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Optimization and characterization of dimethacrylate-based resin
Baradzina, Lizaveta ; Petruš, Josef (referee) ; Poláček, Petr (advisor)
This diploma thesis was focused on the optimization and characterization of resins based on dimethacrylate monomers. The polymerization process was also monitored depending on the type and molar ratio of monomers used, on the content of barium glass filler and the presence of glass fibers. Changes in the viscoelastic properties of materials during polymerization were also investigated. The following methods were used to characterize the prepared dimethacrylate resins and composite materials based on them: viscosimetry, differential scanning photocalorimetry (DPC), photoreology, dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA). The dynamic viscosity of the prepared dimethacrylate matrices was determined by viscometry. Based on the results of DPC analysis of the tested resins, the dependences of heat flow on time, conversion on time and polymerization rate on conversion were created. With photoreology, the course of curing, the onset of the gelation point and changes in the viscoelastic properties of the systems were monitored. The viscoelastic properties of the cured composite materials were then determined by DMA in the three-point arrangement. TGA was performed to accurately determine the composition of the tested samples
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Complex diagnostics static structural condition of the building
Voltr, Vojtěch ; Rozsypalová, Iva (referee) ; Schmid, Pavel (advisor)
This diploma thesis deals with the problems of revitalization of historical objects. The theoretical part describes the technologies for static reinforcing and rehabilitation of vertical and horizontal bearing structures for a purpose of increasing the general stiffness of the object. As the practical part a static design project is made for reinforcing of the bearing walls and also for the general reconstruction of the slab. The slab is designed as the composite timber-concrete structure. The design project of the slab is economically compared with other variants. The designs are made for an existing object of the old restaurant in the village Velichovky.
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Optimization and characterization of dimethacrylate-based resin
Baradzina, Lizaveta ; Petruš, Josef (referee) ; Poláček, Petr (advisor)
This diploma thesis was focused on the optimization and characterization of resins based on dimethacrylate monomers. The polymerization process was also monitored depending on the type and molar ratio of monomers used, on the content of barium glass filler and the presence of glass fibers. Changes in the viscoelastic properties of materials during polymerization were also investigated. The following methods were used to characterize the prepared dimethacrylate resins and composite materials based on them: viscosimetry, differential scanning photocalorimetry (DPC), photoreology, dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA). The dynamic viscosity of the prepared dimethacrylate matrices was determined by viscometry. Based on the results of DPC analysis of the tested resins, the dependences of heat flow on time, conversion on time and polymerization rate on conversion were created. With photoreology, the course of curing, the onset of the gelation point and changes in the viscoelastic properties of the systems were monitored. The viscoelastic properties of the cured composite materials were then determined by DMA in the three-point arrangement. TGA was performed to accurately determine the composition of the tested samples
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Complex diagnostics static structural condition of the building
Voltr, Vojtěch ; Rozsypalová, Iva (referee) ; Schmid, Pavel (advisor)
This diploma thesis deals with the problems of revitalization of historical objects. The theoretical part describes the technologies for static reinforcing and rehabilitation of vertical and horizontal bearing structures for a purpose of increasing the general stiffness of the object. As the practical part a static design project is made for reinforcing of the bearing walls and also for the general reconstruction of the slab. The slab is designed as the composite timber-concrete structure. The design project of the slab is economically compared with other variants. The designs are made for an existing object of the old restaurant in the village Velichovky.
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Breathing Apparatus equipment in the Units of the Fire Rescue Service of the South Bohemia Region
SOKOL, Karel
The Fire Rescue Service of the Czech Republic is one of the fundamental components of the Integrated Rescue System. Its overall development and modern equipment allows for a very effective way to provide assistance in all types of emergencies. The breathing apparatus equipment is one of the many parts of the common personal protective equipment that allows firefighters to remain within even a stifling environment. The aim of this thesis was to make a full analysis of the numbers and the range of age in use of these kinds of breathing apparatuses and cylinders, which belong to the units of the equipment in the Fire Rescue Service of the South Bohemia Region. Furthermore, I have made a comparison between the two basic types of air breathing apparatuses that are being used, in terms of the protection period, which have been provided to the users (carriers). The participants of this inquiry were members of the FRS of the South Bohemia Region, which include the separation of chemical and technical services into the various local departments. I have received the data from twenty different fire stations in total. In the questionnaire which was given, I collected the data from the respondents, according to their age and added the number of different types of breathing apparatus and cylinders and period or time of use to this study. The data was collected during February and March 2010. Hypothesis 1: the number of pieces of the breathing apparatus equipment in the South Bohemia Fire Rescue units is sufficient; this was confirmed. The result has been compared with the numerical data collected from the indicated positions in the current legislation set to 1.7 times of the number of the members serving in one inning. Hypothesis 2: that these breathing apparatuses meet the requirements of all of the current legislation; this has not been confirmed. The result shows a comparison of the technical parameters of the instruments and technical conditions, as reported by the Interior Ministry decree No. 255/1999 Coll. as amended, regarding the technical conditions kind of fire. The results will be used to establish the financial balance sheet and the planned purchases of the pressurized breathing apparatus equipment and the used variations of the composite cylinders.
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