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Comparision of methods for sulphide determination
Zlámalová, Magda ; Nesměrák, Karel (advisor) ; Červený, Václav (referee)
The aim of this work is determination of sulphides in a solution by suitable methods and it's subsequent comparison from a point of view to the precision, financial and time demands. Iodometric titration, argentometric titration, and potassium ferricyanide titration were chosen for the determination of sulphides in the solution. Anhydrous sodium sulphide and sodium sulphide hydrate were used as model samples. From the point of view to financial and time demands the most advantageous method was potassium ferricyanide titration and the least advantageous method was iodometric titration. The precision of used methods was dependent on type of used sample. Iodometry was the least precise determination of sulphides in the sample of anhydrous sodium sulphide; the precision of argentometry and potassium ferricyanide titration was comparable. Potassium ferricyanide titration was the most precise determination of sulphides in the sample of sodium sulfide hydrate; the least precise determination was argentometry.
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In situ weathering experiments of sulphides and silicates
Jarošíková, Alice ; Mihaljevič, Martin (advisor) ; Drahota, Petr (referee)
Weathering is a natural process which is occuring on the Earth's surface. Its effect on minerals and other materials is significant. Besides mechanical alteration, the result of weathering can reach the chemical reactions, which can lead to contamination of the environment (e.g. ground water and soils). Not only for this reason has weathering become an object of intensive studies. In situ weathering experiments are one way of research. The aim of this bachelor thesis is to review the advantages and disadvantages of these experiments, to describe their course and the complications which can happen during the experiments, and how to use knowledge of these observations. Attention is also focused on several concrete experiments which were concerned with the weathering of sulphides and silicates, and where it is possible to observe these things on them.
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Comparision of methods for sulphide determination
Zlámalová, Magda ; Červený, Václav (referee) ; Nesměrák, Karel (advisor)
The aim of this work is determination of sulphides in a solution by suitable methods and it's subsequent comparison from a point of view to the precision, financial and time demands. Iodometric titration, argentometric titration, and potassium ferricyanide titration were chosen for the determination of sulphides in the solution. Anhydrous sodium sulphide and sodium sulphide hydrate were used as model samples. From the point of view to financial and time demands the most advantageous method was potassium ferricyanide titration and the least advantageous method was iodometric titration. The precision of used methods was dependent on type of used sample. Iodometry was the least precise determination of sulphides in the sample of anhydrous sodium sulphide; the precision of argentometry and potassium ferricyanide titration was comparable. Potassium ferricyanide titration was the most precise determination of sulphides in the sample of sodium sulfide hydrate; the least precise determination was argentometry.
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