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Possibilities of using tailings from the ore mining for the production of blended cements.
Šrámek, Ondřej ; Gazdič, Dominik (referee) ; Dvořák, Karel (advisor)
The bachelor's thesis deals with the possibility of partial replacement of Portland clinker in blended cements. It is focused on the study of the slate’s usability, especially their calcination ability and the analysis of the activatability of pozzolanic properties by a suitable temperature. A search of the available literature was performed in this work. Also suitable type of sedimentary slate was selected, on which a basic experiments was performed. The experiments showed that slate has enough minerals with the potential of pozzolanic properties and this was proved at a calcination temperature above 600 °C.
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Verification of ECPC and EPCC concepts for the use of the k-value of selected active admixtures with mixed cement
Prudil, Matěj ; Slánský,, Bohuslav (referee) ; Hela, Rudolf (advisor)
This bachelor thesis deals with the verification of the replacement of blended cement, latent hydraulic and pozzolanic additions used in the production of concrete. In the theoretical part of this thesis, the use of blended cements in concrete production is firstly described and the effect of additions on the properties of fresh and hardened concrete is briefly discussed. The next chapters focus on fly ash and blast furnace slag as Type II additions and their basic properties. The theoretical part also focuses exclusively on the concepts used to replace cement with active additions. These concepts are successively presented in this thesis as: K-value concept, Equivalent concrete performance concept (ECPC) and Equivalent performance of combinations concept (EPCC). In the experimental part, the properties of the test mortars with cement replacement by concrete active additions (slag from Kotouč Štramberk and high temperature fly ash from Opatovice and Chvaletice) are compared. The above mentioned concepts for the replacement of cement with active additions are evaluated in the experimental part from the economic point of view (prices per m3 of concrete) and ecological point of view (calculation of carbon footprint in t CO2 per m3 of concrete production). In order to compare these benefits, a concrete mix of strength class C30/37 is proposed according to each concept. From the knowledge gained in the development of the ECPC and EPCC concepts, a q-value concept is proposed in the experimental part. In the last chapter of the experimental part, the resulting values of this work are compared with the experimental work already carried out to replace Portland cement with identical active admixtures.
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High Temperature Processes in Silicon Solar Cells Production
Frantík, Ondřej ; Hudec, Lubomír (referee) ; Banský,, Juraj (referee) ; Szendiuch, Ivan (advisor)
The thesis is focused on high temperature processes in crystalline solar cells production. Main topic is diffusion of traditional dopants phosphorus and boron. Diffusion processes for creating solar cells are different from classical diffusion in semiconductor industrial. It is reason why the thesis describes crated layers in detail. Knowledge of diffusion processes is used for creating bifacial solar cells and development of a new phosphorus emitter for conventional solar cells. Bifacial cells are a new type of cells. Developed new emitter increases efficiency and decreases cost of solar cells production. Another part the thesis is devoted to the prediction of diffusion processes. New models of phosphorus and boron diffusion for photovoltaic industrial are created in software SILVACO. Models correspond with real results.
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Influence of temperature on lead acid batteries lifetime
Kopečný, Martin ; Bača, Petr (referee) ; Neoral, Jiří (advisor)
Lead –acid batteries are the most common type of secondary cells used in automotive industry. This diploma thesis deals with the influence of temperature on their lifetime. In the preamble of this work is shortly described their history, division, construction and processes during battery operation. There are noted unfavorable phenomena which have an impact on increasing the temperature inside the battery. The first experimental part is devoted to evaluation the effects of addition on the temperature rise during charging. The second part is focused on conditions simulation in hot areas at the temperature above 30 °C and effects of this temperature on the function of lead – acid batteries.
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The development of high-strength concrete with a high content of el. fly ash
Roubal, David ; Ťažký, Tomáš (referee) ; Hela, Rudolf (advisor)
This diploma thesis deals with the study of high-strength, high-volume fly ash concrete. The theoretical part of this thesis focuses on the detailed characteristic and main principles of high-strength concrete, high-volume fly ash concrete. In addition, according to the findings, the technology of high-strength and high-volume fly ash concrete, including principles of high strength, has been described. On the basis of the findings, high-strength, high-volume fly ash concrete for specific compressive strengths has been designed and created in the experimental section. These concretes were then subjected to a number of tests.
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Monitoring the influence of concrete composition on abrasion resistance
Černá, Hana ; Novosad, Petr (referee) ; Bodnárová, Lenka (advisor)
This diploma thesis focuses on the resistance of concrete to abrasion with regard to the raw materials used for their production. In the theoretical part of the thesis are described admixtures, different types of aggregate and aggregate composition which influence the resistance of concrete to abrasion. In the experimental part, 15 different C30 / 37, S4 concrete formulations were proposed. Different types of aggregates - fecal gravel (Žabčice), biotic granodiorite (Olbramovice) and amphibolite (Želešice) have always been used in the recipes. Fine ground limestone, micro-silica, high-temperature fly ash and finely ground slag were ingredients that were added to the proposed recipes. Consistency was determined by the method of cone seating and the density of fresh concrete. In the hardened state, concrete density, compressive strength, bending tensile strength, tensile strength, watertightness, concrete absorption, and abrasion resistance were determined using the Böhm method and wide wheel method. The test specimens were tested after 7, 28, and 90 days of maturation.
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Pozzolanic Activity of Silicon Dioxide
Barek, Jaroslav ; Žižková, Nikol (referee) ; Rovnaníková, Pavla (advisor)
The aim of this bachelor's thesis is to investigate and identify the present status of resources with dominant amorphous silicon dioxide content and summarize feasible test methods to assess pozzolanic activity. The use of pozzolan as a partial replacement of Portland cement reduces the carbon dioxide emitted per tonne of product and can also improve various physical properties of the resulting cementitious composites. Assessment of the pozzolanic activity of cement replacement materials is increasingly important because of the economic sustainability of cementing materials. The pozzolanic activity of wheat straw ash, silica fume, nanosilica, two diatomites, glass powder and expanded perlite have been investigated and compared using the strength activity index test, the modified Chapelle test and the pozzolanicity test in accordance with the European Standard EN 196-5. From an experimental investigation of seven different pozzolans, the following main conclusions can be drawn. In the case of an acid-base titration (determination of [OH–], the procedure specified in EN 196-5) is better to use Tashiro (mixed indicator) instead of required methyl orange, Tashiro changes color at the endpoint of a titration distinctly. Strength activity index: the procedure used was based on EN 450-1. In its current form, this procedure is misleading because of two other significant properties of the pozzolan, namely its density and its water-reducing/increasing capabilities. Based on the results of our experimental investigation, the current testing procedure is evaluated against an alternative in which the 25% pozzolan replacement for cement is performed on a volumetric basis and the volume fraction of water is held constant.
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Investigation and Modelling of Concrete Carbonation
Rovnaníková, Markéta ; Keršner, Zbyněk (referee) ; Bajza, Adolf (referee) ; Havlica, Jaromír (advisor)
The corrosion of steel reinforcement is probably the most frequent type of degradation of reinforced concrete structures. Reinforcing bars are protected from corrosion by a thin iron oxide layer which is formed on their surface due to a high alkalinity of the surrounding concrete. Corrosion may start when this layer is destroyed (i) either by chloride ion penetration (when the concentration of dissolved chloride at the depth of the reinforcing steel exceeds a critical value) or (ii) by a reduction in the pH value of pore solution to values below 9.5. Such a reduction in alkalinity is the result of carbonation of the Ca(OH)2 in the concrete mass, i.e. of its reaction with the atmospheric CO2. The main aim of this work is an experimental investigation and modelling of carbonation process. The effect of relative humidity, curing period and replacement of Portland cement by supplementary cementing materials (SCM - fly ash, blast furnace slag and metakaolin) on carbonation process has been studied. Calcium hydroxide content in the presence of SCM and their pozzolanic activities have been also determined. Furthermore, lots of parametric studies and comparison of carbonation models have been provided. The software tools based on the introduced models and considering the input data to be statistically independent random variables have been described and used for other parametric studies.
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Infusorial Earth - Reactive Admixture for Cement Composites
Zimmermann, Štěpán ; Žižková, Nikol (referee) ; Rovnaníková, Pavla (advisor)
The aims of this bachelor´s thesis are the properties and the use of diatomaceous earth as a partial replacement of cement in concrete. It provides information about the origin of diatomaceous earth, sedimentation of dead diatoms and variety of algae, including chemical and physical properties of the diatoms according to origin. The paper also contains information about significant deposits of diatoms, the manner and intensity of mining, including treatment of raw diatomaceous earth for further use. The main use of diatomaceous earth is in the filtration, which represents more than half of total consumption. An important factor for use in building is a high content of amorphous SiO2 and associated pozzolana activity of diatomaceous earth. The experimental part was carried out research on the influence of diatomaceous earth as pozzolanic admixtures on the properties of cement mortars. Tested specimens were obtained by adding 10% diatomaceous earth by weight of cement in the cement mortars. As admixtures were use three diatomaceous earth of different chemical composition, particle size and pozzolanic activity. The evaluated parameters were mortar density, flexural and compressive strength. The microsture of mortars were also observed. Test results were compared with those determined by reference mortars.
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Conductive ceramic as additive in the lead-acid accumulators
Šrut, Martin ; Křivík, Petr (referee) ; Bača, Petr (advisor)
Lead-acid batteries are most used secondary electrochemical power sources. Their basic principle has remained the same for several years; only the operating parameters are in development. Lead-acid batteries are used in hybrid electric vehicles (HEV), which operates in the partial charge PSoC. Sulphation is one of the possible failures lead-acid batteries in the HEV, especially the negative electrode. By adding additives to the negative active mass can reduce the rate of sulphation and increase ability to accept an electrical charge by negative electrode.
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