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Study of the technological heat utilization system in the waste gas-to-energy process
Beneš, Daniel ; Kilkovský, Bohuslav (referee) ; Jegla, Zdeněk (advisor)
This diploma thesis deals with the conceptual design of systems for the technological use of heat in "waste gas-to-energy" (WGtE) industrial processes. In the beginning of the work, familiarization with the WGtE processes is carried out. Their general concept, equipment composition and possible design of exchangers within this system are presented. In the next part of the thesis, a specific industrial case of the WGtE process is presented, on which the analytical method for the design of new units is subsequently presented and assessed. The following is a part of the work that is devoted to the creation of a graphic-calculation tool for the conceptual design of the technological heat utilization system using the analytical method of calculation. At the end of the thesis, this tool is applied to the cases of two WGtE processes for the conceptual design of the optimal technical-economic solution of the technological heat utilization system of these processes, and the achieved optimization results are subsequently evaluated.
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Waste gas combustion
Krček, Robin ; Lisá, Hana (referee) ; Baláš, Marek (advisor)
This bachelor thesis deals with the issue of using waste gases as fuel. The first part is focused on the production processes, properties and composition of selected waste gases. The following part is an overview of the methods used in the treatment and removal of pollutants from the gas. Finally, technologies that generate electrical, thermal or mechanical energy by burning waste gases are summarized.
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Study on the potential of an integrated waste-to-energy unit
Freisleben, Vít ; Turek, Vojtěch (referee) ; Jegla, Zdeněk (advisor)
This diploma thesis is focused on the design of technological modifications of the existing industrial unit „waste-to-energy“, used for thermal treatment of process waste gases containing VOC and CO while flue gas is produced. The main objective of the existing unit modification is to improve its operating parameters considering economy, ecology and energy utilization. In the first part, the current industrial plant was presented with all necessary process data. Furthermore, all the key equipment used for the waste gases treatment or for the utilization of waste heat was identified. In the main part of the thesis there are performed modifications of the existing unit including the technology of existing heat exchangers intensification, the design of new and more efficient heat exchangers and finally the catalytic oxidation technology implementation for the decomposition of pollutants contained in the waste gas. The result of the thesis is a technical, economic and ecological comparison of the proposed technological modifications with the existing operation.
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Design for waste gas cleaning
Kubík, Michal ; Lisá, Hana (referee) ; Baláš, Marek (advisor)
This diploma thesis deals with impurities in waste gases and syngas. Those gases usually have low heating value and contain impurities which are the main issue of those gas fuels. Waste gases and syngas can replace natural gas after right gas treatment. First part is theoretical. It starts with description of biomass and gasification technology. Then the waste gases are described – their origin and usual composition. Next part is dedicated to impurities and is followed by impurities treatment technologies. For removing of almost every type of impurity wet scrubber can be used which is described in detail in following part. There are other types of gas cleaning technologies, so they are described too but not in such detail as wet scrubber. In second part the wet scrubber is designed, and its function is tested by cleaning syngas from fluidized-bed gasifier called Biofluid. During gas cleaning in wet scrubber the influence of water temperature on efficiency of tar removal is examined.
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Treatment of waste gases polluted by freons
Frydrych, Tomáš ; Houdková, Lucie (referee) ; Dvořák, Radek (advisor)
This thesis inquire into experimental decomposition of freon R-22 (CHClF2 - chlorodifluorometan) for different process conditions, by the help of pilot experimental unit in heavy laboratories DEPARTMENT of process and enviromental engineering Brno. This unit can decomposition waste gas, as the case may be combustion gas by the thermic oxidation or catalytic oxidation. Ground was in theoretical research, in which had been executed decomposition of freon R-22 in laboratory. In terms of experimental work were to be execution states for decomposition of freon R-22, next will be decomposition of freon R-22 by catalytic oxidation on catalyst Pt/Al2O3 and consequently this experiment will be analyse. Part of this thesis is exploration of facts basic way to decomposition of freon R-22, accounting of experimental unit and discussion of results.
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Equipment for Disposal of Waste Gases of Catalytic Oxidation
Brummer, Vladimír ; Martinec, Jan (referee) ; Leštinský, Pavel (referee) ; Bébar, Ladislav (advisor)
This thesis deals with the design of the equipment and documentation for the design of equipment for the removal of volatile organic compounds (VOC) and carbon monoxide (CO) by catalytic oxidation and the selection of appropriate technological conditions for this technology. Introduction is devoted to familiarization with the field of the catalytic oxidation, used catalysts, catalyst supports and their active components. Advantages and disadvantages of the use of catalytic oxidation versus thermal incineration are outlined and currently applicable legislative terms for VOC and CO emissions are listed. In the next part of the thesis the fundamental mathematical tools and research findings available for catalytic reactor model designed primarily for monolithic catalysts are summarized. Presented kinetic model considers continuous reactor with plug flow of gas and adiabatic heating by oxidation reactions corrected for the heat loss of the reactor. The next chapter discusses the design of the new prototype of the catalytic oxidation pilot plant (i.e. the reactor incl. peripherals) primarily intended for monolithic catalysts and bulk catalysts in the form of the fixed bed. The basis for the design and sizing are material and energy balances in the ChemCAD for different intended use of the unit, from which boundary conditions of the unit operating parameters arises. Pilot plant has been designed and built, functionality tests was scheduled also with consecutive obtaining of experimental data not only for the reactor kinetic model. Results of the model for the catalytic combustion were in good agreement with measured data. The next part includes two industrial case studies of the catalytic oxidation process usage for the chemical industry. In particular it was dealt with a replacement of the non-catalytic combustion for the catalytic for VOC abatement from chemical production plants off-gas streams of the company Momentive Specialty Chemicals in Sokolov and German city Leuna. These case studies have brought many valuable experimental and technological knowledge from long-term pilot tests and also verification of design concept, thanks to which it was later possible to design a pilot unit for removal of pollutants in premises of NETME Centre and among other to economically evaluate the usage of catalytic oxidation for the off gas cleaning, in comparison with traditional combustion, in two completely different individual cases. This information was valuable and necessary for the verification of theoretical assumptions of the thesis on specific conditions of two different industrial productions. Based on acquired practical experience and theoretical background, guidelines for designing of devices for VOC and CO removal in the industry were developed.
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Integrated solution of waste gas-to-energy unit
Freisleben, Vít ; Buzík, Jiří (referee) ; Reppich, Marcus (referee) ; Jegla, Zdeněk (advisor)
Waste Gas-to-Energy (WGtE) units allow the thermal processing of gaseous waste and its simultaneous energy recovery. However, the operation of WGtE units involves a large consumption of external fuel, and the flue gases produced require the application of flue gas cleaning technology. This thesis presents the results of a study focused on the topic of integrated WGtE unit design, which is an effective approach for achieving external fuel consumption savings while minimizing investment costs. Firstly, it presents the developed analytical method for the design of technological modifications of existing WGtE units treating waste gases in order to achieve their economical and more environmentally friendly operation. Attention is mainly paid to the description of the developed mathematical relations and graphical tools that can be used by the professional community, especially by the operators of WGtE units. To further reduce the negative environmental impact of these units, the second area addressed in the thesis is the development of flue gas cleaning equipment for the reduction of nitrogen oxides concentration. In addition to the technological concept and design of this device, the results of experimental work in laboratory and industrial environment are presented, where the great potential of using these devices in WGtE units as well as in a wide range of other industrial combustion plants was confirmed.
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Waste gas combustion
Krček, Robin ; Lisá, Hana (referee) ; Baláš, Marek (advisor)
This bachelor thesis deals with the issue of using waste gases as fuel. The first part is focused on the production processes, properties and composition of selected waste gases. The following part is an overview of the methods used in the treatment and removal of pollutants from the gas. Finally, technologies that generate electrical, thermal or mechanical energy by burning waste gases are summarized.
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Study on the potential of an integrated waste-to-energy unit
Freisleben, Vít ; Turek, Vojtěch (referee) ; Jegla, Zdeněk (advisor)
This diploma thesis is focused on the design of technological modifications of the existing industrial unit „waste-to-energy“, used for thermal treatment of process waste gases containing VOC and CO while flue gas is produced. The main objective of the existing unit modification is to improve its operating parameters considering economy, ecology and energy utilization. In the first part, the current industrial plant was presented with all necessary process data. Furthermore, all the key equipment used for the waste gases treatment or for the utilization of waste heat was identified. In the main part of the thesis there are performed modifications of the existing unit including the technology of existing heat exchangers intensification, the design of new and more efficient heat exchangers and finally the catalytic oxidation technology implementation for the decomposition of pollutants contained in the waste gas. The result of the thesis is a technical, economic and ecological comparison of the proposed technological modifications with the existing operation.
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Design for waste gas cleaning
Kubík, Michal ; Lisá, Hana (referee) ; Baláš, Marek (advisor)
This diploma thesis deals with impurities in waste gases and syngas. Those gases usually have low heating value and contain impurities which are the main issue of those gas fuels. Waste gases and syngas can replace natural gas after right gas treatment. First part is theoretical. It starts with description of biomass and gasification technology. Then the waste gases are described – their origin and usual composition. Next part is dedicated to impurities and is followed by impurities treatment technologies. For removing of almost every type of impurity wet scrubber can be used which is described in detail in following part. There are other types of gas cleaning technologies, so they are described too but not in such detail as wet scrubber. In second part the wet scrubber is designed, and its function is tested by cleaning syngas from fluidized-bed gasifier called Biofluid. During gas cleaning in wet scrubber the influence of water temperature on efficiency of tar removal is examined.
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