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Cleanliness of steels manufactured in vacuum induction furnaces
Pastyřík, Petr ; Záděra, Antonín (referee) ; Pernica, Vítězslav (advisor)
The topic of this thesis is the micropurity of steels manufactured in vacuum induction furnaces. The thesis describes 3 processes of steel melting using the same type of steel with different production parameters. Subsequently, samples were prepared and based on those samples the micropurities of the melting processes were evaluated. To obtain the results image analysis and electron microscope were used. Furthermore, elemental analyzer was used to measure the content of oxygen, nitrogen, sulphur and carbon. Afterwards, a discussion on micropurity and comparison of the melting processes is presented. In the conclusion section there are some possible suggestions concerning operation of the university foundry.
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Crystal and molecular structure study of garnets from selected localities of the České středohoří Mts.
Píšová, Barbora ; Skála, Roman (advisor) ; Laufek, František (referee)
Major and minor element contents of garnets from mantle peridotites and eclogites brought to the surface by volcanic rocks of the České středohoří Mts. were determined by an electron probe microanalyzer. Garnets are homogenous and their chemical composition corresponds to solid solution containing 65-71 % pyrope, other end members significantly present are almandine, uvarovite and grosulare. This method also help to discover polyphase inclusions chemically corresponding to amphiboles (pargasite, cummingtonite, magnesio-hornblende and katophorite). Next to amphiboles following minerals were found in inclusions: omphacite, carbonates, phlogopite, clinochlore, olivine, apatite, spinel group minerals, and sulfidic phases potentially close to pentlandite. Samples were also analyzed by powder X-ray diffraction. Qualitative phase analysis confirmed pyrope homogeneity. The refinement of crystal structure parameters was performed by the Rietveld method. Raman microspectroscopy showed shifts of individual bands in the Raman spectra compared to those of pure pyrope. Position of bands in spectra differs due to the substitution of Ca for Mg at the dodecahedral sites of the structure. Mutual positive correlations among elements Cr, Ca, Mg, Al, Si, Mn, Ti and Na were observed. Correlations were found also between...
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Chemical variability of garnets from the České středohoří Mountains and characterization of their mineral inclusions
Píšová, Barbora ; Skála, Roman (advisor) ; Kotková, Jana (referee)
The samples of garnets used in this study come from clastic sediments from the drillcores Tř-1 and T-31, selected localities of the České středohoří Mountains and garnet-bearing ultramafic rocks sampled by the drillcore T-7. The contents of the major and some minor elements were determined by an electron probe microanalyzer. The garnets from the sediments were divided into 3 groups according to the contents of the end-members: 1) pyrope-, 2) almandine - pyrope- and 3) grosular - almandine-rich. Garnets from the drillcore T-7 were classified according to individual rock types in which they occurred: lherzolite, hazburgite, pyroxenite, eclogite and granulite. Chemical analyzes of garnets displayed the presence of positive correlations Cr vs. Ca vs. Ti Mn in pyrope grains. The contents of trace elements in garnets were studied by an LA-ICP-MS. After normalization to the CI-reservoir, garnets most often show lherzolite profiles of rare earth elements. Garnets of intense red and purple colors show slightly sinusoidal REE profiles. Inclusions enclosed in garnets were studied by a scanning electron microscope. If their dimensions allowed, the major and minor elements were determined by electron microanalysis for inclusions. Inclusions of amphiboles in association with spinel group minerals, carbonates and...
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Chemical variability of garnets from the České středohoří Mountains and characterization of their mineral inclusions
Píšová, Barbora ; Skála, Roman (advisor) ; Kotková, Jana (referee)
The samples of garnets used in this study come from clastic sediments from the drillcores Tř-1 and T-31, selected localities of the České středohoří Mountains and garnet-bearing ultramafic rocks sampled by the drillcore T-7. The contents of the major and some minor elements were determined by an electron probe microanalyzer. The garnets from the sediments were divided into 3 groups according to the contents of the end-members: 1) pyrope-, 2) almandine - pyrope- and 3) grosular - almandine-rich. Garnets from the drillcore T-7 were classified according to individual rock types in which they occurred: lherzolite, hazburgite, pyroxenite, eclogite and granulite. Chemical analyzes of garnets displayed the presence of positive correlations Cr vs. Ca vs. Ti Mn in pyrope grains. The contents of trace elements in garnets were studied by an LA-ICP-MS. After normalization to the CI-reservoir, garnets most often show lherzolite profiles of rare earth elements. Garnets of intense red and purple colors show slightly sinusoidal REE profiles. Inclusions enclosed in garnets were studied by a scanning electron microscope. If their dimensions allowed, the major and minor elements were determined by electron microanalysis for inclusions. Inclusions of amphiboles in association with spinel group minerals, carbonates and...
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Design of a technology and checking the production of small steel ingots
Jakubčíková, Lucie ; Čamek, Libor (referee) ; Záděra, Antonín (advisor)
The thesis deals with the design of ingots from duplex (austenitic-ferritic) stainless steels in terms of minimal occurrence of axial porosity. The optimal shape and dimension of the ingot and the casting conditions are determined based on numerical simulations. The resulting internal quality of the realized ingot is evaluated. The presence of shrinkage porosity is determined by penetrant testing. The degree of chemical heterogeneity, the extent of macrosegregation, of selected elements in given ingot locations is measured by an optical emission spectrometer. Segregation values are compared with simulation results. The micro-purity of the ingot is assessed on the basis of metallographic samples.
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Crystal and molecular structure study of garnets from selected localities of the České středohoří Mts.
Píšová, Barbora ; Skála, Roman (advisor) ; Laufek, František (referee)
Major and minor element contents of garnets from mantle peridotites and eclogites brought to the surface by volcanic rocks of the České středohoří Mts. were determined by an electron probe microanalyzer. Garnets are homogenous and their chemical composition corresponds to solid solution containing 65-71 % pyrope, other end members significantly present are almandine, uvarovite and grosulare. This method also help to discover polyphase inclusions chemically corresponding to amphiboles (pargasite, cummingtonite, magnesio-hornblende and katophorite). Next to amphiboles following minerals were found in inclusions: omphacite, carbonates, phlogopite, clinochlore, olivine, apatite, spinel group minerals, and sulfidic phases potentially close to pentlandite. Samples were also analyzed by powder X-ray diffraction. Qualitative phase analysis confirmed pyrope homogeneity. The refinement of crystal structure parameters was performed by the Rietveld method. Raman microspectroscopy showed shifts of individual bands in the Raman spectra compared to those of pure pyrope. Position of bands in spectra differs due to the substitution of Ca for Mg at the dodecahedral sites of the structure. Mutual positive correlations among elements Cr, Ca, Mg, Al, Si, Mn, Ti and Na were observed. Correlations were found also between...
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Recrystallization study of free-cutting steel by in-situ SEM/EBSD technique
Babinský, Tomáš ; Němec, Karel (referee) ; Petrenec, Martin (advisor)
Placing recrystallization annealing in a manufacturing proces is often necessary in order to restore plasticity of worked blanks right before working products to its final shape. For better understanding of processes which are taking place in a material during annealing the use of in-situ techniques is favorable. Such observations enable us to watch changes in the materiál in real time at the original spot. Observations at grain-level are ideally made with scanning electron microscope – SEM by electron back-scattered diffraction – EBSD. The technique makes watching nucleation, growth and potential coarsening of recrystallized grains possible. Special construction of a tensile stage allows us to watch changes of a sample during tensile tests which can be used in observing influence of MnS inclusions on plasticity of free-cutting steels. Materials studied in this work are commonly used free-cutting steel 11SMnPb30 and its lead-free alternative 11SMnBi30.
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New analytical techniques for the study of amber inclusions
Škorpíková, Šárka ; Prokop, Jakub (advisor) ; Sakala, Jakub (referee)
Amber is an amorphous organic material, a fossil plant resin, mostly produced by Mesozoic and Cenozoic wetland trees. It was often used in jewelry in the past. However, together with the development of paleobiology it has begun to be used as an object of scientific studies, due to its unique abilities to conserve various inclusions in their three-dimensional matter and unusual preservation of their structures. These facts show its important role in the reconstruction of past ecosystems and organism interactions. Various groups of insects and chelicerates groups are typical inclusions that can be found in fossil resins. But the spectrum of these fossil organisms is much wider - from unicellular to vertebrates. For menaningful research of fossil material, precise analytic observations methods are necessary. Their development made a huge progress in last few years. This thesis summarizes the overview of some of these methods and also of inclusions described in several past years from various amber deposits (review of major deposits is included). Powered by TCPDF (www.tcpdf.org)
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Dynamics of structural defects in CdTe-based semiconductors
Bugár, Marek ; Belas, Eduard (advisor) ; Holý, Václav (referee) ; Fochuk, Petro (referee)
Title: Dynamics of structural defects in CdTe-based semiconductors Author: RNDr. Marek Bugár Institute: Institute of Physics, Charles University in Prague Supervisor of the doctoral thesis: Doc. Ing. Eduard Belas CSc.; Institute of Physics, Charles University in Prague Abstract: The work was aimed at investigation of the effect of annealing on structural, electrical and optical properties of CdZnTe epitaxial substrates and CdTe-based and CdZnTe-based X-ray and gamma-ray detectors. The first part of the work is focused on investigation of structural properties of one type of second phase defects - inclusions - present in the material, which degrade the material quality. Consequent annealing experiments were aimed at reduction of these defects. In case of CdZnTe substrates, an annealing treatment leading to increase of the infrared transmittance was investigated. On the other hand, annealing experiments on the detectors of high-energetic radiation were focused on preservation of the high-resistive state. Moreover, the work contains detailed measurements of transport properties of CdTe taken directly at high temperatures. Key words: CdTe, annealing, inclusions, detectors, defects
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Influence of using the secondary metallurgy on steel properties
Navrátil, Horymír ; Fila, Pavel (referee) ; Záděra, Antonín (advisor)
This bachelor thesis describes metallurgical processes of production of steel in electric arc furnaces. It also describes oxidation and reduction phases of melting. Furthermore, it describes the main elements of secondary metallurgy used in steel foundries and their applications. The thesis also concerns with impurities in the steel, namely non-metallic inclusions, gases and trace elements, which is also connected with final utility properties of the steel. This thesis also describes in detail the technological properties of steel. The influence of several selected elements on steel properties is also described. Finally, the thesis evaluates the effect of secondary metallurgy on the volume of defects in steel castings, on mechanical properties and the resulting chemical composition.
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