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Nuclear magnetic resonance of Pb(x)Ba(1-x)(FeNb)0.5O3 perovskites
Adamec, Martin ; Chlan, Vojtěch (advisor) ; Kohout, Jaroslav (referee)
Temperature dependences of nuclear magnetic resonance spectra of isotopes 207 Pb, 137 Ba, and 93 Nb in polycrystalline samples of PbxBa1-x(FeNb)0.5O3, with x = 0 (BFN), 0.5 (PBFN), 1 (PFN) and in Pb(FeNb)0.5O3 single crystal (PFN SC) were acquired. Measured nuclear magnetic resonance spectra are analyzed in this work. The temperature dependence of the spectra show strong broadening with decreasing temperature. Part of the temperature dependences of nuclear magnetic resonance spectra did not comply with expected characteristics. Possible hypotheses for interpretation of such behavior are discussed in the text. Probable arrangement of Fe and Nb cations in PFN and BFN phases is deduced and, based on these differences, the contrast in Néel temperatures of these phases is explained.
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Visualization of selected flows of water and cryogenic helium using tracer particles
Pilcová, Veronika ; Skrbek, Ladislav (advisor) ; Kohout, Jaroslav (referee)
Flow visualization techniques have recently been applied for the investigation of various cryogenic flows of liquid helium. Particle image velocimetry and particle tracking velocimetry techniques, proven in the past as very fruitful in many scientific and industrial areas of research, are being used for the analysis of cryogenic flows. The Joint Low Temperature Laboratory at the Charles University in Prague is the first in Europe to employ flow visualization techniques to investigate liquid helium flows. The approach had to be optimized due to a number of technical and fundamental dificulties, i.e., the optical access to the helium bath and choice of suitable tracer particles. Water experiments at room temperature were performed to prove that the experimental apparatus is well-suited for the low-temperature experiments performed as the main part of the work. The latter focused on thermal counter flow. The results from both, room-temperature experiments and low-temperature experiments are discussed and positively compared with well-known theoretical results.
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Investigation of quantum turbulence using microresonators
Midlik, Šimon ; Schmoranzer, David (advisor) ; Kohout, Jaroslav (referee)
The principal aim of this Thesis is the construction of a cryogenic setup for the investigation of quantum turbulence in superfluid helium (He II) using microresonators and a to perform a study of the transition to turbulence in oscillatory flow of He II in the temperature range from 2.170 K down to 1.293 K. We have designed and constructed a setup consisting of a superconducting vibrating microwire and a so-called fountain pump, and, after initial testing and characterization, used it to probe the instabilities occurring in the flow of He II. Specifically, we were interested in the origin of the instabilities in the flow around the microwire and in the question whether they originate mostly from classical-like flow of the normal component, as is often the case with the well-known tuning forks, or whether they are related to the generation of quantized vortices in the superfluid component of He II. To distinguish between these two types of instabilities, we have derived from the Navier-Stokes equations scaling laws related to drag forces in classical oscillatory flow, which we have applied to the normal component of superfluid helium. This also enabled us to verify the validity of the high-frequency limit of oscillatory flow for the case of the microwire. Finally, we have examined the capability of the...
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Hyperfine interactions in multiferroics containing iron
Kmječ, Tomáš ; Kohout, Jaroslav (advisor)
Multiferroic materials, in which spontaneous orderings (especially magnetic and electrical, in some cases elastic) jointly exist and may mutually interact, are currently in the center of attention in many fields of research due to their high application potential. They are already used in many applications, as in various sensors, microwave filters or electro / magneto- mechanical manipulators and actuators. Nevertheless, many features of microstructure and moment arrangements are not yet fully explained and understood. The presented work is mostly experimental and focuses on the investigation of several promising multiferroic materials: Pb1 − xBax(Fe0.5Nb0.5)O3 (x = 0 - 1) and Pb(Fe0.5Sb0.5)O3 with a perovskite structure and labeled as multiferroics of the I. type according to the Khomsky classification, BaYFeO4, which belongs to the multiferroics of the II. Khomsky class, and LiFePO4, which is a potentially multiferroic substance containing Fe2+ and are used in electric accumulators at present. Mössbauer spectroscopy of the 57 Fe isotope was used as a key experimental method, which can provide new information about the local arrangement in the vicinity of resonantly absorbing nuclei in the investigated substances. Data evaluation and interpretation would not be possible without the using results...
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Study of properties of iron-containing nanoparticles stressing their application potential
Kubíčková, Lenka ; Kohout, Jaroslav (advisor) ; Javorský, Pavel (referee) ; Mašláň, Miroslav (referee)
Magnetic nanoparticles offer a plethora of application possibilities in various fields of human endeavors. The fundamental understanding of their physical properties, related to the constituent magnetic phase, surface termination, and possible coating, synthesis method, size, shape, or even clustering, is crucial for their effective use and optimization for the intended applications. This thesis aims to contextualize original results, concerning especially the structure and magnetic properties, obtained during fundamental research on nanoparticles of selected iron-containing systems and employ these findings in testing the nanoparticles in chosen applications. Iron presents an ideal constituting element due to its low cost, high abundance in the Earth's crust, exploitability, and low toxicity. The selected systems involved in this thesis comprise iron-containing oxides (ferrites, and various polymorphs of iron(III) oxide, including ε-Fe2O3 and doped counterparts), and sulfides (greigite, chalcopyrite), all of which exhibit specific properties such as magnetic or structural transitions. Among the studied applications, the largest attention is devoted to the use of magnetic nanoparticles as contrast agents in magnetic resonance imaging, and the analysis of their efficacy in contrast enhancement -...
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Hyperfine interactions in multiferroics containing iron
Kmječ, Tomáš ; Kohout, Jaroslav (advisor) ; Mašláň, Miroslav (referee) ; Šepelák, Vladimír (referee)
Multiferroic materials, in which spontaneous orderings (especially magnetic and electrical, in some cases elastic) jointly exist and may mutually interact, are currently in the center of attention in many fields of research due to their high application potential. They are already used in many applications, as in various sensors, microwave filters or electro / magneto- mechanical manipulators and actuators. Nevertheless, many features of microstructure and moment arrangements are not yet fully explained and understood. The presented work is mostly experimental and focuses on the investigation of several promising multiferroic materials: Pb1 − xBax(Fe0.5Nb0.5)O3 (x = 0 - 1) and Pb(Fe0.5Sb0.5)O3 with a perovskite structure and labeled as multiferroics of the I. type according to the Khomsky classification, BaYFeO4, which belongs to the multiferroics of the II. Khomsky class, and LiFePO4, which is a potentially multiferroic substance containing Fe2+ and are used in electric accumulators at present. Mössbauer spectroscopy of the 57 Fe isotope was used as a key experimental method, which can provide new information about the local arrangement in the vicinity of resonantly absorbing nuclei in the investigated substances. Data evaluation and interpretation would not be possible without the using results...
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Modification of a laser welding system for welding materials releasing excessive amounts of fumes
Kohout, Jaroslav ; Sigmund, Marian (referee) ; Mrňa, Libor (advisor)
The thesis deals with the implementation of a suction system for laser welding. The specific product is grate used for outdoor drainage. The original GMAW production technology is to be replaced by a laser. During the welding of S235JR steel, a significant development of exhaust gases was observed, which subsequently made the actual process impossible. Practical experiments were performed and evaluated using tensile testing and metallographic cut. Based on the results, the optimal position of the suction nozzle and welding parameters were recommended. The obtained values were re-verified by experiment. Furthermore, a suitable extraction device was proposed and an economic evaluation was performed.
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Relaxivity of magnetic iron oxide nanoparticles containing diamagnetic cations
Kubíčková, Lenka ; Kohout, Jaroslav (advisor)
Magnetic nanoparticles have received extensive attention in the biomedical research, e.g. as prospective contrast agents for T2-weighted magnetic resonance imaging. The ability of a contrast agent to enhance the relaxation rate of 1 H in its vicinity is quantified by relaxivity. The main aim of this thesis is to evaluate the transversal re- laxivity of ε-Fe2−x Alx O3 nanoparticles coated with amorphous silica or citrate - its dependence on external magnetic field, temperature and thickness of silica coating - by means of nuclear magnetic resonance. The aluminium content x = 0.23(1) was determined from XRF, the material was further characterised by XRPD, Möss- bauer spectroscopy, DLS, TEM and magnetic measurements. The size of magnetic cores was ∼ 21 nm, the thickness of silica coating ∼ 6,10,17 and 21 nm. Magne- tization of the ε-Fe2−x Alx O3 nanoparticles increased by ∼ 30 % when compared to ε-Fe2O3. The saturating dependence of relaxivity on external magnetic field and on the linear decrease with increase of thickness of silica coating contravene the theo- retical model of motional averaging regime (MAR); nevertheless, the temperature dependence acquired in 0.47 T and 11.75 T may be explained by MAR. In compari- son to ε-Fe2O3 nanoparticles, the relaxivity of examined samples was higher for par-...
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Spherically symmetrical thermal counterflow of superfluid helium
Novotný, Filip ; Schmoranzer, David (advisor) ; Kohout, Jaroslav (referee)
The principal aim of this Thesis was the investigation of quantum tur- bulence in superfluid helium in a special type of flow, spherically symmetric thermal counterflow. To this end, a new cell was designed and 3D-printed. Measurements of quantum turbulence were realized using the traditional technique of second sound attenuation, focusing both on steady state of tur- bulence and its temporal decay. The measured dependence of the quantized vortex line density L versus the counterflow velocity vns, where the data clearly show that L ∝ v3/2 ns , does not agree with the Vinen equation, which predicts L ∝ v2 ns. On the other hand, the dependence of vortex line density on time t obtained during the decay measurements L ∝ t−1 is paradoxically in close agreement with the Vinen equation. For the future, spherically sym- metrical thermal counterflow thus promises many interesting challenges and will remain an important topic of research. 1
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Optimization of manufacturing process of tubes
Kohout, Jaroslav ; Staněk, Vojtěch (referee) ; Podaný, Kamil (advisor)
Elaborated thesis presents a proposal to increase welding speed in the process of production of stainless steel tubes 1.4301 and 1.4404. Based on analysis of the existing method was evaluated, that performance improvement would be most appropriate by adjusting the welding technology. Four methods have been proposed, describing the principle, andvantages and disadvantages. The most effective and cheapest was the modification of the existing TIG method using two torches, with the possible improvement of using another shielding gas.
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