Národní úložiště šedé literatury Nalezeno 4 záznamů.  Hledání trvalo 0.01 vteřin. 
Optoelectrical characterization of well oriented n-type zno nanorod arrays on p-type GaN templates
Yatskiv, Roman ; Grym, Jan ; Schenk, Antonín ; Vaniš, Jan ; Roesel, David ; Chlupová, Šárka
A heterojunction formed between a single n-type ZnO nanorod and p-type GaN template was successfully prepared by low cost chemical bath deposition technique. Periodic circular patterns were fabricated by focused ion beam etching through poly(methyl methacrylate) mask to control the size, position, and periodicity of the ZnO nanorods. A possible growth mechanism is introduced to explain the growth process of the nanorods. Optical and electrical properties of the heterojunctions were investigated by low temperature photoluminescence spectroscopy and by the measurement of current-voltage (I-V) characteristics. The I-V characteristics were measured by directly contacting single ZnO nanorods with the conductive atomic force microscopy tip. The diode-like rectifying behavior was observed with a turn-on voltage of 2.3 V and the reverse breakdown voltage was 5 V
Electrical properties of nanoscale heterojunctions formed between GaN and ZnO nanorods
Tiagulskyi, Stanislav ; Yatskiv, Roman ; Grym, Jan ; Schenk, Antonín ; Roesel, David ; Vaniš, Jan ; Hamplová, Marie
Vertical periodic arrays of ZnO nanorods are prepared by hydrothermal growth on GaN templates patterned by focused ion beam. Electro-physical properties of a single vertically-oriented ZnO nanorod are investigated by measuring the current-voltage characteristics using a nanoprobe in a scanning electron microscope. This technique enables to observe the surface morphology of ZnO nanorods simultaneously with their electrical characterization in vacuum. The vacuum chamber rejects the impact of gas adsorption and light irradiation, which both affect the properties of ZnO nanorods. Moreover, mechanical damage and strain induced during the nanorod transfer are eliminated. Nonlinear current-voltage characteristics under the forward bias are explained by the tunneling-recombination process and by the space charge limited current. The high reverse bias current in the p-n heterojunction is attributed to direct tunneling via a narrow tunnel barrier
Influence of H2O2 treatment on morphological and photoluminescence properties of hydrothermally grown ZnO nanorods
Yatskiv, Roman ; Grym, Jan
We report photoluminescence properties of hydrothermally grown ZnO nanorods (NRs) before and after hydrogen peroxide (H2O2) treatment. The H2O2 treatment introduces oxygen related defects and thus enhances chemisorption processes in ZnO NRs. These effects amplify interactions between the gas species and adsorbed oxygen and thus can influence sensing properties of ZnO NRs
Monolayers of platinum nanoparticles prepared by dip-coating
Černohorský, Ondřej ; Grym, Jan ; Yatskiv, Roman ; Pham, V.H. ; Hudry, D. ; Dickerson, J.H.
Platinum is a transition metal known for its catalytic properties, which are further enhanced when employed in a nanoparticle form. We have recently shown that a monolayer of Pt nanoparticles deposited on semiconductor substrates forms high quality Schottky diodes, which were used in sensitive hydrogen sensors with a detection limit of 1 ppm of H-2 in N-2. Preparation of ordered monolayers of Pt nanoparticles is essential for the understanding of the behaviour of such an interface. To obtain a hexagonal closed-packed nanoparticle array, we prepared Pt nanoparticles stabilized by oleylamine and oleic acid with a narrow size distribution and uniform shapes. A monolayer prepared by dip-coating of Si substrate in the suspension containing Pt nanoparticles showed hexagonal arrangement within separate domains with the surface coverage up to 90%. The increase of the surface coverage with increasing withdrawal speed of the dip-coating process was observed