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Study of the Ta2O5 insulating layer degradation
Velísek, Martin ; Majzner, Jiří (referee) ; Sedláková, Vlasta (advisor)
The aim of the thesis is to examine the dielectric function Ta2O5 insulating layers in tantalum capacitors. The capacitor plugged in the regular mode represents a MIS structure of reverse direction. Three different factors can be determined for the residual current of the component according to its charge transmission mode: the ohmic, Pool–Frenkel, tunnel and Schottky. An apparatus was constructed by the author of the thesis to measure the temporary connection between residual current and rise of temperature of the tantalum capacitors. Annealing of three different sets of tantalum capacitors made by different producers was performed at the temperature of 400 K and nominal voltage of 35 V during the period of 20 days.The experiment has proved the residual current in the electric field changes with rising temperature in time as a result of the ion movement. The singular factors of the residual current are influenced during the process. By the “ion movement” is meant the ion drift influenced by the attached electric field and diffusion caused by the concentration gradient. First, the samples were being annealed for c. 2 x 106 s, and then the residual current was being regenerated under the voltage of 5 V for 106 s. The residual current values increased considerably after annealing, and decreased again to more or less the original level after the regeneration, some of the samples reaching even values bellow the original level. The VA characteristics of the samples measured before and after the process of controlled obsolescence, and after the regeneration prove not only a change in parameters of the different current factors, but also a change of the current transmission mechanism employed in the process.
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Transport of Electric Charge in Tantalum Capacitor
Pelčák, Jaromír ; Koktavý, Bohumil (referee) ; Hájek, Karel (referee) ; Grmela, Lubomír (advisor)
The task of the thesis was studding of tantalum capacitors with solid electrolytes properties. Ta – Ta2O5 – MnO2 capacitor by its construction represents MIS structure, where tantalum anode has metal conductivity and MnO2 cathode is semiconductor. Isolation layer consists of tantalum pentoxide Ta2O5 with relative permitivity r = 27. Dielectric thickness is typically in range from 30 to 150nm. The capacitor charge is not only stored and accumulated on electrodes but also in localised states (oxide vacancies) in isolation layer. The capacitor connected in normal mode represents MIS structure polarized in reveres direction when the applied voltage higher potential barrier between semiconductor - MnO2 cathode and isolation of Ta2O5. The transport of charge carriers via isolation layer is determined by Poole-Frenkel mechanisms and tunnelling. Poole-Frenkel mechanism of charge transport is dominant in low intensity of electric field. Tunnelling determines current at higher electric field intensity. During low intensity of electric field ohmic component is also presented which is determined by volume of resistance of impurities in isolation layer due to donor states of oxygen vacancies. Based on the modelling of measured VA characteristics is possible to estimate determine dielectric thickness of Ta2O5 and determine share of Poole-Frenkelov and tunnel current and charge transportation. The thesis is described charge transport and charge concentration on tantalum capacitor in low frequency area and analysis of capacitor behaviour at frequency band. The first impulse for the thesis was an effort to create equivalent circuit diagram of tantalum capacitor in respect of its physical and electrical behaviour. There is an opportunity to study and determine electric charge transport and its accumulation based on the equivalent circuit diagram structure. There is also a chance to define and trace potential barriers and charge distribution in the capacitor structure based on an measurement and carried out experiments. This methodology and analysis consists of electrical characteristic determination to create physical model of the capacitor describing it function, properties and behaviour.
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Transport of Electric Charge in Tantalum Capacitor
Pelčák, Jaromír ; Koktavý, Bohumil (referee) ; Hájek, Karel (referee) ; Grmela, Lubomír (advisor)
The task of the thesis was studding of tantalum capacitors with solid electrolytes properties. Ta – Ta2O5 – MnO2 capacitor by its construction represents MIS structure, where tantalum anode has metal conductivity and MnO2 cathode is semiconductor. Isolation layer consists of tantalum pentoxide Ta2O5 with relative permitivity r = 27. Dielectric thickness is typically in range from 30 to 150nm. The capacitor charge is not only stored and accumulated on electrodes but also in localised states (oxide vacancies) in isolation layer. The capacitor connected in normal mode represents MIS structure polarized in reveres direction when the applied voltage higher potential barrier between semiconductor - MnO2 cathode and isolation of Ta2O5. The transport of charge carriers via isolation layer is determined by Poole-Frenkel mechanisms and tunnelling. Poole-Frenkel mechanism of charge transport is dominant in low intensity of electric field. Tunnelling determines current at higher electric field intensity. During low intensity of electric field ohmic component is also presented which is determined by volume of resistance of impurities in isolation layer due to donor states of oxygen vacancies. Based on the modelling of measured VA characteristics is possible to estimate determine dielectric thickness of Ta2O5 and determine share of Poole-Frenkelov and tunnel current and charge transportation. The thesis is described charge transport and charge concentration on tantalum capacitor in low frequency area and analysis of capacitor behaviour at frequency band. The first impulse for the thesis was an effort to create equivalent circuit diagram of tantalum capacitor in respect of its physical and electrical behaviour. There is an opportunity to study and determine electric charge transport and its accumulation based on the equivalent circuit diagram structure. There is also a chance to define and trace potential barriers and charge distribution in the capacitor structure based on an measurement and carried out experiments. This methodology and analysis consists of electrical characteristic determination to create physical model of the capacitor describing it function, properties and behaviour.
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Study of the Ta2O5 insulating layer degradation
Velísek, Martin ; Majzner, Jiří (referee) ; Sedláková, Vlasta (advisor)
The aim of the thesis is to examine the dielectric function Ta2O5 insulating layers in tantalum capacitors. The capacitor plugged in the regular mode represents a MIS structure of reverse direction. Three different factors can be determined for the residual current of the component according to its charge transmission mode: the ohmic, Pool–Frenkel, tunnel and Schottky. An apparatus was constructed by the author of the thesis to measure the temporary connection between residual current and rise of temperature of the tantalum capacitors. Annealing of three different sets of tantalum capacitors made by different producers was performed at the temperature of 400 K and nominal voltage of 35 V during the period of 20 days.The experiment has proved the residual current in the electric field changes with rising temperature in time as a result of the ion movement. The singular factors of the residual current are influenced during the process. By the “ion movement” is meant the ion drift influenced by the attached electric field and diffusion caused by the concentration gradient. First, the samples were being annealed for c. 2 x 106 s, and then the residual current was being regenerated under the voltage of 5 V for 106 s. The residual current values increased considerably after annealing, and decreased again to more or less the original level after the regeneration, some of the samples reaching even values bellow the original level. The VA characteristics of the samples measured before and after the process of controlled obsolescence, and after the regeneration prove not only a change in parameters of the different current factors, but also a change of the current transmission mechanism employed in the process.
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