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National Repository of Grey Literature 1 records found  Search took 0.01 seconds. 
Estimation of racemization barriers of selected helquats and their derivatives by capillary electrophoresis using sulfated cyclodextrins as chiral selectors
 Sázelová, Petra ; Koval, Dušan ; Severa, Lukáš ; Reyes Gutierrez, Paul Eduardo ; Jirásek, Michael ; Teplý, Filip ; Kašička, Václav
The recently developed capillary electrophoretic (CE) method for chiral analysis of helquats (helical N-heteroaromatic dications) was applied to monitoring of racemization of selected helquats and helquat styryl dyes and for the determination of their racemization barriers, i.e. activation Gibbs free energy deltaG≠. deltaG≠ of analyzed compounds was found to be in the range 107.7 – 115.7 kJ/mol.
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