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National Repository of Grey Literature

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Chemical vapor generation of cadmium for analytical atomic spectrometry Sagapova, Linda ; Kodríková, Barbora ; Svoboda, Milan ; Musil, Stanislav ; Kratzer, Jan Chemical vapor generation of cadmium volatile compounds was optimized, several reaction modifiers based on inorganic salts and complexes of CrIII+, CoII+, TiIII+, TiIV+ were tested. Their use resulted in 4-5 times enhancement in sensitivity, reflected also in corresponding increase of generation efficiency and better repeatability. Generation efficiency was determined from a comparison between sensitivities obtained with chemical vapor generation and conventional solution nebulization, both simultaneously coupled with inductively coupled plasma mass spectrometry. The identity of the generated cadmium compounds was identified. Detailed record

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