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Properties of the perspective ferroelectric materials
Krejčí, Josef ; Frk, Martin (referee) ; Rozsívalová, Zdenka (advisor)
This thesis studies the properties and the applications of prospective ferroelectric materials which are used in electrical engineering and electronic industry. Further are physically explained and mathematically described the basic principles running in their structure. The practical part is aimed to build a workplace for measuring the components of the complex permittivity in the frequency and temperature area, controlled by the programmed measurement and service application using the Agilent VEE Pro 8.0 and MS Excel. The functionality of the workplace was verified on the selected material samples by measurement and evaluation of selected properties. For this issue was created electronic text, which can be used as a guide for laboratory exercises and it is an integral part of this work.
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Dielectric Properties of Thermoplastic Materials with Ground Mica
Fiala, Ivo ; Havlíček, Svatopluk (referee) ; Polsterová, Helena (advisor)
The subject of this thesis are composite materials, measuring of their dielectric qualities, particularly of the polyamide and the polyamide filled with various weight percentage of the ground mica. The essential intent of the thesis is to determine the measuring methodology and respective measurement of the basic dielectrical quantities of materials, as are loss factor and the complex permitivity components. The measuring should be done for various temperature and humidity combinations. The thesic contains the physical explanation of measured dependences.
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Dielectric Relaxation Spectroscopy of Composite Systems
Holcman, Vladimír ; Liedermann, Karel (advisor)
The subject of this doctoral thesis is the study of dielectric properties of a binary composite made up of a polymer matrix and metallic filler. Properties of such composites have been extensively examined in the past and they turned out to depend on temperature, frequency and in particular on filler concentration. The objective of this work was first to experimentally establish and second to describe quantitatively the effect of the size of metallic particles on the properties of the composite concerned, yet at the same filler concentration. This study was carried out on the model system ethylene-vinylacetate copolymer – nickel. The acquisition of experimental results required extensive measurements in a wide frequency and temperature interval, as well as a manufacture and preparation of a large set of samples with different concentrations and Ni filler sizes. Measurements were in part carried out at the Centre for Electronic Correlations and Magnetism, Institute of Experimental Physics V of the University of Augsburg (Germany) and, after the installation of a new cryogenic system, at the Department of Physics at FEEC, BUT Brno. Measurements were performed on a number of meters (Alpha-Analyzer of Novocontrol, HP4284A and HP4285A of Hewlett Packard and E4991A of Agilent) in the frequency range 1 Hz – 1 MHz and in the temperature interval 10 K – 300 K. The nickel concentration in systems studied varied from 0 % to 75 % and nickel particles were of a spherical shape with diameters between 35 and 115 m. The measurement results have shown that in the above frequency and temperature window just a single relaxation and a single conductivity mechanism occur. It was also proved that the frequency dependence of complex permittivity is for different Ni particle sizes at the same concentration different. These results have been quantified and a simple mathematical formula based on the Lichtenecker mixture rule has been proposed for their description. The physical origin of the effect of particle size at the same total nickel concentration is sought in different surface areas of internal interfaces between nickel and polymer in the composite
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Analysis of degradation mechanisms oligobutadienes
Baťa, David ; Rozsívalová, Zdenka (referee) ; Frk, Martin (advisor)
This work deals with the studies of liquid oligobutadiens properties in AC electric field by dielectric relaxation spectroscopy method. The current issue in the diagnosis of oligomeric and polymeric materials during the activity of various degradation factors and options of their alleviation and suppression was studied. The existing apparatus is modified for monitoring possibilities of polymeric materials during the action of various degradation and operational factors. Effect of climatic factors are experimentally investigated, especially UV radiation and temperature on the course of the frequency dependence of complex permittivity components with respect to the different composition and length of the polymer chain.
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Free space method for measurement of complex permittivity
Nekovář, Jiří ; Hertl, Ivo (referee) ; Láčík, Jaroslav (advisor)
The aim of this thesis is the development of the workplace for the complex permittivity measurement by free space method. At the beginning of this thesis, the method is described. Further attention is focused on the discussions concerning electromagnetic properties of materials, comparison of the methods used for complex permittivity measurement, interactions of planar electromagnetic wave with planar infinite dielectric slab of general environment and description of radiation patterns of microwave antennas. In the rest of the thesis, the measuring workplace for the free space method is designed and fabricated. A pyramidal horn antenna is selected as a radiator. The antenna is designed with coax to waveguide transition in CST Microwave Studio, and than fabricated in two samples and measured. Finally, the fabricated measuring workplace is exploited for the complex permittivity measurement.
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Properties of liquids based on organic esters
Toulová, Jana ; Rozsívalová, Zdenka (referee) ; Frk, Martin (advisor)
This master's thesis deals with the electrical insulation fluids used in electronics industry. The analysis of the current state of research and innovations in modern, biodegradable fluids in terms of their use as diagnostics. It is described by the physical nature of polarization and conductivity mechanisms, which are applied in liquids. It was compiled automated workstation for monitoring components of the complex permittivity over a wide temperature range. In the experimental part we analyzed the behavior of liquids selected alternative based on natural esters when exposed to an alternating electric field at various temperatures. Evaluated results are compared with values for conventional mineral oil.
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Study of alternative electroinsulating liquids properties
Bannert, Tomáš ; Hylský, Josef (referee) ; Frk, Martin (advisor)
This bachelor´s thesis is dealing with the study of alternative electrical insulating properties of the materials used in the electronics industry, particularly liquids based on natural esters and especially their constituents in the form of higher fatty acids and esters. The work is divided into theoretical and practical part. The theoretical part deals with the characterization of vegetable oils, their constituents and mineral oils, their comparison in terms of electrical and non-electrical properties and current state of the use of vegetable oils and their constituents in the electronics industry. Further it’s dealing with analysis of diagnostic methods for these characteristics. In the experimental part were analyzed electrical and non-electrical properties of selected samples of vegetable oils, their constituents and mineral oils such as the density, the dynamic viscosity and the complex permittivity and its parts as relative permittivity and loss number. Evaluations of the results of each group are compared with each other.
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Influence of terminal groups of oligobutadiene on dielectric spectra
Vilhelm, Ondřej ; Rozsívalová, Zdenka (referee) ; Frk, Martin (advisor)
The bachelor works discourses about atributes of KRASOL LB oligobutadiens by Sartomer industries and KRASOL LB’s final groups. The research proceed by dielectric sweep spectroscopy using electrode technology Agilent 16452A that is used for gauge of transtition capacity and dissipation factor, by which we are able to enumerate both relative permittivity [‘] and figure of loss [“]. Every gauge depends on frequency and temperature.
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