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Incineration of Sludge Mixed with Alkali
Urban, Václav ; Jecha, David (referee) ; Houdková, Lucie (advisor)
Subject of the present Ing. thesis is problem of incineration of sewage sludge and influence of lime on production of editions. In work are described kinds of sewage sludge combustion and possibilities of edition cleaning. Work includes design and description of experimental combustion of sewage sludge mixtured with kalcite in fluidized bed reactor. The end of work delal with, evaluation of editions from combustion experiment. Evaluated components of bunt gases are: heavy metals, TZL, SO2, CO, CO2, HCl, HF, O2, NO, PAH, PCB, PCDD/F.
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Biomass gasification with oxygen
Dubinová, Petra ; Lisý, Martin (referee) ; Baláš, Marek (advisor)
Biomass gasification using air with addition of oxygen can be the right way to increase the quality of the syngas produced. This thesis aims to characterize the gasification process using oxygen-enriched air and verify its effect on the gas. The theoretical part deals with description of the technology with an emphasis on various gasifying agents and different possibilities of increasing gas quality. The practical part contains the results of measurements on the atmospheric fluidized bed reactor and their evaluation. The experiment was performed with various oxygen enrichment taking into account the capabilities of the equipment used.
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Modelling of heterogeneous catalytic reactions in chemical reactors
Orava, Vít ; Hron, Jaroslav (advisor) ; Pavelka, Michal (referee) ; Růžička, Marek (referee)
This thesis consists of two parts discussing modelling of heterogeneous catalytic reactors. In the first one, an industrial prototype of a fluidized bed reactor serving as a hydrogen generator based on endothermic decomposition of formic acid is studied. After initial determination of the main reactor characteristics a system of nine con- stituents is derived and, consequently, reduced to a three phase flow. The solid and bubble particles immersed in a liquid are modelled by the Basset-Boussinesq- Ossen equation. Furthermore, an averaging technique is used to derive a three phase Euler-Euler model. Finally, numerical computations with a verification towards the measurements and a CFD analysis are proceeded. The second part discusses interfacial transport phenomena between a bulk and catalytic surfaces of a reactor mediated via the boundary conditions. The constitu- tive relations, that by construction comply with the second law of thermodynamics, follow from the specification of suitable thermodynamic potentials together with an identification of the bulk and surface entropy productions. The derived model is suitable for further analysis providing clear guidelines for the incorporation of the Langmuir-type adsorption model as well as other sorption models. Keywords: Heterogeneous catalysis, multi-phase...
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Modelling of heterogeneous catalytic reactions in chemical reactors
Orava, Vít ; Hron, Jaroslav (advisor)
This thesis consists of two parts discussing modelling of heterogeneous catalytic reactors. In the first one, an industrial prototype of a fluidized bed reactor serving as a hydrogen generator based on endothermic decomposition of formic acid is studied. After initial determination of the main reactor characteristics a system of nine con- stituents is derived and, consequently, reduced to a three phase flow. The solid and bubble particles immersed in a liquid are modelled by the Basset-Boussinesq- Ossen equation. Furthermore, an averaging technique is used to derive a three phase Euler-Euler model. Finally, numerical computations with a verification towards the measurements and a CFD analysis are proceeded. The second part discusses interfacial transport phenomena between a bulk and catalytic surfaces of a reactor mediated via the boundary conditions. The constitu- tive relations, that by construction comply with the second law of thermodynamics, follow from the specification of suitable thermodynamic potentials together with an identification of the bulk and surface entropy productions. The derived model is suitable for further analysis providing clear guidelines for the incorporation of the Langmuir-type adsorption model as well as other sorption models. Keywords: Heterogeneous catalysis, multi-phase...
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Modelling of heterogeneous catalytic reactions in chemical reactors
Orava, Vít ; Hron, Jaroslav (advisor)
This thesis consists of two parts discussing modelling of heterogeneous catalytic reactors. In the first one, an industrial prototype of a fluidized bed reactor serving as a hydrogen generator based on endothermic decomposition of formic acid is studied. After initial determination of the main reactor characteristics a system of nine con- stituents is derived and, consequently, reduced to a three phase flow. The solid and bubble particles immersed in a liquid are modelled by the Basset-Boussinesq- Ossen equation. Furthermore, an averaging technique is used to derive a three phase Euler-Euler model. Finally, numerical computations with a verification towards the measurements and a CFD analysis are proceeded. The second part discusses interfacial transport phenomena between a bulk and catalytic surfaces of a reactor mediated via the boundary conditions. The constitu- tive relations, that by construction comply with the second law of thermodynamics, follow from the specification of suitable thermodynamic potentials together with an identification of the bulk and surface entropy productions. The derived model is suitable for further analysis providing clear guidelines for the incorporation of the Langmuir-type adsorption model as well as other sorption models. Keywords: Heterogeneous catalysis, multi-phase...
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Biomass gasification with oxygen
Dubinová, Petra ; Lisý, Martin (referee) ; Baláš, Marek (advisor)
Biomass gasification using air with addition of oxygen can be the right way to increase the quality of the syngas produced. This thesis aims to characterize the gasification process using oxygen-enriched air and verify its effect on the gas. The theoretical part deals with description of the technology with an emphasis on various gasifying agents and different possibilities of increasing gas quality. The practical part contains the results of measurements on the atmospheric fluidized bed reactor and their evaluation. The experiment was performed with various oxygen enrichment taking into account the capabilities of the equipment used.
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Modelling of heterogeneous catalytic reactions in chemical reactors
Orava, Vít ; Hron, Jaroslav (advisor) ; Pavelka, Michal (referee) ; Růžička, Marek (referee)
This thesis consists of two parts discussing modelling of heterogeneous catalytic reactors. In the first one, an industrial prototype of a fluidized bed reactor serving as a hydrogen generator based on endothermic decomposition of formic acid is studied. After initial determination of the main reactor characteristics a system of nine con- stituents is derived and, consequently, reduced to a three phase flow. The solid and bubble particles immersed in a liquid are modelled by the Basset-Boussinesq- Ossen equation. Furthermore, an averaging technique is used to derive a three phase Euler-Euler model. Finally, numerical computations with a verification towards the measurements and a CFD analysis are proceeded. The second part discusses interfacial transport phenomena between a bulk and catalytic surfaces of a reactor mediated via the boundary conditions. The constitu- tive relations, that by construction comply with the second law of thermodynamics, follow from the specification of suitable thermodynamic potentials together with an identification of the bulk and surface entropy productions. The derived model is suitable for further analysis providing clear guidelines for the incorporation of the Langmuir-type adsorption model as well as other sorption models. Keywords: Heterogeneous catalysis, multi-phase...
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Incineration of Sludge Mixed with Alkali
Urban, Václav ; Jecha, David (referee) ; Houdková, Lucie (advisor)
Subject of the present Ing. thesis is problem of incineration of sewage sludge and influence of lime on production of editions. In work are described kinds of sewage sludge combustion and possibilities of edition cleaning. Work includes design and description of experimental combustion of sewage sludge mixtured with kalcite in fluidized bed reactor. The end of work delal with, evaluation of editions from combustion experiment. Evaluated components of bunt gases are: heavy metals, TZL, SO2, CO, CO2, HCl, HF, O2, NO, PAH, PCB, PCDD/F.
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