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Structure and properties of welded joint TiAl6V4 / 6061 made by electron beam technology
Král, Michael ; Jan, Vít (referee) ; Foret, Rudolf (advisor)
Titanium and aluminium alloys are among the most used construct materials due to their physical and mechanical properties except steels. The joining of these alloys can improve properties of whole construction but it is still difficult task. Especially welding of titanium and aluminium alloys is difficult cause formation of undesirable intermetalic phases in the weld. This thesis focuses on influences of electron beam welding parameters especially focusing and deflection of beam and preheating of base material to quality of heterogeneous join of titanium alloy Ti6Al4V and aluminium alloy EN AW-6061 – T651. There is described preparation of welded joins and brazed joins in the thesis, which are evaluated by light microscopy, scanning electron microscopy and EDS analysis of chemical composition. There was evaluated presence and chemical composition of formated intermetalic phases in the welded joins and quality and defects in the brazed joins.
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ELECTRON BEAM WELDING OF HETEROGENEOUS WELDS OF Ti/Al ALLOYS
Havlík, Petr ; Dřímal, Daniel (referee) ; Schwarz,, Drahomír (referee) ; Foret, Rudolf (advisor)
The problematics of weldability of heterogeneous welds of aluminium and titanium alloys produced by electron beam welding is discussed in this work. Homogenous welds of selected alloys were analyzed in the first stage. Welding of these materials relates to formation of intermetallic phases at the interface of base materials due to differences in physical, chemical and metallurgical properties of base materials. One of the prerequisites for producing high quality weld joints is to find optimal process parameters. The influence of selected process parameters to integrity, structure and mechanical properties of heterogeneous Al/Ti joints is evaluated.
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Heat and mechanical resistance of zinc coating
Horák, Karel ; Dzimko, Marián (referee) ; Černý, Michal (advisor)
The work is aimed at studying the thermal degradation of the protective zinc coating. Its large part deals with the structure of the various stages of transition and their arrangement, the main emphasis is on analysis of brittle intermetallic phases, which arise due to increased temperature. Conclusion of the work is trying to clear itself causes degradation of this protective layer.
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In-situ Synthesised Intermetallic Compounds in Powder Materials
Hanusová, Petra ; Novák, Pavel (referee) ; Skotnicová, Kateřina (referee) ; Dlouhý, Ivo (advisor)
The mechanical treatment of solids is one of the most common and widely used operations. The volume of solids subjected to chemical treatment is very large too. Therefore, combining these two ways into one seems to be a logical solution. This method is called the mechanochemical processing of materials. Processing materials in this way has many advantages. On the one hand, this processing is economically as well as technologically feasible. Even the materials that not react together in conventional way can be prepare in this way. The mechanochemistry/mechanochemical synthesis utilizes the mechanical energy to activate chemical reactions and structural changes. The aluminothermic reduction reactions induced by the high – energy ball milling are gaining importance because of the potential applications like the synthesis of microcrystalline and nanocrystalline in – situ metal matrix composites. The mechanical activation of the chemical reactions by high energy ball milling often changes the reaction mechanism and produces metastable materials. Changes of reaction mechanisms during mechanical alloying on four different systems were studied. The system was based on this composition: Al - B2O3 - X (X = C, Ti, Nb, Cr). The possibility of another in – situ reactions during spark plasma sintering process (SPS) was also investigated. All systems were mechanically alloyed under the same conditions. After alloying, on each system scanning electron microscopy was performed and qualitative and quantitative analysis was performed using X-ray diffraction. The indentation hardness and the indentation modulus of elasticity were evaluated using nanoindentation. All analyzes were performed after mechanical alloying as well as SPS and the results were compared to each other. Based on the results, a change of reaction mechanisms was proposed for all systems. It has been found that metal matrix composites are formed and, when chromium is used, hybrid composite material reinforced with intermetallic phase and aluminum borate has been developed.
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Manufacturing, use and properties of duplex austenitic-ferritic steels
Klapetek, Václav ; Blažík, Petr (referee) ; Myška, Martin (advisor)
This bachelor thesis focuses on stainless duplex austenitic-feritic steels. The first chapter is focused on mechanical and technological properties, microstructure and chemical proposition with its impact on corrosion resistance, following the introduction to the issue. Intermetallic phases and their effect on properties are also described. Second chapter deals with their usage in several industry spheres, such as petrochemical industry, paper-producing, transport and storage of chemicals etc.
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Precipitation of Intermetallic Phases in Austenitic-Ferritic Duplex Steels
Myška, Martin ; Foret, Rudolf (referee) ; Čech, Jan (referee) ; Záděra, Antonín (advisor)
This PhD thesis addresses the issue of precipitation of intermetallic phases in cast duplex stainless steel according to the ASTM A890 Gr4A standard. The aim of the thesis was to determine the amount of precipitated intermetallic phases depending on the temperature and holding time during isothermal annealing and under anisothermal conditions during cooling of the material in the temperature range from 1000 to 600 °C. The partial aim of the work was to determine the relationship between the amount of precipitated intermetallic phases and the mechanical properties of cast steel ASTM A890 Gr4A. As part of the work, the description and prediction of the kinetics of precipitation of intermetallic phases using the Johnson-Mehl-Avrami equation were verified. The relationship between the amount of precipitated intermetallic phases and the failure character of the material was determined by fractographic evaluation. The critical cooling rate of the casting was determined to ensure the minimum toughness of the steel that is desirable to reduce the risk of cracking during cooling of duplex stainless steel castings.
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ELECTRON BEAM WELDING OF HETEROGENEOUS WELDS OF Ti/Al ALLOYS
Havlík, Petr ; Dřímal, Daniel (referee) ; Schwarz,, Drahomír (referee) ; Foret, Rudolf (advisor)
The problematics of weldability of heterogeneous welds of aluminium and titanium alloys produced by electron beam welding is discussed in this work. Homogenous welds of selected alloys were analyzed in the first stage. Welding of these materials relates to formation of intermetallic phases at the interface of base materials due to differences in physical, chemical and metallurgical properties of base materials. One of the prerequisites for producing high quality weld joints is to find optimal process parameters. The influence of selected process parameters to integrity, structure and mechanical properties of heterogeneous Al/Ti joints is evaluated.
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Manufacturing, use and properties of duplex austenitic-ferritic steels
Klapetek, Václav ; Blažík, Petr (referee) ; Myška, Martin (advisor)
This bachelor thesis focuses on stainless duplex austenitic-feritic steels. The first chapter is focused on mechanical and technological properties, microstructure and chemical proposition with its impact on corrosion resistance, following the introduction to the issue. Intermetallic phases and their effect on properties are also described. Second chapter deals with their usage in several industry spheres, such as petrochemical industry, paper-producing, transport and storage of chemicals etc.
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In-situ Synthesised Intermetallic Compounds in Powder Materials
Hanusová, Petra ; Novák, Pavel (referee) ; Skotnicová, Kateřina (referee) ; Dlouhý, Ivo (advisor)
The mechanical treatment of solids is one of the most common and widely used operations. The volume of solids subjected to chemical treatment is very large too. Therefore, combining these two ways into one seems to be a logical solution. This method is called the mechanochemical processing of materials. Processing materials in this way has many advantages. On the one hand, this processing is economically as well as technologically feasible. Even the materials that not react together in conventional way can be prepare in this way. The mechanochemistry/mechanochemical synthesis utilizes the mechanical energy to activate chemical reactions and structural changes. The aluminothermic reduction reactions induced by the high – energy ball milling are gaining importance because of the potential applications like the synthesis of microcrystalline and nanocrystalline in – situ metal matrix composites. The mechanical activation of the chemical reactions by high energy ball milling often changes the reaction mechanism and produces metastable materials. Changes of reaction mechanisms during mechanical alloying on four different systems were studied. The system was based on this composition: Al - B2O3 - X (X = C, Ti, Nb, Cr). The possibility of another in – situ reactions during spark plasma sintering process (SPS) was also investigated. All systems were mechanically alloyed under the same conditions. After alloying, on each system scanning electron microscopy was performed and qualitative and quantitative analysis was performed using X-ray diffraction. The indentation hardness and the indentation modulus of elasticity were evaluated using nanoindentation. All analyzes were performed after mechanical alloying as well as SPS and the results were compared to each other. Based on the results, a change of reaction mechanisms was proposed for all systems. It has been found that metal matrix composites are formed and, when chromium is used, hybrid composite material reinforced with intermetallic phase and aluminum borate has been developed.
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Structure and properties of welded joint TiAl6V4 / 6061 made by electron beam technology
Král, Michael ; Jan, Vít (referee) ; Foret, Rudolf (advisor)
Titanium and aluminium alloys are among the most used construct materials due to their physical and mechanical properties except steels. The joining of these alloys can improve properties of whole construction but it is still difficult task. Especially welding of titanium and aluminium alloys is difficult cause formation of undesirable intermetalic phases in the weld. This thesis focuses on influences of electron beam welding parameters especially focusing and deflection of beam and preheating of base material to quality of heterogeneous join of titanium alloy Ti6Al4V and aluminium alloy EN AW-6061 – T651. There is described preparation of welded joins and brazed joins in the thesis, which are evaluated by light microscopy, scanning electron microscopy and EDS analysis of chemical composition. There was evaluated presence and chemical composition of formated intermetalic phases in the welded joins and quality and defects in the brazed joins.
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