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Organic vapour sensing and thermoelectric properties of carbon nanotubes/ethylene-octene copolymer composites combined in a thermopile
Slobodian, P. ; Říha, Pavel ; Olejník, R. ; Benlikaya, R.
A novel self-powered thermoelectric vapor sensor, whose thermogenerated voltage was modulated by chemical vapors is presented. The sensor was made of composites of oxidized multi-walled carbon nanotubes within\nethylene-octene copolymer. The multi-walled carbon nanotubes within ethylene-octene copolymer showed that the oxidation with KMnO4 enhanced its p-type electrical conductivity and that the thermoelectric power increase was proportional to the formation of new oxygen-containing\nfunctional groups on the surface of carbon nanotubes. When this composite was subjected to a saturated vapor of either heptane (aliphatic hydrocarbon), toluene (aromatic hydrocarbon) or ethanol (alcohol), its respective relative resistance increased in average by 3.6, 1.1 and 0.05.

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