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Characterization of ionically active membranes
Kůdela, Vlastimil ; Richau, K. ; Schauer, Jan
It has been shown that liquid junction potentials (LJP) are the cause of a systematic error of hydroxonium ions (protons) static transport numbers in membranes made from sulfonated poly(phenylene oxide) if LJP are calculated from concentration potentials measured by means of KCl filled electrodes. The remedy has been found in the use of wire electrodes of second kind like Ag/AgCl. Theory and results.
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