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Interaction of ultrashort laser pulses with semiconductor nanostructures
Preclíková, Jana ; Malý, Petr (advisor) ; Potůček, Zdeněk (referee) ; Oswald, Jiří (referee)
The thesis is devoted to the optical spectroscopy (photoluminescence, transmission, ultrafast photoluminescence) of nanocrystalline diamond films and silver nanoparticles in titanium dioxide matrix. We studied the influence of the laser irradiation on optical properties of both materials under various conditions. Nanocrystalline diamond exhibits strong subpicosecond and picosecond photoluminescence parameters of which (intensity and decay rate) change with the laser irradiation and ambient air pressure. The effects are accompanied by a change in optical thicknesses of the nanocrystalline diamond films. We assigned the phenomena to light induced adsorption processes which influence the subgap states originating from surface and grainboundaries atoms. We implemented and optimized the preparation technique of the nanocomposite Ag-TiO2films exhibiting the multicolour photochromic effect. The analysis of the initial stages of the photochromic transformation revealed that during the laser irradiation the plasmon frequency of the resonating silver nanoparticles was blue shifted. The photoluminescence spectroscopy confirmed an increase in number of the Ag+ ions during the photochromic transformation. The photoluminescnece of the nanocrystalline TiO2 is due to the two types of radiative transitions: the...
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Interaction of ultrashort laser pulses with semiconductor nanostructures
Preclíková, Jana ; Malý, Petr (advisor) ; Potůček, Zdeněk (referee) ; Oswald, Jiří (referee)
The thesis is devoted to the optical spectroscopy (photoluminescence, transmission, ultrafast photoluminescence) of nanocrystalline diamond films and silver nanoparticles in titanium dioxide matrix. We studied the influence of the laser irradiation on optical properties of both materials under various conditions. Nanocrystalline diamond exhibits strong subpicosecond and picosecond photoluminescence parameters of which (intensity and decay rate) change with the laser irradiation and ambient air pressure. The effects are accompanied by a change in optical thicknesses of the nanocrystalline diamond films. We assigned the phenomena to light induced adsorption processes which influence the subgap states originating from surface and grainboundaries atoms. We implemented and optimized the preparation technique of the nanocomposite Ag-TiO2films exhibiting the multicolour photochromic effect. The analysis of the initial stages of the photochromic transformation revealed that during the laser irradiation the plasmon frequency of the resonating silver nanoparticles was blue shifted. The photoluminescence spectroscopy confirmed an increase in number of the Ag+ ions during the photochromic transformation. The photoluminescnece of the nanocrystalline TiO2 is due to the two types of radiative transitions: the...
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Fotoluminiscence erbiem dopovaných krystalů KTaO.sub.3./sub..
Potůček, Zdeněk ; Bryknar, Z. ; Trepakov, Vladimír
Photoluminescence emission spectra of KTaO3:Er crystals was studied within the wide temperature (12 – 300 K) and spectral (300 – 1200 nm) regions in order to reveal luminescence centers related to Er ions and to elucidate their optical properties. Under excitation with band-gap light at low temperatures, the KTaO3:Er crystals shoved a broad asymmetric emission band peaking near 490 nm at 12 K that belongs to well-known “green” photoluminescence of KTaO3 crystals. Erbium doping was accompanied by appearance of narrow structured emission bands in the vicinity of 550, 660, and 850 nm that were attributed to radiative transitions within Er3+ ions with 4f11 electron configuration.
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