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Magnetic properties of Ce compounds studied by specific heat
Čermák, Petr ; Javorský, Pavel (advisor)
Materials containing the 4f (rare earth) or 5f (actinides) exhibit a large variety of interesting physical properties. The Ce-based compounds have a special place among the rare-earth compounds. The Ce atom contains only a single f-electron that is responsible for the magnetic behavior. The 4f states in compounds with the heavy rare earths have a well localized character, whereas many Ce-based compounds are on the borderline between the localized and itinerant behavior. These compounds show large variety of the magnetic ground states what is a result of the competition between the long-range order of the RKKY type and the screening of the localized moments by conduction electrons. We observe nonmagnetic states with a mixed valence (between Ce3+ and Ce4+), metallic systems with a long-range order of the Ce moments (ferromagnetic, antiferromagnetic or more complex structures). To analyze the electronic properties, the heat capacity data, and namely their low-temperature part, play an indispensable role. This diploma work comprise the sample preparation of selected cerium compounds, their phase characteristics and the heat capacity measurements at low temperatures (0.4 - 300 K). The main part is focused on the data analysis and comparison with theoretical models.
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Magnetic properties of Ce compounds studied by specific heat
Čermák, Petr ; Javorský, Pavel (advisor)
Materials containing the 4f (rare earth) or 5f (actinides) exhibit a large variety of interesting physical properties. The Ce-based compounds have a special place among the rare-earth compounds. The Ce atom contains only a single f-electron that is responsible for the magnetic behavior. The 4f states in compounds with the heavy rare earths have a well localized character, whereas many Ce-based compounds are on the borderline between the localized and itinerant behavior. These compounds show large variety of the magnetic ground states what is a result of the competition between the long-range order of the RKKY type and the screening of the localized moments by conduction electrons. We observe nonmagnetic states with a mixed valence (between Ce3+ and Ce4+), metallic systems with a long-range order of the Ce moments (ferromagnetic, antiferromagnetic or more complex structures). To analyze the electronic properties, the heat capacity data, and namely their low-temperature part, play an indispensable role. This diploma work comprise the sample preparation of selected cerium compounds, their phase characteristics and the heat capacity measurements at low temperatures (0.4 - 300 K). The main part is focused on the data analysis and comparison with theoretical models.
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The Role of Microstructure in Fracture Resistence Control of TiAl Based Intermetallics
Dlouhý, Ivo ; Haga, H. ; Chlup, Zdeněk ; Hadraba, Hynek ; Hasegawa, M. ; Fukutomi, H.
The analysis of the role of microstructure in fracture performance of TiAl intermetalics at room and elevated temperatures has been carried out. For Ti-46Al-0.7Cr-0.1Si-7Nb-0.2Ni alloy different regimes of thermal and thermal-mechanical treatment were applied enabling to control substantially microstructural parameters. Attention was paid to grain (colony) size effect, effect of lamellas thickness and morphology and, in addition, to β-phase effect. For separate treatment regimes the flexural strength and fracture toughness were evaluated in addition to microstructural parameters. Fractographic analysis enabled to evaluate fracture micromechanisms; development of shear ligament toughening was observed in almost all cases. This is the key mechanism controlling the fracture behaviour. Based on findings obtained key aspects of the effect of separate microstructural components have been discussed.
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Lomová houževnatost a mechanismy porušování intermetalika na bázi TiAl
Dlouhý, Ivo ; Chlup, Zdeněk ; Hadraba, Hynek ; Kozák, Vladislav
The paper is focused on the analysis of the role of microstructure in fracture performance of TiAl intermetalics at room and elevated temperatures. Tensile properties, flexural strength and fracture toughness have been evaluated for Ti-40Al-2Cr-2Nb-1B and Ti-46Al-0,7Cr-0,1Si-7Nb-0,2Ni alloys. Positive Nb effect on fracture resistance was found; fracture toughness of the high Nb alloy was increased at contemporary increase of tensile and flexural strength. Fracture surfaces were evaluated using scanning electron microscopy showing the key role of mechanical twinning in deformation of both alloys. As a governing mechanism of the crack initiation a microcrack nucleation at boundaries between -TiAl grains was confirmed. Based on findings obtained key aspects of the effect of separate microstructural components have been discussed. Summary of toughening effects acting in this group of intermetalics has been provided.
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Fracture toughness and damage mechanisms of intermetalic based on TiAl
Dlouhý, Ivo ; Chlup, Zdeněk ; Hadraba, Hynek ; Kozák, Vladislav
The paper concentrates on the analysis of the role of microstructure in fracture behaviour of TiAl intermetalics at room and elevated temperatures. Tensile properties, flexural strength and fracture toughness have been evaluated for alloys Ti-40Al-2Cr-2Nb-1B and Ti-46Al-0,7Cr-0,1Si-7Nb-0,2Ni. Positive effect of Nb on fracture resistance has been found; fracture toughness of the high Nb alloy increased at contemporary increase of tensile and flexural strength. Fracture surfaces have been evaluated using scanning electron microscopy showing the key role of mechanical twinning in deformation of both alloys followed. As a governing mechanism of the crack nucleation a microcrack formation at boundaries between mechanical twins and gama-TiAl grains has been confirmed. Extensive development of shear ligament toughening was observed supplying quite good values of fracture toughness in high niobium alloy.
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The role of microstructure in racture behaviour of TiAl based intermetalics
Krahula, Karel ; Prokešová, Zdenka ; Dlouhý, Ivo
The contribution is focused on the analysis of the role of microstructural parameters in fracture behaviour of TiAl intermetalics at room and increased temperatures. Flexural strength and fracture toughness have been evaluated for alloys Ti-40Al-2Cr-2Nb-1B and Ti-46Al-0,7Cr-0,1Si-7Nb-0,2Ni. Positive effect of Nb on fracture resistance has been found; fracture toughness of the high Nb alloy increased at contemporary increase of flexural strength. Fracture surfaces have been evaluated using scanning electron microscopy showing the key role of mechanical twinning in deformation of both alloys followed. As a governing mechanism of crack nucleation microcrack formation at boundaries between mechanical twins and gama grains has been confirmed.
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