|
|
Study of Thermal Properties of Materials
Štefková, Pavla ; Pavlík, Zbyšek (referee) ; Matiašovský, Peter (referee) ; Zmeškal, Oldřich (advisor)
The doctoral thesis deals with study of thermal properties of materials. Behavior of homogeneous matters at different temperatures is well described in theory and experimentally verified. Overall effect of all components of mixture and other influences related with material creation affect behaviour and properties of heterogeneous matters. For study of thermal properties can be used transient method of measurement which provide a picture about overall influence of all components of mixture on studied heterogeneous material and among others enable determination of thermophysical properties of whole macroscopic system in observed temperature range. Properties of solid matters, thin foil and liquids can be measured by means of pulse and step-wise transient method which is used for experimental activity in the thesis. It is contact measurement method and its principle is based on small quantity of heat generating inside the specimen and temperature response measuring. Theoretical part of thesis is focused on creation of method for determination of thermophysical parameters. The base is differential equation of the heat conduction. Its solution is temperature function. Three methods of evaluation are described mathematically. They start from general relations designed for study of fractal structure physical properties (maximum of function method, differential method and multi-parametric non-linear regression method).
|
|
|
Study of Electric and Dielectric Properties of Alkali-Activated Aluminosilicate with Increased Electrical Conductivity
Florián, Pavel ; Pavlík, Zbyšek (referee) ; Matiašovský, Peter (referee) ; Zmeškal, Oldřich (advisor)
This dissertation deals with the study of electric and dielectric properties of composite structures on the base of alkali-activated aluminosilicates with admixtures of various carbon particles. These materials fabricated from alkali-activated blast furnace slag, quarz sand, natrium water glass as alkali activator, water, dispersant and small amount of carbon admixture (carbon black, graphite powder, carbon fibers or carbon nanotubes) to increase electric conductivity may be used for example to construction of snow-melting, deicing and self-monitoring systems. Their current-voltage characteristics and impedance spectra were used for determination of electric and dielectric properties of these structures. The equivalent circuits were used for evaluation of impedance spectra. The results were correlated with thermal properties of these structures.
|
|
|
Thermal properties of high performance fibre reinforced concrete
Pecháčková, Kateřina ; Krouská, Jitka (referee) ; Zmeškal, Oldřich (advisor)
This diploma thesis is focused on the study of the thermal properties of high-performance fiber reinforced concrete HPFRC. The composites are based on a combination of steel and polymeric fibers. Typical properties of these materials include high mechanical strength, water resistence and salt penetration. HPFRCs are mainly used in the construction industry to build tall buildings. The differential transient method was used to study thermophysical variables. The theoretical part of the thesis described the types of concrete, their production, and their properties. Furthermore, thermophysical quantities and methods of their determination (stationary and transient methods, thermal analysis) are defined in the thesis. The aim of the thesis was to determine thermal properties, namely thermal conductivity and specific heat capacity. The results of the thesis can reveal changes in the composition of studied materials as well as critical temperatures for damaging the materials.
|
|
|
Study of thermal properties of sucrose
Pecháčková, Kateřina ; Lucie, Trhlíková (referee) ; Zmeškal, Oldřich (advisor)
This work is focused on the study of thermal properties of materials that are used for accumulating heat on the basis of phase transition. These are mainly sugar alcohols (mannitol, erythritol) or carbohydrates (glucose) respectively. Thermal properties, thermal in particular, and thermal conductivity and specific heat capacity were measured in a wide range of temperatures comprising of the transformation from the solid to the liquid phase in the entire volume of substance. To study the temperature dependence of thermal properties, transient methods were used, that allow to determine the diffusion and relaxation time, thermal absorption coefficient and a parameter characterizing the properties of resources based on the fractal model of heat transfer (shape and the heating of the sample). Thermal parameters were determined from those values for defined ideal heat source (planar) and defined ideal heating (leap). There are results of three sucrose samples produced in the Opava refinery (unrefined, refined, clean). Differences in their thermal properties were studied. In addition, thermal properties of a pure solution (commercial) of sugar in distilled water at different concentrations were studied (1:1, 3:1, 1:3). The results presented in this thesis may be used to more efficient use of thermal energy in heating of dwellings, both with the use of solutions, which have a higher heat capacity than water and also with the use of phase transformation.
|
|
|
Study of energy accumulation during phase change of paraffin wax
Lapčíková, Tereza ; Krouská, Jitka (referee) ; Zmeškal, Oldřich (advisor)
This thesis deals with the study of the process of energy storage during phase transformation, the so-called latent heat for commercial materials of the Rubitherm® RT line (Rubitherm Technologies GmbH) with applications in the construction industry. The thermophysical properties of Rubitherm® RT35HC, RT28HC and RT18HC materials differing in phase transformation temperature were investigated using the transient method. For the Rubitherm® RT35HC material a value of the thermal conductivity coefficient in the solid phase of 0.21 W/m/K and in the liquid phase of 0.23 W/m/K was determined. The specific heat capacity value in the solid phase was determined to be 1980 J/kg/K and in the liquid phase 1995 J/kg/K. For Rubitherm® RT28HC, the value of the thermal conductivity coefficient in the solid phase was determined to be 0,23 W/m/K and the value of the specific heat capacity in the solid phase was determined to be 1997 J/kg/K. For the Rubitherm® RT18HC material, a liquid phase thermal conductivity coefficient of 0,27 W/m/K and a liquid phase specific heat capacity of 2010 J/kg/K were determined. Using differential scanning calorimetry (DSC), the melting temperature of the Rubitherm® RT28HC sample was determined at 27.43 °C and solidification at 23.51 °C, while for the Rubitherm® RT35HC sample melting occurred at 36.51 °C and solidification at 31.86 °C and 32.28 °C. In the experimental part of this work, modifications were made to the measuring apparatus used in such a way that it could be used for the study of materials that change their state of matter during the experiment.
|
|
|
Study of Electric and Dielectric Properties of Alkali-Activated Aluminosilicate with Increased Electrical Conductivity
Florián, Pavel ; Pavlík, Zbyšek (referee) ; Matiašovský, Peter (referee) ; Zmeškal, Oldřich (advisor)
This dissertation deals with the study of electric and dielectric properties of composite structures on the base of alkali-activated aluminosilicates with admixtures of various carbon particles. These materials fabricated from alkali-activated blast furnace slag, quarz sand, natrium water glass as alkali activator, water, dispersant and small amount of carbon admixture (carbon black, graphite powder, carbon fibers or carbon nanotubes) to increase electric conductivity may be used for example to construction of snow-melting, deicing and self-monitoring systems. Their current-voltage characteristics and impedance spectra were used for determination of electric and dielectric properties of these structures. The equivalent circuits were used for evaluation of impedance spectra. The results were correlated with thermal properties of these structures.
|
|
|
Thermal properties of high performance fibre reinforced concrete
Pecháčková, Kateřina ; Krouská, Jitka (referee) ; Zmeškal, Oldřich (advisor)
This diploma thesis is focused on the study of the thermal properties of high-performance fiber reinforced concrete HPFRC. The composites are based on a combination of steel and polymeric fibers. Typical properties of these materials include high mechanical strength, water resistence and salt penetration. HPFRCs are mainly used in the construction industry to build tall buildings. The differential transient method was used to study thermophysical variables. The theoretical part of the thesis described the types of concrete, their production, and their properties. Furthermore, thermophysical quantities and methods of their determination (stationary and transient methods, thermal analysis) are defined in the thesis. The aim of the thesis was to determine thermal properties, namely thermal conductivity and specific heat capacity. The results of the thesis can reveal changes in the composition of studied materials as well as critical temperatures for damaging the materials.
|
|
|
Study of thermal properties of sucrose
Pecháčková, Kateřina ; Lucie, Trhlíková (referee) ; Zmeškal, Oldřich (advisor)
This work is focused on the study of thermal properties of materials that are used for accumulating heat on the basis of phase transition. These are mainly sugar alcohols (mannitol, erythritol) or carbohydrates (glucose) respectively. Thermal properties, thermal in particular, and thermal conductivity and specific heat capacity were measured in a wide range of temperatures comprising of the transformation from the solid to the liquid phase in the entire volume of substance. To study the temperature dependence of thermal properties, transient methods were used, that allow to determine the diffusion and relaxation time, thermal absorption coefficient and a parameter characterizing the properties of resources based on the fractal model of heat transfer (shape and the heating of the sample). Thermal parameters were determined from those values for defined ideal heat source (planar) and defined ideal heating (leap). There are results of three sucrose samples produced in the Opava refinery (unrefined, refined, clean). Differences in their thermal properties were studied. In addition, thermal properties of a pure solution (commercial) of sugar in distilled water at different concentrations were studied (1:1, 3:1, 1:3). The results presented in this thesis may be used to more efficient use of thermal energy in heating of dwellings, both with the use of solutions, which have a higher heat capacity than water and also with the use of phase transformation.
|
|
|
Study of Thermal Properties of Materials
Štefková, Pavla ; Pavlík, Zbyšek (referee) ; Matiašovský, Peter (referee) ; Zmeškal, Oldřich (advisor)
The doctoral thesis deals with study of thermal properties of materials. Behavior of homogeneous matters at different temperatures is well described in theory and experimentally verified. Overall effect of all components of mixture and other influences related with material creation affect behaviour and properties of heterogeneous matters. For study of thermal properties can be used transient method of measurement which provide a picture about overall influence of all components of mixture on studied heterogeneous material and among others enable determination of thermophysical properties of whole macroscopic system in observed temperature range. Properties of solid matters, thin foil and liquids can be measured by means of pulse and step-wise transient method which is used for experimental activity in the thesis. It is contact measurement method and its principle is based on small quantity of heat generating inside the specimen and temperature response measuring. Theoretical part of thesis is focused on creation of method for determination of thermophysical parameters. The base is differential equation of the heat conduction. Its solution is temperature function. Three methods of evaluation are described mathematically. They start from general relations designed for study of fractal structure physical properties (maximum of function method, differential method and multi-parametric non-linear regression method).
|
guest ::
