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National Repository of Grey Literature 2 records found  Search took 0.00 seconds. 
The synthesis of functionalised electron donors and acceptors and the study of their interaction
 Rejchrtová, Blanka ; Starý, Ivo (advisor) ; Betík, Robert (referee)
This work is focused on the stepwise preparation of model dimer, containing tetrathiafulvalene as electron donor unit. Main method used in the synthesis was Sonogashira coupling. Theoretical part deals with current state of research in the field of nanoscience and nanotechnology and molecular electronics. It is focused on noncovalent interactions, especially of the electron donor - electron acceptor (CT complexes). Properties of tetrathiafulvalene and its derivatives are described in detail as well as mechanism of Sonogashira coupling. In the part devoted to the results and discussion is described preparation of monomeric precursor from known TTF alcohol and new iodobenzylbromide with protected acetylene function. Stepwise synthesis utilizing Sonogashira coupling leads to the preparation of model dimer in moderate yield. All new compounds were characterized by spectral methods (NMR, MS, FTIR) and by elemental analysis, eventually HR-MS.
Detailed record
The synthesis of functionalised electron donors and acceptors and the study of their interaction
 Rejchrtová, Blanka ; Betík, Robert (referee) ; Starý, Ivo (advisor)
This work is focused on the stepwise preparation of model dimer, containing tetrathiafulvalene as electron donor unit. Main method used in the synthesis was Sonogashira coupling. Theoretical part deals with current state of research in the field of nanoscience and nanotechnology and molecular electronics. It is focused on noncovalent interactions, especially of the electron donor - electron acceptor (CT complexes). Properties of tetrathiafulvalene and its derivatives are described in detail as well as mechanism of Sonogashira coupling. In the part devoted to the results and discussion is described preparation of monomeric precursor from known TTF alcohol and new iodobenzylbromide with protected acetylene function. Stepwise synthesis utilizing Sonogashira coupling leads to the preparation of model dimer in moderate yield. All new compounds were characterized by spectral methods (NMR, MS, FTIR) and by elemental analysis, eventually HR-MS.
Detailed record

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