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Reducing emissions of SO2 in the flue gas from the fluidized bed boiler
Tesař, Jan ; Jecha, David (referee) ; Brummer, Vladimír (advisor)
Aim of this thesis is to design a technology of a flue gas desulphurization of fluidized bed boiler. Currently, the state of technology is not able to provide flue gas desulphurisation to required level. For this reason it is necessary to build additional device for the desulphurisation. Theoretical part of the thesis deals with the emission limits of sulphur dioxide, available methods of desulphurization and sorbents suitable for the desulfurization. In practical part conditioned dry sorption method is chosen for the specified source, technological and structural design for suggested desulphurization technology including design of all device is proposed. The thesis also includes a technology design and a 3D model.
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Absorption Cleaning of Flue Gases Arising from the Incineration of Wastes
Jecha, David ; Klemeš,, Jiří (referee) ; Žaloudík, Petr (referee) ; Bébar, Ladislav (advisor)
This doctoral thesis deals with potentials of methods for cleaning of flue gas from pollutants such as acidic components. Wet method of flue gas cleaning is analysed in detail with special focus on elimination of sulphur dioxide (SO2). Introduction presents advantages and disadvantages of thermal processing of waste and production of undesired pollutants. Following parts comprise facts about main pollutants produced from incineration. Legislation providing for emission of gaseous pollutants from incinerators is also given. Chapter concerning methods of pollutants elimination is mostly focused on absorption (wet and/or semidry scrubber) and adsorption methods. Several up-to-date technological procedures are mentioned; they have a multifunctional effect such as elimination of acidic components, heavy metals, polychlorinated dibenzo-p-dioxines and dibenzo-furanes from flue gas using single injection of suspense. Elimination of mercury (Hg) is among the technologies for heavy metal elimination which is described in detail. Main part of the thesis is related to experiments at two-stage flue gas cleaning equipment. Function of this experimental unit is described along with methods for measurement of individual quantities and detailed description of all the equipment and its components. Experimental measurements carried out at this equipment are explicated and assessed. Along with experimental work, the author has created a simulation model of wet flue gas cleaning in ChemCad programme. Particular operational parameters were tested on this model. This thesis contains results of the measurement which provide background for verification of the mathematical model. Further, the balance of heavy metals conducted on the basis of measurements in waste incinerator is displayed. Main contribution of the thesis may be summed up as follows: Author has designed and constructed experimental equipment for two stage flue gas cleaning. He also formed calculation for pressure drop of O-element prototype equipment and for packing column with FLEXIPAC structured packing. He created data file with measurements at the experimental unit. He determined temperature at outlet of a random device where liquid is injected into stream of hot flue gas. He designed a simulation model which is identical with experimental equipment and which usage enabled comparison of measured and calculated data; it also serves as a basis for industrial applications. Last part deals with creation off heavy metals balance in a case industrial waste incinerator.
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Corrosion of Steel and Aluminium in Chosen Enviroments
Stavinoha, Jakub ; Tulka, Jaromír (referee) ; Molliková, Eva (advisor)
This Master’s thesis is related to corrosion degradation processes on metal surfaces exposed in different environments. The theoretical part is concern with basic principles in electrochemical and atmospheric corrosion. Practical part describes experimentation of corrosion process of aluminium (99,5) and low carbon steel (11321) in two different atmospheric environments. The conclusion of thesis includes evaluations of the results from practical part and comparison with the theoretical part.
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Purification of flue-gas desulfurization
Křesťan, Jan ; Špiláček, Michal (referee) ; Hrnčířová, Michaela (advisor)
The aim of this thesis is theoretical elaboration of flue-gas desulfurization and emission limits of sulphur dioxide. Thesis is divided into three parts. First part is about content of sulphur in fuel, formation of sulphur oxides and their influence on human health and environment. Second part is dedicated to sources of sulphur dioxide, present emission situation in the Czech Republic and emission limits of sulphur dioxide. The third part describes methods how to reduce emissions of sulphur dioxide, especially methods of flue-gas desulfurization. The thesis is based on technical texts, Czech laws about air pollution and data from the Czech hydrometeorological institute.
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The comparison of the European Union Emission Trading Scheme and the Acid Rain Program in USA
Zelená, Vladimíra ; Petrášek, František (advisor) ; Škop, Vladislav (referee)
The thesis focuses on comparison of emission trading of the European Union (European Union Emission Trading Scheme) which trades with carbon dioxide allowances and emission trading of the United States of America (Acid Rain Program) which trade with sulphur dioxide allowances. Despite of using same mechanisms and principles, these systems brought diverse results -- mostly because of different implementation of key parameters. The thesis which concerns with both of these systems is trying to find the major reasons of unsuccessful implementation of the European Union trading and the most important reasons leading to successful performance of the U.S. program.
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