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Adsorption of natural organic matter (NOM) on granular activated carbon in the treatment of drinking water
Le Duc, Duy ; Mega, Jaroslav (referee) ; Dolejš, Petr (advisor)
In the first part of this thesis the methodic of lab trial was studied, which will be useful for studying adsorption of natural organic matter by activated carbon. As an optimal method of testing adsorption characters jar testing was chosen. Again as an indicator of organic contamination, it was decided to use permanganate chemical oxygen demand (in Czech CHSKMn) will be used. In the second part of this thesis the adsorption characters of eight types of granular activated carbon were studied. Those granular activated carbon came from two world produces, from company NORIT five type of granular activated carbon were tested: NORIT GAC 1020, NORIT PK 1-3, NORIT GAC 1240, NORIT ROW 0.8 SUPRA a TOD NORIT ROX 0.8 and from company Chemviron Carbon three types of granular activated carbon were tested: F100 FE11120A, F400 FE11210A a TL830 FE2028B. Batch kinetic tests of natural organic matter adsorption were conducted with all types of granular activated carbon at first. For description of sorption not only the batch kinetic tests and duration needed for setting equilibrium were observed, but also the process decreasing of concentration of natural organic matters to the value of equilibrium concentration known as adsorption equilibrium was followed.
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Comparison of various modifications of coagulating tests
Vymazalová, Kamila ; Dolejš, Petr (referee) ; Mega, Jaroslav (advisor)
In the theoretical part of diploma thesis is elaboreted literary search relating to problems with using of various modifications of coagulation tests. The experimental part of diploma thesis is focused on comparison of three types of coagulation tests during treatment of model water with increased content of humic matter. Concretly was compared classic jar test, modified jar test and centrifugation test. As a coagulant was used ferric sulphate. The efficiency of treatment was tested under various conditions (temperature, time of fast mixing and intensity of slow mixing). Information capability of results was evalueted on the basis of absorbance by 254 nm and 387 nm, residual concentration of iron and dichromate value. Obtained results were numerically processed and they are presented in the form of tables and graphs.
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Removal of micropolutants in drinking water treatment
Hambálková, Kateřina ; Vávrová, Milada (referee) ; Dolejš, Petr (advisor)
Intrusion of pharmaceuticals into surface and drinking water is nowadays a problem, that is solved all over the world. This diploma thesis is focused on the removal of pharmaceuticals from water by coagulation. The efficiency of two coagulant agents - chitosan and ferric sulphate was compared. For comparison was used adsorption on a granular-activated-carbon. Efficiency of removal was investigated by UV-VIS spectrophotometer and HPLC.
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Monitoring of changes of drinking water quality during accumulation and distribution
Vaňková, Jitka ; Dolejš, Petr (referee) ; Mega, Jaroslav (advisor)
Theoretical part of the diploma thesis purveys information on drinking water and quality requirements, changes of drinking water quality during distribution and accumulation caused by disinfection, chemical processes, corrosion of constructional materials, incrusting solids, biofilms, nitrification of ammonia nitrogen, sediments in pipelines, elution of harmful matter. Attention was given to drinking water quality indicators which are associated with changes in drinking water distribution systems. In experimental part are studied changes of drinking water quality during distribution on the basis of selected drinking water quality indicators. There is specifically chemical oxygen demand, concentration of iron, manganese, ammonia ions, nitrites, nitrates, chloroform and chlorine. For periodical monitoring were selected suitable locality within the framework of Brno distribution system; for illustration were taken water samples from distribution systems of drinking water treatment plants Švařec, Vír, Štítary and Mostiště. For selected methods of analytical determination of above mentioned drinking water quality indicators are presented their characteristics. Obtained information on drinking water quality is mentioned in tabular and graphical form.
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Study of seasonal changes of water quality in Vír reservoir
Navrátilová, Martina ; Dolejš, Petr (referee) ; Chocholáčová, Hana (advisor)
Thesis deals with measuring of chosen indicators of water quality in Vír reservoir (temperature, pH, colour, turbidity, fluorescence of fykocyanin, concentration of chlorofyl-a, pheopigments, microcystin-LR, orthophosphates, nitrates, etc.). Samples were taken from the sampling profiles 10, 30 a 50 metres from absolute level and in the season from May to October was direct in reservoir measured a vertical profile by a multifunction sonde YSI 6600.
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Problems of humic matters as precursor of trihalomethanes (THMs) in water
Jelínková, Zuzana ; Dolejš, Petr (referee) ; Doležalová Weissmannová, Helena (advisor)
The bachelor’s thesis deals with qualities of humic matters, their origins, structures and occurrence in aquatic environment. There are suitable methods for determination of humic substances and processes used for their removing from water. The thesis describes disinfection of water and related origin of trihalomethanes. The aim of the experimental part of the thesis is to coagulate model humic water on the laboratory mixing column including suggestion of optimal dose of selected coagulation agent and comparison of effectivity of floccules separation by membrane filtration and centrifugation. Effectivity of the removal of humic matters was determined by measuring water absorbance at wavelengths 245 nm in a silica cuvette with optical 1 cm trajectory and at 387 nm in a glass cuvette with optical 5 cm trajectory. For evaluation of quality suspension concentration of residual iron of coagulation agent in water was determined.
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Aggregation reactions of chitosan in drinking water treatment
Leskovjanová, Jana ; Mega, Jaroslav (referee) ; Dolejš, Petr (advisor)
The diploma thesis deals with treatment of surface waters containing humic substances. The most often used method of surface water treatment is coagulation with subsequent separation of aggregates. In this study, only perikinetic coagulation phase was studied. It is the phase when aggregates are formed by the Brownian motion only, i.e. without mixing. Separation of the formed aggregates was made by centrifugation. Coagulation tests were made under the laboratory conditions with model humic water. Humic substances were added from a concentrate, which was taken from a natural peatbog. The influence of temperature on the coagulation process was studied, ranging from 5 to 22 °C. Chitosan (natural biopolymer) was used as coagulant. In present, it is not used in Czech water treatment practice yet. No effect of temperature was observed when chitosan was used as coagulant. Influence of temperature was also studied with the use of aluminium and ferrous sulphates, which are used in common praxis as coagulation reagents. Influence of the temperature was observed and is in agreement with previously reported data of pilot-plant experiments by other researchers. Spectroscopic methods were used to evaluate the coagulation efficiency and determine residual concentration of aluminium and ferrous coagulant. Chemical oxygen demand (COD) was determined for optimal doses. At first, coagulation tests were made under the laboratory temperature. This tests determined optimal aggregation time and optimal coagulant dose under low temperature. Afterwards, all coagulants used were compared at given temperatures.
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