|
|
Dating of radioactive mineral springs of the Krkonoše-Jizera crystalline by 230Th/234U method
Fanta, Martin ; Goliáš, Viktor (advisor) ; Mizera, Jiří (referee)
The isotopes 238 U, 234 U and 230 Th, as members of the uranium-radium decay chain, are fractionated in the environment by changes of geochemical conditions, and they can be used for dating of recent or past geochemical processes in the Quaternary. Samples of water with uranium and of water-activated solids were taken of radioactive mineral water springs at two study sites in the area of Krkonoše-Jizera crystalline complex: Svatý Vojtěch (St. Adalbert) in Horní Malá Úpa, and Bukový Pramen in the Těsný důl valley in Janské Lázně. Uranium was co-precipitated in field conditions with hydroxides of FeIII+ in 50-liter water samples of the radioactive springs. In the lab, uranium and thorium were separated from water precipitates, as well as from solid samples after their chemical decomposition, using chromatographic extraction agent UTEVA. All the three isotopes of interest emit alpha particles, and so their activities were measured by alpha spectrometry and expressed as 234 U/238 U and 230 Th/234 U ratios. As an internal standard, 232 U/228 Th was used. The resulting 234 U/238 U activity ratios of four water samples measured ranged from 1.0747 to 1.423. In twelve samples of solid phases activity ratios 234 U/238 U from 0.861 to 1.129 were determined. The 230 Th/234 U activity ratios form two distinct...
|
|
|
Dating of radioactive mineral springs of the Krkonoše-Jizera crystalline by 230Th/234U method
Fanta, Martin ; Goliáš, Viktor (advisor) ; Mizera, Jiří (referee)
The isotopes 238 U, 234 U and 230 Th, as members of the uranium-radium decay chain, are fractionated in the environment by changes of geochemical conditions, and they can be used for dating of recent or past geochemical processes in the Quaternary. Samples of water with uranium and of water-activated solids were taken of radioactive mineral water springs at two study sites in the area of Krkonoše-Jizera crystalline complex: Svatý Vojtěch (St. Adalbert) in Horní Malá Úpa, and Bukový Pramen in the Těsný důl valley in Janské Lázně. Uranium was co-precipitated in field conditions with hydroxides of FeIII+ in 50-liter water samples of the radioactive springs. In the lab, uranium and thorium were separated from water precipitates, as well as from solid samples after their chemical decomposition, using chromatographic extraction agent UTEVA. All the three isotopes of interest emit alpha particles, and so their activities were measured by alpha spectrometry and expressed as 234 U/238 U and 230 Th/234 U ratios. As an internal standard, 232 U/228 Th was used. The resulting 234 U/238 U activity ratios of four water samples measured ranged from 1.0747 to 1.423. In twelve samples of solid phases activity ratios 234 U/238 U from 0.861 to 1.129 were determined. The 230 Th/234 U activity ratios form two distinct...
|
|
|
The 234U/238U isotope ratio in waters near the uranium mineral deposits
Fanta, Martin ; Goliáš, Viktor (advisor) ; Strnad, Ladislav (referee)
Uranium has three natural isotopes: 238 U, 235 U and 234 U. Isotopes 238 U and 235 U are primordial, isotope 234 U is one of the daughter products of 238 U decay series. Genetically dependent uranium isotopes 238 and 234 are fractionated in nature. The main reason is the alpha recoil in solid (crystalline) phase, where there is a preferential settling subsidiary 234 U in a higher oxidation state (VI). The isotope 234 U is then more available at the recent geochemical processes: leaching and alteration. Water then usually has 234 U/238 U activity ratio higher than 1, while the activity ratio in solid residuum is smaller than unity. Isotopic ratio in water is dependent on many factors. The most important are the nature of source rocks, weathering rate, the dynamics of geochemical processes (e.g. fluid-flow velocity) or anthropogenic influence on geological environment at mining of uranium deposits. Identification of these fractionation factors is not easy. Differences in the isotope ratios in water may be used to identify the source of uranium and to evaluate the contribution of technogenic uranium.
|
guest ::
RSS feed.