Tiribilli, Ch. ; Giannarelli, S. ; Sokolová, Romana ; Valášek, M.
Document type: Papers
Conference/Event: Moderní Elektrochemické Metody /34./, Jetřichovice (CZ), 2014-05-19 / 2014-05-23
Year: 2014
Language: eng
Abstract: The electrochemical oxidation of diflunisal in acetonitrile was studied on a glassy carbon electrode. Diflunisal yields one irreversible oxidation wave at 1.6 V (vs. Ag/AgCl/1M LiCl electrode). The oxidation mechanism depends on the basicity of the solvent. The study is based on cyclic voltammetry, electroanalytical methods and UV-Vis spectroelectrochemistry. The degradation products were determined by separation techniques (HPLC-DAD, GC-MS).
Keywords: Cyclic Voltammetry; diflunisal; Oxidation Mechanism
Project no.: M200401201
Funding provider: Rada Programu interní podpory projektů mezinárodní spolupráce AV ČR
Host item entry: Sborník přednášek mezinárodní odborné konference XXXIV. Moderní Elektrochemické Metody, ISBN 978-80-905221-2-1

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0234054

Permalink: http://www.nusl.cz/ntk/nusl-173881


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Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers