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Preparation of Thin Films by Electrochemical Methods
Kaválek, Ondřej ; Studničková, Marie (referee) ; Janderka, Pavel (referee) ; Sedlaříková, Marie (advisor)
The doctoral theses deal with electrochemical deposition of lead, tin, silicon and germanium from aprotic electrolytes in anhydrous inert atmosphere. Deposited layers are studied from the perspective of their surface and of electrochemical characteristics.
Optimal layout proposal of technological workplaces and storage in a mechanical engineering company
Janderka, Pavel ; Dvořák, Milan (referee) ; Štroner, Marek (advisor)
The thesis presents a proposal of the arrangement of technological workplaces and warehouse in TIRAD s r.o. Analysis of the current situation revealed shortcomings in the current location of workplaces. Based on these findings and capacity calculations, two possible solutions have been developed. The first solution was to optimize existing production. The second solution, which was subsequently assessed as more appropriate, involves relocating production to a new production hall. This hall has a larger total production area where we can choose the machine layout to ensure the ideal material flow. Larger areas also guarantee the future development and expansion of the fleet. Thanks to a suitable layout, the transport distances have been reduced and thus the handling times have been reduced to less than half of the current state, resulting in both time and money savings.
Nanofibrous Separators for Lithium-Ion Batteries
Pléha, David ; Míka, Martin (referee) ; Janderka,, Pavel (referee) ; Novák, Vítězslav (advisor)
Nanofibrous separators use in lithium-ion batteries brings many advantages. In contrast to contemporary used commercial separators, nanofibrous ones exhibit higher temperature resistance,ionic conductivity and higher electrolyte uptake. Better ionic conductivity is ensured by porous structure and large specific surface. Fibers creates channels for the ionic species motion. Amorphous texture of nanofibers allows quick lithium ionic species motion within the polymeric matrix of separator. Furthermore, these separators exhibit higher volume of uptaken electrolyte. Further advantage of electrospinned nanofibrous separators are both high porosity and chemical stability.
Preparation Techniques and Characterization of Electrodes with Nanostructured Surface
Hrdý, Radim ; Trnková, Libuše (referee) ; Janderka,, Pavel (referee) ; Hubálek, Jaromír (advisor)
Nowadays, nanostructures fixed on solid substrates and colloidal nanoparticles permeate through all areas of human life, in area of sensors and detection as well. This dissertation thesis deals with the fabrication of nanostructures on the surface of planar electrodes via self-ordered nanoporous template of aluminum trioxide. The nanofabrication, as one of many possible techniques, is used to increase the active surface area of electrodes by creating unique surface types with specific properties. These electrodes are very perspective in the applications, such as biomolecules electrochemical detection and measurement. The transformation of aluminum layer into non-conductive nanoporous template in the process of anodic oxidation is a fundamental technique employed to obtain the array of nanostructures in this thesis. The fabrication of high quality nanoporous membranes with narrow pore size distribution on various types of metallic multilayers is one of the key experimental parts in this work. Several problems associated with the production of the thin-film systems, including the dissolving the barrier oxide layer, are discussed and solved. Another part of this work deals with the use of nanoporous membrane as a template for the production of metallic nanostructures via electrochemical metal ions deposition directly into the pores. The obtained nanostructures as nanowires, nanorods or nanodots are characterized by the scanning electron microscopy and energy-dispersive or wavelength X-ray spectroscopy. The electrode surface, modified by gold nanostructures suitable for the detection of biomolecules, has been chosen for the electrochemical measurements, due to the gold biocompatibility. The nanostructured electrodes were characterized by electrochemical impedance spectroscopy and cyclic voltammetry. The effect of nanostructured surface geometrical parameters, including the size of the electrochemically active area, on the results of electrochemical measurements has been observed and compared to flat gold electrodes. Two model biomolecules, namely guanine and glutathione, have been chosen for the study of potential application of these nanostructures in biosensors.
Preparation of Thin Films by Electrochemical Methods
Kaválek, Ondřej ; Studničková, Marie (referee) ; Janderka, Pavel (referee) ; Sedlaříková, Marie (advisor)
The doctoral theses deal with electrochemical deposition of lead, tin, silicon and germanium from aprotic electrolytes in anhydrous inert atmosphere. Deposited layers are studied from the perspective of their surface and of electrochemical characteristics.
Optimal layout proposal of technological workplaces and storage in a mechanical engineering company
Janderka, Pavel ; Dvořák, Milan (referee) ; Štroner, Marek (advisor)
The thesis presents a proposal of the arrangement of technological workplaces and warehouse in TIRAD s r.o. Analysis of the current situation revealed shortcomings in the current location of workplaces. Based on these findings and capacity calculations, two possible solutions have been developed. The first solution was to optimize existing production. The second solution, which was subsequently assessed as more appropriate, involves relocating production to a new production hall. This hall has a larger total production area where we can choose the machine layout to ensure the ideal material flow. Larger areas also guarantee the future development and expansion of the fleet. Thanks to a suitable layout, the transport distances have been reduced and thus the handling times have been reduced to less than half of the current state, resulting in both time and money savings.
Nanofibrous Separators for Lithium-Ion Batteries
Pléha, David ; Míka, Martin (referee) ; Janderka,, Pavel (referee) ; Novák, Vítězslav (advisor)
Nanofibrous separators use in lithium-ion batteries brings many advantages. In contrast to contemporary used commercial separators, nanofibrous ones exhibit higher temperature resistance,ionic conductivity and higher electrolyte uptake. Better ionic conductivity is ensured by porous structure and large specific surface. Fibers creates channels for the ionic species motion. Amorphous texture of nanofibers allows quick lithium ionic species motion within the polymeric matrix of separator. Furthermore, these separators exhibit higher volume of uptaken electrolyte. Further advantage of electrospinned nanofibrous separators are both high porosity and chemical stability.
Preparation of Thin Films by Electrochemical Methods
Kaválek, Ondřej ; Studničková, Marie (referee) ; Janderka, Pavel (referee) ; Sedlaříková, Marie (advisor)
The doctoral theses deal with electrochemical deposition of lead, tin, silicon and germanium from aprotic electrolytes in anhydrous inert atmosphere. Deposited layers are studied from the perspective of their surface and of electrochemical characteristics.
Preparation of Thin Films by Electrochemical Methods
Kaválek, Ondřej ; Studničková, Marie (referee) ; Janderka, Pavel (referee) ; Sedlaříková, Marie (advisor)
The doctoral theses deal with electrochemical deposition of lead, tin, silicon and germanium from aprotic electrolytes in anhydrous inert atmosphere. Deposited layers are studied from the perspective of their surface and of electrochemical characteristics.
Preparation Techniques and Characterization of Electrodes with Nanostructured Surface
Hrdý, Radim ; Trnková, Libuše (referee) ; Janderka,, Pavel (referee) ; Hubálek, Jaromír (advisor)
Nowadays, nanostructures fixed on solid substrates and colloidal nanoparticles permeate through all areas of human life, in area of sensors and detection as well. This dissertation thesis deals with the fabrication of nanostructures on the surface of planar electrodes via self-ordered nanoporous template of aluminum trioxide. The nanofabrication, as one of many possible techniques, is used to increase the active surface area of electrodes by creating unique surface types with specific properties. These electrodes are very perspective in the applications, such as biomolecules electrochemical detection and measurement. The transformation of aluminum layer into non-conductive nanoporous template in the process of anodic oxidation is a fundamental technique employed to obtain the array of nanostructures in this thesis. The fabrication of high quality nanoporous membranes with narrow pore size distribution on various types of metallic multilayers is one of the key experimental parts in this work. Several problems associated with the production of the thin-film systems, including the dissolving the barrier oxide layer, are discussed and solved. Another part of this work deals with the use of nanoporous membrane as a template for the production of metallic nanostructures via electrochemical metal ions deposition directly into the pores. The obtained nanostructures as nanowires, nanorods or nanodots are characterized by the scanning electron microscopy and energy-dispersive or wavelength X-ray spectroscopy. The electrode surface, modified by gold nanostructures suitable for the detection of biomolecules, has been chosen for the electrochemical measurements, due to the gold biocompatibility. The nanostructured electrodes were characterized by electrochemical impedance spectroscopy and cyclic voltammetry. The effect of nanostructured surface geometrical parameters, including the size of the electrochemically active area, on the results of electrochemical measurements has been observed and compared to flat gold electrodes. Two model biomolecules, namely guanine and glutathione, have been chosen for the study of potential application of these nanostructures in biosensors.

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