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Study of Electrode Materials for Sodium-ion Batteries
Jilčík, Jan ; Bača, Petr (referee) ; Libich, Jiří (advisor)
This bachelor thesis deals with the issue of electrochemical cells, more precisely sodiumion batteries. Part of the work is the introduction and comparison of lithium-ion battery technology with the new sodium-ion battery technology. Sodium-ion batteries represent one of the new and very promising types of batteries that belong to the so-called post lithium system group. As part of the bachelor thesis, the issue of negative (anode) materials for sodium-ion batteries is described and discussed in detail. The work mentions silicon as a promising electrode material for the negative electrode of sodium-ion batteries. The practical part of the bachelor's thesis is focused on doping the anode of a sodium-ion battery with silicon and its electrochemical properties are investigated.
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Electrode Materials for Sodium-ion Batteries Based on Carbon
Homolka, Tomáš ; Binar, Tomáš (referee) ; Libich, Jiří (advisor)
This diploma thesis focuses on electrode materials for sodium batteries with a particular emphasis on anodes, especially hard carbon. The history of sodium-ion batteries and their operating principle are discussed as well. The project also describes the history of lithium ion batteries, as they share a significant part of their development and operating principle with sodium-ion batteries. In the practical part, measurements of rate capability, capacity and coulombic efficiency of the selected hard carbon are then performed. The sodation method is also tested and the effect of moisture on its properties is further investigated.
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Study of Electrode Materials for Sodium-ion Batteries
Varmužová, Zdeňka ; Binar, Tomáš (referee) ; Libich, Jiří (advisor)
The content of this thesis is an introduction and presentation to the issue of sodium-ion batteries and a description of production of the own electrode material and its subsequent electrochemical characterization. It deals with the historical development of electrochemical sources of electrical energy from the first batteries to the current types. Study then discusses lithium-ion type batteries, which are closely related to the development of the studied sodium-ion batteries. From the point of view of sodium-ion batteries, the thesis focuses on their electrode materials, especially on anode materials based on sodium titanates. The thesis describes a synthesis of a sodium titanate and production of a negative electrode for sodium-ion battery application and construction of a test cell. The thesis then proposes and evaluates measurements verifying the properties of prepared sample of sodium titanate.
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Study of intercalation properties of electrode materials based on naturla graphite
Bílek, Lukáš ; Máca, Josef (referee) ; Libich, Jiří (advisor)
This diploma thesis deals with the issue of lithium-ion accumulators. The thesis focuses on the negative electrode of lithium-ion accumulators made of natural graphite. The first part of this thesis points to the issue of electrochemical cells. In the theoretical part the thesis deals with the SEI layer, advantages, disadvantages, characteristics, operating principle and the use of lithium-ion accumulators. The practical part focuses on the electrochemical properties of negative electrode, especially the determination of the diffusion coefficient. Thesis also deals with electrochemical impedance spectroscopy (EIS) and its use in determining the equivalent replacement circuit and calculating the diffusion coefficient.
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Development of negative electrodes for lithium-ions batteries
Drahokoupil, Petr ; Libich, Jiří (referee) ; Sedlaříková, Marie (advisor)
This thesis deals with lithiation of negative electrode li-ion batteries. In this thesis is used several electrode materials: carbon, FeCl3, lithiated carbon electrodes and silicon carbide. Reduction of irreversible capacity lithium-ion batteries leads to increased capacity and also we can use new materials as a positive electrode. Thesis deals with the differences in the properties of materials using lithiation and their use in practice
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Influence of conductive ceramics on the life of lead acid batteries
Tobolák, Jakub ; Vaněk, Jiří (referee) ; Bača, Petr (advisor)
This thesis is focused on lead-acid batteries used in hybrid electric vehicles. These cells work in specific conditions, particularly under partial charge referred to as PSOC. This fact is responsible for the premature loss of capacity cell lead-acid batteries and their short lifetime. The task of this thesis is to examine the effect of conductive ceramics as possible additives to the negative electrode active materials of lead-acid battery cells operating in a PSOC, in order to prolong their life.
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Negative lead-acid battery electrode for hybrid electric vehicles
Dvořáček, Daniel ; Křivík, Petr (referee) ; Bača, Petr (advisor)
The thesis briefly discusses the issue of electrochemical power sources, especially with a focus on lead-acid batteries operating in modes that are typical of hybrid electric vehicles. The theoretical part of the thesis should be a good basis for the subsequent practical part, in which several experimental electrodes and their parameters will be performed and evaluated. The output of the practical part will be conclusions regarding the influence of different variants of modified carbon used as an additive in the active material of the negative electrode on the capacity and life of cells
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Observation of lead electrode surface by atomic force microscope AFM
Bouška, Marek ; Máca, Josef (referee) ; Bača, Petr (advisor)
This master's thesis is focused on in situ observation of the negative electrode of the lead acid accumulator using atomic force microscopy AFM. Discussed topics are lead acid accumulator, atomic force microscopy, cyclic voltammetry and current knowledge of the in situ observation of the lead acid accumulator using AFM. The main task of this project is assembling the experimental cells, make in situ observation of the negative electrode surface of the lead acid accumulator. In the end evaluate if this method is suitable for the lead acid battery observation.
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Impact of technological parameters on electrochemical properties of negative electrode in lithium-ion battery
Živčic, Samuel ; Máca, Josef (referee) ; Libich, Jiří (advisor)
This bachelor thesis deals with the issue of li-ion batteries and consists of two main parts. The first part of the thesis deals with a theory. It describes the functionality of electrochemical cells, especially li-ion cells. Operational principle of the cell is discussed, with the main focus given on negative electrode (anode) and the material it consists of, the natural graphite, mainly his electrochemical properties. Last chapter of theory describes expected impact of technological parameters on electrochemical properties of negative electrode. The second part of the thesis is the practical part. First, it describes procedure of making electrodes in laboratory and afterwards it provides an explanation of used measuring methods, steps taken during the measurement, and the results of the measurements. At the end of the thesis, the influence of pressure and layer thickness on electrochemical properties of natural graphite and on capacitive and current characteristics of negative electrode is evaluated.
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