|
|
Fabrication and characterization of atomically thin layers
Tesař, Jan ; Kunc, Jan (referee) ; Procházka, Pavel (advisor)
Tato práce se zabývá oblastí dvourozměrných materiálů, jejich přípravou a analýzou. Pravděpodobně nejznámějším zástupcem dvourozměrných materiálů je grafen. Tento 2D allotrop uhlíku, někdy nazývaný „otec 2D materiálů“, v sobě spojuje neobyčejnou kombinaci elektrických, tepelných a mechanických vlastností. Grafen získal mnoho pozornosti a byl také připraven mnoha metodami. Jedna z těchto metod však stále vyniká nad ostatními kvalitou produkovaného grafenu. Mechanická exfoliace je ve srovnání s jinými technikami velmi jednoduchá, takto připravený grafen je však nejkvalitnější. Práce je také zaměřena na optimalizaci procesu tvorby heterostruktur složených z vrstev grafenu a hBN. Dle prezentovaného postupu bylo připraveno několik van der Waalsových heterostruktur, které byly analyzovány Ramanovskou spektroskopií, mikroskopií atomových sil a nízkoenergiovou elektronovou mikroskopií. Měření pohyblivosti nosičů náboje bylo provedeno v GFET uspořádání. Získané hodnoty pohyblivosti prokázaly vynikající transportní vlastnosti exfoliovaného grafenu v porovnání s grafenem připraveným jinými metodami. V práci popsaný proces přípravy je tedy vhodný pro výrobu kvalitních heterostruktur.
|
|
|
Origin and evolution of silcretes
Kohoutová, Iveta ; Zachariáš, Jiří (advisor) ; Adamovič, Jiří (referee)
Summary: Silcretes are rocks with high content of SiO2 (usually more than 90 wt. %) formed by mobilization of SiO2 during weathering processes. Silcretes formed near the Earth's surface by soil weathering in warm and humid climate are termed as pedogenic silcretes. Another type of silcrete is groundwater silcrete, whose origin is usually associated with the groundwater table and depths of 5-50 m below the surface and arid to semi-arid climate. The third type of silcretes is associated with evaporites. Its genesis is complicated; as well it is difficult to date this silicification. There are four types of silcrete textures: GS-, F-, M-, C- textures; the most common is the F-texture. In the Czech Republic silcretes are more known under the term "sluňáky" or "quartzite". Indeed, in every country where they occur, have their own specific name. Silcretes are essentially composed of SiO2, minor constituents represent heavy minerals and/or feldspar. Cement is mostly α-quartz, chalcedony and opal. Average thickness of silcretes is 1-3 m, rarely 5 meters. Main source of SiO2 is chemical weathering of silicate minerals or quartz dust grains carried by wind and deposited on natural barriers, like blades of grass. There are two models of silcrete formation: lateral and vertical transport model SiO2. Sedimentary...
|
|
|
Structure and magnetism of transition metal-based nanoparticles
Mantlíková, Alice
The aim of the work is characterization of structure and magnetic properties of various CoFe2O4/SiO2 nanocomposites. Emphasis was put on the corelation of the magnetic properties with particle size (samples with different annealing temperature) and with strenght of the interparticle interactions (samples with different Fe/Si ratio or without silica matrix). Structure properties of all samples were determinated by powder x-ray diffraction, scanning and transmission electron microscopy. Magnetic properties were determinated by standard (temperature dependence of magnetization, magnetization isotherms) and advanced (a.c. susceptibility, memory effects) magnetic measurements. A sharp increase of the values of blocking temperature and coercivity with increase of strenght of the interparticle interactions and with increase of particle size was observed. Particle size determines the maximum value of coercivity and blocking temperature and strengh of the interparticle interactions shift this values in the interval determined by particle size.
|
|
|
Design, fabrication and testing of graphene biosensors
Tripský, Andrej ; Gablech, Imrich (referee) ; Bartošík, Miroslav (advisor)
Pokrok ve vývoji nanotechnologií nám poskytuje dobrou příležitost k vývoji nových špičkových zařízení. Tato práce si klade za cíl vyrobit, popsat a změřit grafenové pH senzory na dvou různých substrátech - polymeru parylenu C a SiO2. Tento pH senzor je prvním krokem ve vývoji nositelné náplasti monitorující stav kůže a možné infekce. Grafen je 2D materiál na bázi uhlíku se zajímavými vlastnosti a nadějnými aplikacemi. Úspěšně jsme provedli dva různé experimenty sloužící k charakterizaci grafenových senzorů a jejich odezvu na různé hodnoty pH. V prvním experimentu jsme použili horní elektrolytické hradlo k určení bodu neutrality (Diracův bod). Druhý experiment popsal změnu rezistence grafenu jako funkce pH. Dále jsme také funkcionalizovali grafen polyanilinem, abychom zlepšili jeho vlastnosti. Prokázali jsme citlivost grafenových senzorů na pH pro oba substráty a objevili jsme několik výzev jako potřebu kontroly iontové síly, experimentů samotných a destrukce grafenu.
|
|
|
Fabrication and characterization of atomically thin layers
Tesař, Jan ; Kunc, Jan (referee) ; Procházka, Pavel (advisor)
Tato práce se zabývá oblastí dvourozměrných materiálů, jejich přípravou a analýzou. Pravděpodobně nejznámějším zástupcem dvourozměrných materiálů je grafen. Tento 2D allotrop uhlíku, někdy nazývaný „otec 2D materiálů“, v sobě spojuje neobyčejnou kombinaci elektrických, tepelných a mechanických vlastností. Grafen získal mnoho pozornosti a byl také připraven mnoha metodami. Jedna z těchto metod však stále vyniká nad ostatními kvalitou produkovaného grafenu. Mechanická exfoliace je ve srovnání s jinými technikami velmi jednoduchá, takto připravený grafen je však nejkvalitnější. Práce je také zaměřena na optimalizaci procesu tvorby heterostruktur složených z vrstev grafenu a hBN. Dle prezentovaného postupu bylo připraveno několik van der Waalsových heterostruktur, které byly analyzovány Ramanovskou spektroskopií, mikroskopií atomových sil a nízkoenergiovou elektronovou mikroskopií. Měření pohyblivosti nosičů náboje bylo provedeno v GFET uspořádání. Získané hodnoty pohyblivosti prokázaly vynikající transportní vlastnosti exfoliovaného grafenu v porovnání s grafenem připraveným jinými metodami. V práci popsaný proces přípravy je tedy vhodný pro výrobu kvalitních heterostruktur.
|
|
|
Morphology study of ultra thin layers by XPS analysis of multiple peaks of a single element
Pokorný, David ; Šik, Ondřej (referee) ; Polčák, Josef (advisor)
This diploma thesis deals with methodology of thin film thickness determination using X-ray radiation of silver anode which provides radiation with energy of 2984,3 eV. This energy is twice as high as the standard aluminium radiation which allows a measurement of new photoelectron lines with higher bonding energy and it also provides thanks to the higher photoelectron energy greater information depth. In order to get the right results it was necessary to calibrate the spectrometer Kratos Axis Supra in the silver anode mode first and found out the form of the transmission function. The determination of the thickness of the thin layer was demonstrated by the comparation of the ratio of different photoelectron lines intensities with the theoretical model. For that purpose was specifically used the Si 1s and Si 2p peak bound in the substrate in the Si-Si bonding or in the thin oxid layer in the Si-O bonding. The results show that for thin SiO2/Si film thickness determination is the best to use the intensity ratio of only one photoelectron line. A silver anode however provides greater information depth.
|
|
|
Structure and magnetism of transition metal-based nanoparticles
Mantlíková, Alice
The aim of the work is characterization of structure and magnetic properties of various CoFe2O4/SiO2 nanocomposites. Emphasis was put on the corelation of the magnetic properties with particle size (samples with different annealing temperature) and with strenght of the interparticle interactions (samples with different Fe/Si ratio or without silica matrix). Structure properties of all samples were determinated by powder x-ray diffraction, scanning and transmission electron microscopy. Magnetic properties were determinated by standard (temperature dependence of magnetization, magnetization isotherms) and advanced (a.c. susceptibility, memory effects) magnetic measurements. A sharp increase of the values of blocking temperature and coercivity with increase of strenght of the interparticle interactions and with increase of particle size was observed. Particle size determines the maximum value of coercivity and blocking temperature and strengh of the interparticle interactions shift this values in the interval determined by particle size.
|
|
|
SiO2 etching by Si deposition
Pokorný, David ; Bábor, Petr (referee) ; Polčák, Josef (advisor)
This bachelor thesis deals with one of the most interesting reactions taking place in the solid phase in UHV conditions and that is decomposition of SiO2 according to the equation Si + SiO2 = 2SiO. It was used the previously untested procedure - providing Si atoms not from substrate, but by direct deposition on the surface of the oxide. As a source of silicon atoms was used effusion cell. Deposition of silicon on SiO2 substrate was used at room temperature and at elevated temperature to clarify the principle of this reaction. The activation energy and temperature dependence of the reaction rate was determined. It was also verified the possibility of etching SiO2 by Si deposition in UHV conditions. The prepared samples were examined by x-ray photoelectron spectroscopy and atomic force microscopy.
|
|
|
Origin and evolution of silcretes
Kohoutová, Iveta ; Zachariáš, Jiří (advisor) ; Adamovič, Jiří (referee)
Summary: Silcretes are rocks with high content of SiO2 (usually more than 90 wt. %) formed by mobilization of SiO2 during weathering processes. Silcretes formed near the Earth's surface by soil weathering in warm and humid climate are termed as pedogenic silcretes. Another type of silcrete is groundwater silcrete, whose origin is usually associated with the groundwater table and depths of 5-50 m below the surface and arid to semi-arid climate. The third type of silcretes is associated with evaporites. Its genesis is complicated; as well it is difficult to date this silicification. There are four types of silcrete textures: GS-, F-, M-, C- textures; the most common is the F-texture. In the Czech Republic silcretes are more known under the term "sluňáky" or "quartzite". Indeed, in every country where they occur, have their own specific name. Silcretes are essentially composed of SiO2, minor constituents represent heavy minerals and/or feldspar. Cement is mostly α-quartz, chalcedony and opal. Average thickness of silcretes is 1-3 m, rarely 5 meters. Main source of SiO2 is chemical weathering of silicate minerals or quartz dust grains carried by wind and deposited on natural barriers, like blades of grass. There are two models of silcrete formation: lateral and vertical transport model SiO2. Sedimentary...
|
|
|
Structure and magnetism of transition metal-based nanoparticles
Mantlíková, Alice ; Kalbáčová Vejpravová, Jana (advisor) ; Prchal, Jiří (referee)
The aim of the work is characterization of structure and magnetic properties of various CoFe2O4/SiO2 nanocomposites. Emphasis was put on the corelation of the magnetic properties with particle size (samples with different annealing temperature) and with strenght of the interparticle interactions (samples with different Fe/Si ratio or without silica matrix). Structure properties of all samples were determinated by powder x-ray diffraction, scanning and transmission electron microscopy. Magnetic properties were determinated by standard (temperature dependence of magnetization, magnetization isotherms) and advanced (a.c. susceptibility, memory effects) magnetic measurements. A sharp increase of the values of blocking temperature and coercivity with increase of strenght of the interparticle interactions and with increase of particle size was observed. Particle size determines the maximum value of coercivity and blocking temperature and strengh of the interparticle interactions shift this values in the interval determined by particle size.
|
guest ::
