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Monitoring of corrosion of refractory lining
Taraba, Vojtěch ; Ptáček, Petr (referee) ; Opravil, Tomáš (advisor)
This bachelor’s thesis is focused on the monitoring of corrosion of refractory lining in the cement rotary kiln, chemical and mineralogical changes of the refractory and their influence on the lining properties. Magnesia-spinel refractories located in the lower transition zone are analyzed by X-ray diffraction, X-ray fluorescence, inductively coupled plasma optical emission spectrometry and scanning electron microscopy.
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Reactivity and controll of properties of metallic materials
Ševčíková, Barbora ; Opravil, Tomáš (referee) ; Zmrzlý, Martin (advisor)
The main objective of the bachelor thesis is to investigate the reactivity and corrosion of materials, namely of magnesium alloys. The theoretical part comprises a brief summary of the existing knowledge on magnesium alloys in the field of metal corrosion and a description of essential properties of the examined and utilized material. These are followed by the protection technology and a material resistance analysis including the specification of the processes applied in the experimental part. The thesis is focused on a comparison of the microstructure and corrosion resistance of magnesium alloys AZ31, AZ61 and AZ91. The applied methodology lied on metallography preparation of light optical micrographs of the surface-region cross-sections and on corrosion tests. These were carried out in 3% sodium chloride solution where the samples were immersed for the period of 8 hours.
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Monitoring of alkalis in Portland clinker
Siudová, Alena ; Šoukal, František (referee) ; Opravil, Tomáš (advisor)
This bachelor thesis focuses on the localization of alkali in Portland clinker and their properties, which can significantly affect the lifetime of the concrete produced from these cements. The bachelor thesis deals with the study of the phases of the alkali in Portland clinker and the compounds they represent. Further, the bachelor thesis deals with the study of the rate of transfer of alkali into solution when mixing Portland clinker with water. Several different Portland slinks are analyzed and compared. The aim of the thesis is to try to find a connection between measured experimental values, clinker composition and alkaline-silica reaction precursors.
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Possibilities of utilisation of salt slags from aluminum production
Sedlačík, Martin ; Másilko, Jiří (referee) ; Opravil, Tomáš (advisor)
Bachelor thesis deals with characterisation of salt slag formed during melting of aluminium scrap in rotary furnaces and proposes options of utilization of this material as a secondary raw material. Samples from top, middle and bottom part of mould, where slag cools down after the melting process is finished, were tested. Aim of the thesis is also to evaluate the effect of air access during the cooling process on phase and chemical composition of salt slag. Particle size distribution, content of soluble substances and composition were examined in collected samples. Phase and chemical compositions of both soluble and insoluble portion of idividual fractions were determined using X-ray powder diffraction and X-ray fluorescence spectrometry.
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Inorganic thermal insulation material for masonry elements
Sedlačík, Martin ; Švec, Jiří (referee) ; Opravil, Tomáš (advisor)
This master’s thesis deals with preparation of foam glass and explores the possibilies of utilization of this material as an inorganic thermal insulating filler of fired hollow bricks. Foam glass was prepared via powder sintering method from waste packaging glass, using limestone and graphite as foaming agents. After inital analysis of raw materials, the effect of mixture composition and different processing parameters on bulk density, pore size and morphology of foam glass was investigated. Last but not least, different ways of manufacturing thermal insulating bricks, by preparation of foam glass directly in the cavities of fired hollow bricks, were tested.
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Influence of fly ash containing products after flue gases denitrification to corrosion of metal parts of technological units
Řezanina, Marek ; Tkacz, Jakub (referee) ; Opravil, Tomáš (advisor)
This thesis deals with the influence of fly ash containing residues of flue gas denitrification after SNCR method. There are remains of ammonium compounds and bicarbonate compoudns, especially the hydrogen ammonium sulphate in solid combustion products, when using the SNCR method. This substance itself is corrosive, and it releases ammonium ions to the solution and releases an ammonia gas in case the pH is higher than 9. Because the fly ash gets processed, transported, and if you add lime it also produces the so called stabilizate. it is necessary to think about the corrosion of equipment in which these processes take place. The aim of this thesis is to assess the degree of corrosion of various types of steel in corrosive environments described above.
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Utilization of recycled brick waste for growing the agricultural plants
Šmírová, Barbora ; Másilko, Jiří (referee) ; Opravil, Tomáš (advisor)
The master thesis follows up on previous bachelor thesis, which dealt with the sorption capacity of brick recyclate. Brick recyclate, as same as brick, excel with very high porosity. For this reason this work deals with possible implementation of plant growth aids (fertilizers) on the inside surface of such highly porous material This thesis studies possibilities of preparation of brick recyclate with the content of components supporting plant growth. It is a material, that is able to bind water in the soil and nourish cultivated plants at the same time. Aim of the work is to find out, what maximum amount of supporting substances, that later will be released back into surrounding enviroment (soil), is possible to incorporate into the brick recyclate. Such prepared recyclate was added in different amounts into predefined substrates, where plants were grown. Subsequently, the growth course, germination and yields of selected crops were monitored. It was verified that the material based on recycled brick enriched with nutrients improves the distribution of nutrients in the soil and positively affects the germination, growth and yields of tested crops.
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Mapping the potential of secondary products from the production of titanium white
Nehéz, Samuel Emil ; Šoukal, František (referee) ; Opravil, Tomáš (advisor)
This bachelor’s thesis deals with the use of secondary products from the production of titanium white and its subsequent use during cement production. Secondary products from the production of TiO2 could be regarded as several kinds of sulphate waters, where by their successive neutralization gypsum by-products are prepared. The aim of the bachelor’s thesis was to experiment whether it is possible to use some of these gypsum by-products as solidification retarder in Portland cement. Cement pastes were prepared and subjected to mechanical and analytical examinations. During the mechanical examinations, strength in pressure during bending and strength in pulling for the duration of 60 days were monitored. The material from tested bodies of pastes was reviewed by x-ray difraction analysis after 7 and 28 days. Just as was determined the optimum W/C, initial and final setting time. The prepared samples with the gypsum by-product as their content had some features comparable with commercially used cement.
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Possibilities of utilization of brick-grind-dust in alternative binding systems based on fluidized ash
Tušla, Václav ; Švec, Jiří (referee) ; Opravil, Tomáš (advisor)
This bachelor´s thesis deals with usage of brick-grind-dust in alternative binding systems based on ashes of fluid combustion. Specifically it deals with fly ashes and softly milled bed ashes of brown coal combustion. Primarily thanks of content of free lime, anhydrite and other components, fluid ashes have binding properities. Brick-grind-dust arise in end formation of burned bricks. The aim of thesis is to verify, possibilities to create composite of appropriate abilities with high or even exclusive amount of fluid ashes and brick-grind-waste. The paper also deals with influence of some chemical modifying additive on this alternative systems.
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Possibilities of application of fluidized bed combustion solid residues from municipal waste
Melicher, Daniel ; Solný, Tomáš (referee) ; Opravil, Tomáš (advisor)
The bachelor thesis deals with the use of solid residues from incineration waste products, especially in the construction industry. The aim of the thesis is to test various modifications of solid residues from incineration waste. These secondary materials were tested in bonding systems based on hydratation of portland cement, gypsum made from chemogypsum, quicklime and alkali-activated systems. The aim was to verify whether solid residues from waste incineration could be used as a component of alternative materials for the construction industry.
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