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12M-IMMEDIATE Research Report: Preparation of Pt on Carbon Black Supported Catalysts
Kaluža, Luděk ; Zdražil, Miroslav ; Gulková, Daniela ; Vít, Zdeněk ; Šolcová, Olga ; Soukup, Karel ; Maixnerová, Lucie
The aim of this work was to elucidate on advanced preparation of Pt/C catalysts from TimCal carbon black and H2PtCl6. The attention was directed to residual content of chloride in the prepared catalysts and scale-up to the amount about 1 gram of final product. The textrual properties of the supports and selected catalyst were studied by nitrogen physisorption. The analytical methods such as instrumental neutron activation analysis (INAA), liquid ion chromatography (LC), and titration with silver nitrates were applied for Cl analysis. Electron probe micro analysis (SEM-EDX), hydrogen chemisorption, temperature programed desorption of hydrogen (TPD) and a simplified determination of ignition temperature in air flow were used for Pt/C catalysts characterization.
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Hydrogen or Soot ?: Partial Oxidation of High-Boiling Hydrocarbon Wastes
Lederer, J. ; Hanika, Jiří ; Nečesaný, F. ; Poslední, W. ; Tukač, V. ; Veselý, Václav
This paper is focussed to research of the influence of process parameters of partial oxidation like quality of hydrocarbon raw materials, which differed in their stock properties (especially the boiling point and viscosity), on the composition of output gas (selectivity of the process) and also on the formation extent of soot which can be used as an excellent and valued sorbent CHEZACARB(™) and/or filler in rubber industry, e.g. for automotive tires. The effects of steam flow rate and oxygen to raw material feed rate ratio is discussed as well.
Fulltext: content.csg -  PDF
Plný tet: SKMBT_C22014090110411 - PDF
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Highly Loaded Carbon Black Supported Pt Catalysts for Fuel Cells
Kaluža, Luděk ; Zdražil, Miroslav ; Gulková, Daniela ; Vít, Zdeněk ; Šolcová, Olga ; Soukup, Karel ; Maixnerová, Lucie
The aim of this work was to elucidate on the methods of Pt deposition on carbon black to achieve high loadings of Pt of about 60 wt.% in highly dispersed form. The carbon black supports were characterized by nitrogen physisorption. Platinum was deposited on the supports: from true solutions of H2PtCl6, Pt(C5H7O2)2, Pt(NH3)4(NO3)2, or Pt(NH3)2(NO2)2, and from fine dispersions of Pt(C5H7O2)2, PtO2, Pt(NH3)4(OH)2. Atomic adsorption spectroscopy, AAS, and scanning electron microscopy, SEM, were used for elemental analysis and determination of Pt content. The deposited Pt species were dried, calcined or reduced and were subjected to temperature programmed reduction, TPR. After degassing at increased temperature, the Pt dispersion was determined by hydrogen chemisorption at -60 C.
Fulltext: content.csg - PDF
Plný tet: SKMBT_C22014082908313 - PDF
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Plasma modification of powder materials
ČERNÝ, Pavel
Thesis is focused on plasma modification of materials. The work has the character of a search of available literature, especially the papers presented in impacted journals. The aim is to provide a broader overview of the subject. The first section describes the most commonly modified powdered materials. The second part is focused on the plasma modification, the reasons for its use, capabilities and benefits respectively and disadvantages of these processes. The following sections are devoted to plasma discharges, plasma reactors, aspects of plasma modification and companies engaged in production, or modification of powders. Each chapter is intended to provide an overview of the modified powder materials, processes within the plasma discharges, construction and use of plasma reactors, plasma modification of aspects and the market situation in the context of powdered materials and companies dealing with the plasma modification.
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