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Organic semiconductors properties
Kočer, Martin ; Vaněk, Jiří (referee) ; Špinka, Jiří (advisor)
This diploma thesis deals with optical properties of organic semiconductors and measuring method of absorption edge. Project is focused on absorption of light in organic semiconductors. This work also describes device for measuring of absorption edge.
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Organic semoconductors materials
Černošek, Michal ; Starý, Jiří (referee) ; Špinka, Jiří (advisor)
This bachelor thesis deals with organic materials and parts made of this materials. Described are also principels of their functions, structure of whore part and issues linked with production. Next are refered advanteges and disadvantages of those parts. Described are also events which occures during using organic parts. Attention is given to light emitting diods. In experimental part is measured electrical attriburtes of PLED structures, exposed to different sources of illumination. Influence of illumination to transfer of electrical charge is examined too
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Low-molecular materials for organic electronics and photonics
Češka, Matěj ; Salyk, Ota (referee) ; Weiter, Martin (advisor)
This master´s thesis deals with organic materials for use in electronics and photonics. Attention was paid to low molecular weight materials. The theoretical part of this thesis contains brief introduction to organic electronics and photonics. In particular, organic transistors, organic solar cells and organic light-emitting diodes are mentioned. The experimental part is focused on study of electrical and optical properties of two types of phthalocyanines. Thin films and solutions of phthalocyanines were characterized by UV-VIS spectroscopy. Thin films were also characterized by current voltage characteristics, spectral response measurement of photocurrent and by method of transient photoconductivity. It was found that illumination affects the electrical properties of thin layers of phthalocyanines, the performance of the prepared thin films depends on the type phthalocyanine and also depends on the thickness of the layer.
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Measurement of spectral characteristics in Labview environment
Konečný, Dávid ; Hégr, Ondřej (referee) ; Boušek, Jaroslav (advisor)
This work deals with design of a program for measurement of characteristics luminescence of inorganic semiconductors in LabView environment. After understanding with theoretic part a program for automated measurements was made including two type of measurements option. The program for measurement of Volt-Ampere characteristics by given wave length and for measurement of current on wave length dependencies is presented.
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Impedance spectroscopy of organic conductors and semiconductors
Černošek, Michal ; Sedláček, Jiří (referee) ; Hubálek, Jaromír (advisor)
This thesis deals with organic materials and determining their electrical parameters. In the thesis are discussed methods of deposition of organic layers and their measurement. Described are the aspects, which are characteristic for organic materials. They will briefly mention some new components and commercial systems. Special attention is given to conducting polymers and determining their parameters. In the experimental part were measured VA and impedance characteristics of the conductive polymer PEDOT-PSS. The research was also about material degradation in time and effects of thickness on the electrical parameters.
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New organic semiconductors for bioelectronics
Malečková, Romana ; Salyk, Ota (referee) ; Vala, Martin (advisor)
This thesis focuses on the characterization of PEDOT:DBSA, a new semiconducting polymer for use in bioelectronic devices. It also deals with possibilities of surface treatment in order to enhance its biocompatibility and stability in aqueous environments. For this purpose, the organic polymer films were crosslinked with two crosslinking agents – GOPS and DVS. The ability of these agents to prevent leaching of some fractions of the polymer films in an aqueous environment and the ability to bind polymer molecules to each other as well as to the glass substrate was studied using the delamination test. Subsequently, the effects of these crosslinking agents on the film properties essential for the proper functions of bioelectronics made of these materials, was studied by contact angle measurements and four-point probes respectively. Moreover, several OECTs were prepared using original and crosslinked material as an active layer and were characterized by measuring transconductance and volumetric capacitance. PEDOT:DBSA has been shown to be a suitable material for use in bioelectronics, but its thin layers need to be stabilized in an aqueous environment. The agent DVS appears to be unsuitable for this purpose, mainly due to its insufficient film stabilization and its increased hydrophilicity of the film surface, thus increased tendency to interact with water, resulting in degradation of these thin layers. In contrast, GOPS, despite some reduction in film conductivity, has been able to stabilize the polymer layer over the long term, and thus appears to be a suitable way to stabilize PEDOT:DBSA.
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Growth of organic heterostructures on metal surfaces
Kugler, David ; Novák,, Jiří (referee) ; Procházka, Pavel (advisor)
Během depozice organických molekul na kovové substráty často dochází k spontánnímu uspořádání molekul vlivem mezimolekulárních a molekulárně-substrátových interakcí. Tento jev se nazývá samouspořádání a může být využit k vytváření atomárně přesných funkčních struktur. Vzrůstající zájem vzbuzují zejména tenké vrstvy organických polovodičů pro jejich potenciální využití v polovodičovém průmyslu. Efektivita takovýchto zařízení je však nevyhnutelně spojena s přechodovým odporem na rozhraní polovodiče a kovové elektrody. Studium typu růstu organických polovodičů na kovových substrátech je tak zcela zásadní pro jejich budoucí využití. Tato diplomová práce se nejprve zabývá vytvořením krycí monovrstvy substrátu Ag(111) z dobře uspořádaných molekul kyseliny 1,3,5-benzen-trikarboxylové (BTB). Hlavním cílem práce je pak použití této vrstvy jako substrátu pro růst dalších vrstvev tvořených molekulami pentacenu, což je jeden z intenzivně zkoumaných organických polovodičů. Bylo dosaženo pokrytí povrchu uspořádanou vrstvou pentacenu o rozloze vhodné pro praktické využití. Pro studium růstu molekulárních vrstev a jejich vlastností byla použita nízkoenergiová elektronová mikroskopie, skenovací tunelovací mikroskopie, rentgenová fotoelektronová spektroskopie a ultrafialová fotoelektronová spektroskopie.
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New organic semiconductors for bioelectronics
Malečková, Romana ; Salyk, Ota (referee) ; Vala, Martin (advisor)
This thesis focuses on the characterization of PEDOT:DBSA, a new semiconducting polymer for use in bioelectronic devices. It also deals with possibilities of surface treatment in order to enhance its biocompatibility and stability in aqueous environments. For this purpose, the organic polymer films were crosslinked with two crosslinking agents – GOPS and DVS. The ability of these agents to prevent leaching of some fractions of the polymer films in an aqueous environment and the ability to bind polymer molecules to each other as well as to the glass substrate was studied using the delamination test. Subsequently, the effects of these crosslinking agents on the film properties essential for the proper functions of bioelectronics made of these materials, was studied by contact angle measurements and four-point probes respectively. Moreover, several OECTs were prepared using original and crosslinked material as an active layer and were characterized by measuring transconductance and volumetric capacitance. PEDOT:DBSA has been shown to be a suitable material for use in bioelectronics, but its thin layers need to be stabilized in an aqueous environment. The agent DVS appears to be unsuitable for this purpose, mainly due to its insufficient film stabilization and its increased hydrophilicity of the film surface, thus increased tendency to interact with water, resulting in degradation of these thin layers. In contrast, GOPS, despite some reduction in film conductivity, has been able to stabilize the polymer layer over the long term, and thus appears to be a suitable way to stabilize PEDOT:DBSA.
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Organic semoconductors materials
Černošek, Michal ; Starý, Jiří (referee) ; Špinka, Jiří (advisor)
This bachelor thesis deals with organic materials and parts made of this materials. Described are also principels of their functions, structure of whore part and issues linked with production. Next are refered advanteges and disadvantages of those parts. Described are also events which occures during using organic parts. Attention is given to light emitting diods. In experimental part is measured electrical attriburtes of PLED structures, exposed to different sources of illumination. Influence of illumination to transfer of electrical charge is examined too
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