National Repository of Grey Literature 2 records found  Search took 0.01 seconds. 
Development of a synthetic methodology for the preparation of advanced cycloarenes and their analogues
Bambas, Daniel ; Stará, Irena (advisor) ; Míšek, Jiří (referee)
This Bachelor's Thesis deals with a design and preparation attempts leading to building blocks suitable for macrocycle construction with further utilization in cycloarene synthesis. In Theoretical Background methods for preparation of [n]circulenes and kekulene-like structures are summarized with focus on the final ring-closing steps. In Results and Discussion chapter efforts to prepare the selected advanced building block as a starting compound for macrocyle construction whose transformation using [2+2+2] cyclotrimerization as a ring-forming reaction might provide the selected cycloarene are described. Part Proposed alternatives of synthesis and discussion of further approach is about future possible development of this study. Experimental Part provides practical information about undertaken experiments and characterizations of the prepared compounds.

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