Original title: Electrochemical Impedence Spectroscopy and Steady-State Voltammetry at the Micro- between Two Immiscible Electrolyte Solution
Authors: Silver, Barry Richard ; Holub, Karel ; Mareček, Vladimír
Document type: Papers
Conference/Event: Moderní elektrochemické metody /36./, Jetřichovice (CZ), 20160523
Year: 2016
Language: eng
Abstract: The kinetic data of simple tetraethylammonium ion transfer across the water/1,2-DCE interface obtained by electrochemical impedance spectroscopy and steady-state voltammetry are compared. It is shown that the geometry of the microcapillary tip region is of critical importance to obtain reliable kinetic data. Quasi-reversible behavior of the ion transfer reaction, corresponding to an apparent standard rate constant of about 0.2 cm s-1, is observed with both experimental methods.\n
Keywords: AC impedance; ion transport; liquid-liquid interface
Project no.: GA13-04630S (CEP)
Funding provider: GA ČR
Host item entry: XXXVI. Moderní elektrochemické metody. Sborník přednášek, ISBN 978-80-905221-4-5

Institution: J. Heyrovsky Institute of Physical Chemistry AS ČR (web)
Document availability information: Fulltext is available at the institute of the Academy of Sciences.
Original record: http://hdl.handle.net/11104/0259910

Permalink: http://www.nusl.cz/ntk/nusl-251394


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Research > Institutes ASCR > J. Heyrovsky Institute of Physical Chemistry
Conference materials > Papers
 Record created 2016-06-14, last modified 2022-09-29


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