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Design of syngas cleaning by wet scrubber
Musilová, Petra ; Milčák, Pavel (referee) ; Baláš, Marek (advisor)
Gasification is a process which produces gas of low heating value, however, generated gas contains several pollutants. This thesis is dealing with the issue of purity and cleaning of generated gas. Theoretic part of thesis consists of research, describing the very process of gasification itself, mapping of possible pollutants appearing during gasification and particular ways of purifying gas, looking in detail at wet scrubbing with several scrubbing liquids. Further, it looks into proposition of conditions for wet scrubbing and balance of scrubbing liquids. Next part deals with calculation of purifying line. Main goal of calculations, is to determine the length of the pipeline, transfering polluted gas from the gasifier to the filter for elimination of solid particles and wet scrubber. Key aspect of length calculation was the input and output temperature of the gas, determined by characteristics of the filter. Calculation for wet scrubber istelf is also included, to detremine if the output temperature of the scrubbing liquid after the passage of the gas needs to be modified by additional cooling or heating. For experimental purposes, syngas generated by gasification of biomass, is gathered from the atmospheric gasifier Biofluid 2. Experiment itself inquires into the purity of the gas before and after the passage through solid particles filter and through the wet scrubber. The purpose of this thesis is to determine the chemical composition of gas before and after wet scrubbing, the difference of composition of tar gathered from purified and nonpurified gas and using gathered data to evaluate the effectiveness of wet scrubbing.
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Syngas Cleaning in Hot Catalytic Filter
Lisý, Martin ; Skála, Zdeněk (advisor)
Disertation thesis deals with development of hot dolomite filter for the purposes of cleaning of gas polluted by biomass and waste gasification with ash and tar as well as sulphur and chlorine compounds as main pollutants. Gas is then cleaned so that it can be utilized in cogeneration units with combustion engines. This supports advancement of gasification techniques using decentralized power and heat generation especially for design of small scale units. Concrete aims of this thesis are stated in chapter 2. Experimental fluid gasification stend Biofluid 100 has been in operations at Brno University of Technology (BUT) since 2000 and it helps research of biomass and waste gasification. Development of the filter initially utilized needs and experience with the utility during cooperation of BUT and ATEKO Hradec Králové. Water scrubber was used for gas cleaning, however, this method proved to be ineffective. Alternative solutions were considered. Based on literature search, natural catalysts with limestone basis were opted. First part of the thesis presents literature search of this issue. Historic development and description of gasification process are briefly discussed as well as elementary classification of gasification generators. This part is followed by chapters dealing with gas pollutants. Tar – the most significant pollutant – is discussed in a separate chapter which presents tar formation, its classification, characteristics and methods for its removal. Brief summary of requirements on gas properties with respect to its utilization in various applications (especially in cogeneration units) follows. Other part of the literature search part focuses on methods of removal of tar from gas, especially on catalyst methods. Dolomite characteristics, description of dolomite calcination as well as simplified kinetic model of tar cracking using dolomite are presented. Based on literature search, laboratory and verification equipment was designed for the purposes of dolomite properties testing. Equipment description as well as description of experimental stend Biofluid 100 where the experimental tests were carried out can be found in introduction of the experimental part. This is followed by a complete description of pilot equipment design of hot dolomite filter with general description of experimental work process, brief characteristics of the fuel and catalytic material used. Final part of the work comprises of experiment results that were carried out on the pilot equipment. Focus is on efficiency of tar removal in connection with operation temperature, amount of catalytist and material used. Influence of these parameters on gas composition and energy intensity of the whole process under these conditions is mentioned as well. Possibility of autonomous unit operations without electricity heating is briefly outlined. Summary of the most significant results including the potential of future hot dolomite filter development is stated the final part of the thesis.
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Syngas composition influence on gas cleaning efficiency
Menšíková, Barbora ; Lisý, Martin (referee) ; Baláš, Marek (advisor)
The diploma thesis deals with the issue of pollution of the generated gas after the gasification process and its subsequent cleaning using a barrier filter. The theoretical part of thesis consists of research on the gasification process, the effects on the gasification process, pollutants in the gas and gas cleaning with a focus on the purification of gas from tar. The experimental part of this thesis is devoted to the gasification itself in a fluidized bed gasification reactor in order to test the effect of the catalyst, which was calcined dolomite, the composition of the gas at variable parameters of water vapor and the temperature inside the laboratory filter.
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Testing of the barrier filter charge for gas cleaning
Muzikářová, Věra ; Milčák, Pavel (referee) ; Baláš, Marek (advisor)
This diploma thesis deals with the issue of pollution of the generated gas during gasification. It consists of two parts. The first part is theoretical, where there is a search describing the course of gasification. There is also an overview of impurities in the generated gas and a description of methods suitable for gas purification. The second part of the work is focused experimentally, where various fillings of the barrier filter are tested during gas cleaning.
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Testing of the barrier filter charge for gas cleaning
Muzikářová, Věra ; Milčák, Pavel (referee) ; Baláš, Marek (advisor)
This diploma thesis deals with the issue of pollution of the generated gas during gasification. It consists of two parts. The first part is theoretical, where there is a search describing the course of gasification. There is also an overview of impurities in the generated gas and a description of methods suitable for gas purification. The second part of the work is focused experimentally, where various fillings of the barrier filter are tested during gas cleaning.
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Syngas composition influence on gas cleaning efficiency
Menšíková, Barbora ; Lisý, Martin (referee) ; Baláš, Marek (advisor)
The diploma thesis deals with the issue of pollution of the generated gas after the gasification process and its subsequent cleaning using a barrier filter. The theoretical part of thesis consists of research on the gasification process, the effects on the gasification process, pollutants in the gas and gas cleaning with a focus on the purification of gas from tar. The experimental part of this thesis is devoted to the gasification itself in a fluidized bed gasification reactor in order to test the effect of the catalyst, which was calcined dolomite, the composition of the gas at variable parameters of water vapor and the temperature inside the laboratory filter.
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Design of syngas cleaning by wet scrubber
Musilová, Petra ; Milčák, Pavel (referee) ; Baláš, Marek (advisor)
Gasification is a process which produces gas of low heating value, however, generated gas contains several pollutants. This thesis is dealing with the issue of purity and cleaning of generated gas. Theoretic part of thesis consists of research, describing the very process of gasification itself, mapping of possible pollutants appearing during gasification and particular ways of purifying gas, looking in detail at wet scrubbing with several scrubbing liquids. Further, it looks into proposition of conditions for wet scrubbing and balance of scrubbing liquids. Next part deals with calculation of purifying line. Main goal of calculations, is to determine the length of the pipeline, transfering polluted gas from the gasifier to the filter for elimination of solid particles and wet scrubber. Key aspect of length calculation was the input and output temperature of the gas, determined by characteristics of the filter. Calculation for wet scrubber istelf is also included, to detremine if the output temperature of the scrubbing liquid after the passage of the gas needs to be modified by additional cooling or heating. For experimental purposes, syngas generated by gasification of biomass, is gathered from the atmospheric gasifier Biofluid 2. Experiment itself inquires into the purity of the gas before and after the passage through solid particles filter and through the wet scrubber. The purpose of this thesis is to determine the chemical composition of gas before and after wet scrubbing, the difference of composition of tar gathered from purified and nonpurified gas and using gathered data to evaluate the effectiveness of wet scrubbing.
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Syngas Cleaning in Hot Catalytic Filter
Lisý, Martin ; Noskievič, Pavel (referee) ; Bébar, Ladislav (referee) ; Kabát, Viktor (referee) ; Skála, Zdeněk (advisor)
Disertation thesis deals with development of hot dolomite filter for the purposes of cleaning of gas polluted by biomass and waste gasification with ash and tar as well as sulphur and chlorine compounds as main pollutants. Gas is then cleaned so that it can be utilized in cogeneration units with combustion engines. This supports advancement of gasification techniques using decentralized power and heat generation especially for design of small scale units. Concrete aims of this thesis are stated in chapter 2. Experimental fluid gasification stend Biofluid 100 has been in operations at Brno University of Technology (BUT) since 2000 and it helps research of biomass and waste gasification. Development of the filter initially utilized needs and experience with the utility during cooperation of BUT and ATEKO Hradec Králové. Water scrubber was used for gas cleaning, however, this method proved to be ineffective. Alternative solutions were considered. Based on literature search, natural catalysts with limestone basis were opted. First part of the thesis presents literature search of this issue. Historic development and description of gasification process are briefly discussed as well as elementary classification of gasification generators. This part is followed by chapters dealing with gas pollutants. Tar – the most significant pollutant – is discussed in a separate chapter which presents tar formation, its classification, characteristics and methods for its removal. Brief summary of requirements on gas properties with respect to its utilization in various applications (especially in cogeneration units) follows. Other part of the literature search part focuses on methods of removal of tar from gas, especially on catalyst methods. Dolomite characteristics, description of dolomite calcination as well as simplified kinetic model of tar cracking using dolomite are presented. Based on literature search, laboratory and verification equipment was designed for the purposes of dolomite properties testing. Equipment description as well as description of experimental stend Biofluid 100 where the experimental tests were carried out can be found in introduction of the experimental part. This is followed by a complete description of pilot equipment design of hot dolomite filter with general description of experimental work process, brief characteristics of the fuel and catalytic material used. Final part of the work comprises of experiment results that were carried out on the pilot equipment. Focus is on efficiency of tar removal in connection with operation temperature, amount of catalytist and material used. Influence of these parameters on gas composition and energy intensity of the whole process under these conditions is mentioned as well. Possibility of autonomous unit operations without electricity heating is briefly outlined. Summary of the most significant results including the potential of future hot dolomite filter development is stated the final part of the thesis.
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Syngas Cleaning in Hot Catalytic Filter
Lisý, Martin ; Skála, Zdeněk (advisor)
Disertation thesis deals with development of hot dolomite filter for the purposes of cleaning of gas polluted by biomass and waste gasification with ash and tar as well as sulphur and chlorine compounds as main pollutants. Gas is then cleaned so that it can be utilized in cogeneration units with combustion engines. This supports advancement of gasification techniques using decentralized power and heat generation especially for design of small scale units. Concrete aims of this thesis are stated in chapter 2. Experimental fluid gasification stend Biofluid 100 has been in operations at Brno University of Technology (BUT) since 2000 and it helps research of biomass and waste gasification. Development of the filter initially utilized needs and experience with the utility during cooperation of BUT and ATEKO Hradec Králové. Water scrubber was used for gas cleaning, however, this method proved to be ineffective. Alternative solutions were considered. Based on literature search, natural catalysts with limestone basis were opted. First part of the thesis presents literature search of this issue. Historic development and description of gasification process are briefly discussed as well as elementary classification of gasification generators. This part is followed by chapters dealing with gas pollutants. Tar – the most significant pollutant – is discussed in a separate chapter which presents tar formation, its classification, characteristics and methods for its removal. Brief summary of requirements on gas properties with respect to its utilization in various applications (especially in cogeneration units) follows. Other part of the literature search part focuses on methods of removal of tar from gas, especially on catalyst methods. Dolomite characteristics, description of dolomite calcination as well as simplified kinetic model of tar cracking using dolomite are presented. Based on literature search, laboratory and verification equipment was designed for the purposes of dolomite properties testing. Equipment description as well as description of experimental stend Biofluid 100 where the experimental tests were carried out can be found in introduction of the experimental part. This is followed by a complete description of pilot equipment design of hot dolomite filter with general description of experimental work process, brief characteristics of the fuel and catalytic material used. Final part of the work comprises of experiment results that were carried out on the pilot equipment. Focus is on efficiency of tar removal in connection with operation temperature, amount of catalytist and material used. Influence of these parameters on gas composition and energy intensity of the whole process under these conditions is mentioned as well. Possibility of autonomous unit operations without electricity heating is briefly outlined. Summary of the most significant results including the potential of future hot dolomite filter development is stated the final part of the thesis.
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