Original title: Electrochemical Properties of Mixed Self-Assembled Monolayers Based on Terpyridine Transition Metal Complexes
Authors: Kocábová, Jana ; Nováková Lachmanová, Štěpánka ; Vavrek, František ; Valášek, M. ; Hromadová, Magdaléna
Document type: Papers
Conference/Event: Moderní elektrochemické metody /42./, Jetřichovice (CZ), 20230522
Year: 2023
Language: eng
Abstract: This work presents the electrochemical characterization of mixed self-assembled monolayers\n(SAMs) of [Os(terpy)2]2+ and terpyridine connected by tripodal anchoring groups to the\npolycrystalline gold bead electrode and provides a comparison with SAM based on\n[Os(terpy)2]2+ tripodal molecules without diluting terpyridine tripodal molecules. It is shown\nthat both arrangements enable reproducible preparation of well-defined compact films. The\nelectron transfer rate constant for mixed SAM was determined from cyclic voltammograms\naccording to Laviron’s analysis and compared with the rate constant obtained previously for\nSAM containing only [Os(terpy)2]2+ tripod.
Keywords: terpyridine; transition metal complexes; tripodal anchor
Project no.: GA21-13458S (CEP)
Funding provider: GA ČR
Host item entry: Moderní elektrochemické metody /42./. Sborník přednášek, ISBN 978-80-908947-0-9

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available on demand via the digital repository of the Academy of Sciences.
Original record: https://hdl.handle.net/11104/0343391

Permalink: http://www.nusl.cz/ntk/nusl-526225


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Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers