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Modification of coating-substrate interface character of thermally sprayed coatings using electron beam technology
Mareš, Jiří ; Moravčík, Igor (oponent) ; Čížek, Jan (vedoucí práce)
This thesis is focused on a modification of the coating-substrate interface of NiCrAlY bond-coats deposited by water stabilized plasma technology on S235JRC+C steel substrates. Electron beam remelting was chosen as the technology used for the modification and two different modifications were investigated. Attempt has been made to determine the effect of remelting on the adhesive strength of the coatings. Further analysis of the microstructure, phase and chemical composition and microhardness were carried out in the state prior and after the modification. During the study it was found that change in phase composition occurs after the deposition as well as after the electron beam modification. It was also found that the electron beam modification caused melting of oxides in the coating original microstructure and resulted in resolidification of these oxides on the surface of the modified layer. Further it was found that electron beam modification resulted in decreased microhardness of the coatings due to oxide removal from the microstructure and coating substrate material mixing. Adhesive strength of the coatings in as-sprayed condition was quantified, however in the case of electron beam modified coatings the adhesive strength could not be fully quantified due to premature failure at the coating adhesive agent interface during adhesion testing.
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Kompletní charakterizace žárově stříkaného povlaku na bázi keramiky na hořčíkové slitině AZ91
Plevová, Kateřina ; Doskočil, Leoš (oponent) ; Wasserbauer, Jaromír (vedoucí práce)
Diplomová práce je zaměřena na studium žárově stříkaného povlaku tvořeného vazebnou vrstvou slitiny NiCrAlY a vrstvou částečně stabilizovaného oxidu zirkoničitého (8YSZ) na hořčíkové slitině AZ91. Teoretická část se zabývá strukturou slitiny AZ91, NiCrAlY a částečně stabilizovaného oxidu zirkoničitého. Dále jsou zde shrnuty metody žárových nástřiků a funkce a vlastnosti povlaků tvořících tepelnou bariéru. Experimentální část se zabývá charakterizací žárově stříkaného povlaku a slitiny AZ91 z hlediska prvkového, strukturního a fázového složení. K charakterizaci byla využita optická a elektronová mikroskopie, EDS a XRD analýza. Elektrochemické vlastnosti byly zkoumány v 3,5% roztoku chloridu sodného pomocí potenciodynamické polarizace. Mechanické vlastnosti (tvrdost, koeficient tření) substrátu a povlaku byly měřeny pomocí tvrdoměru a tribologických zkoušek.
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Microstructure and microhardness evaluation for NiCrAlY materials manufactured by spark plasma sintering and plasma spraying
Hulka, Iosif ; Mušálek, Radek ; Lukáč, František ; Klečka, Jakub ; Chráska, Tomáš
NiCrAlY deposited by different thermal spraying methods is commonly used as the bond coat material in thermal barrier coatings (TBCs). In the present study, two experimental coatings were deposited by hybrid water stabilized plasma (WSP-H) and radio frequency inductively coupled plasma (RF-ICP) using the same feedstock powder. Spark plasma sintering (SPS) was used to manufacture a compact NiCrAlY from the same feedstock powder as a reference material. Microstructure, internal oxidation, phase characterization and quantification of the mechanical behaviour in terms of microhardness were studied. The investigations clearly showed microstructural and mechanical differences between the NiCrAlY samples manufactured by different plasma technologies. The results confirmed that SPS and RF-ICP provide dense structures with no oxides due to the fabrication under protective atmosphere and similar mechanical properties. Thus, RF-ICP may be used for deposition of very dense coatings with microstructure and hardness comparable to compacted materials prepared by SPS.
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Kompletní charakterizace žárově stříkaného povlaku na bázi keramiky na hořčíkové slitině AZ91
Plevová, Kateřina ; Doskočil, Leoš (oponent) ; Wasserbauer, Jaromír (vedoucí práce)
Diplomová práce je zaměřena na studium žárově stříkaného povlaku tvořeného vazebnou vrstvou slitiny NiCrAlY a vrstvou částečně stabilizovaného oxidu zirkoničitého (8YSZ) na hořčíkové slitině AZ91. Teoretická část se zabývá strukturou slitiny AZ91, NiCrAlY a částečně stabilizovaného oxidu zirkoničitého. Dále jsou zde shrnuty metody žárových nástřiků a funkce a vlastnosti povlaků tvořících tepelnou bariéru. Experimentální část se zabývá charakterizací žárově stříkaného povlaku a slitiny AZ91 z hlediska prvkového, strukturního a fázového složení. K charakterizaci byla využita optická a elektronová mikroskopie, EDS a XRD analýza. Elektrochemické vlastnosti byly zkoumány v 3,5% roztoku chloridu sodného pomocí potenciodynamické polarizace. Mechanické vlastnosti (tvrdost, koeficient tření) substrátu a povlaku byly měřeny pomocí tvrdoměru a tribologických zkoušek.
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Modification of coating-substrate interface character of thermally sprayed coatings using electron beam technology
Mareš, Jiří ; Moravčík, Igor (oponent) ; Čížek, Jan (vedoucí práce)
This thesis is focused on a modification of the coating-substrate interface of NiCrAlY bond-coats deposited by water stabilized plasma technology on S235JRC+C steel substrates. Electron beam remelting was chosen as the technology used for the modification and two different modifications were investigated. Attempt has been made to determine the effect of remelting on the adhesive strength of the coatings. Further analysis of the microstructure, phase and chemical composition and microhardness were carried out in the state prior and after the modification. During the study it was found that change in phase composition occurs after the deposition as well as after the electron beam modification. It was also found that the electron beam modification caused melting of oxides in the coating original microstructure and resulted in resolidification of these oxides on the surface of the modified layer. Further it was found that electron beam modification resulted in decreased microhardness of the coatings due to oxide removal from the microstructure and coating substrate material mixing. Adhesive strength of the coatings in as-sprayed condition was quantified, however in the case of electron beam modified coatings the adhesive strength could not be fully quantified due to premature failure at the coating adhesive agent interface during adhesion testing.
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