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Lead isotopic composition of selected certified reference materials in three step extraction procedure.
Martinovský, Václav ; Mihaljevič, Martin (advisor) ; Strnad, Ladislav (referee)
This work deals with the issue of lead isotopic composition in reference materials. These reference materials were extracted by using method of sequential extraction analyses Isotopic composition of the lead was determined by ICP MS (Thermo scientific). The first part summarizes knowledge in the field of sequential extraction analyses; in the following section issue of using isotopic composition of lead in environmental sciences is discussed. Experimental part describes research methodology and presents results of the sequential extraction and the isotopic composition of lead contained in the analysed reference materials. Following reference materials were analysed: CRM BCR 483, CRM BCR 701, SRM NIST 2709a, SRM NIST 2710a, SRM NIST 2711a. Results of modified sequential extraction procedure BCR (three steps methodology created by Community Bureau of Reference, Belgium to harmonize technical procedure) measured in this work corresponds to the certified or indicative values. Isotopic composition expressed by isotopic ratios 206 Pb/207 Pb among fractions of BCR sequential extraction (fractions I - IV) was folloving: CRM BCR 483 (1,1168 - 1,1350); CRM BCR 701 (1,1583 - 1,1844); SRM NIST 2709a (1,1819 - 1,2118); SRM NIST 2710a (1,1583 - 1,1989); SRM NIST 2711a (1,1079 - 1,1284). Key words: lead isotopic...
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Lead isotopic composition of selected certified reference materials in three step extraction procedure.
Martinovský, Václav ; Mihaljevič, Martin (advisor) ; Strnad, Ladislav (referee)
This work deals with the issue of lead isotopic composition in reference materials. These reference materials were extracted by using method of sequential extraction analyses Isotopic composition of the lead was determined by ICP MS (Thermo scientific). The first part summarizes knowledge in the field of sequential extraction analyses; in the following section issue of using isotopic composition of lead in environmental sciences is discussed. Experimental part describes research methodology and presents results of the sequential extraction and the isotopic composition of lead contained in the analysed reference materials. Following reference materials were analysed: CRM BCR 483, CRM BCR 701, SRM NIST 2709a, SRM NIST 2710a, SRM NIST 2711a. Results of modified sequential extraction procedure BCR (three steps methodology created by Community Bureau of Reference, Belgium to harmonize technical procedure) measured in this work corresponds to the certified or indicative values. Isotopic composition expressed by isotopic ratios 206 Pb/207 Pb among fractions of BCR sequential extraction (fractions I - IV) was folloving: CRM BCR 483 (1,1168 - 1,1350); CRM BCR 701 (1,1583 - 1,1844); SRM NIST 2709a (1,1819 - 1,2118); SRM NIST 2710a (1,1583 - 1,1989); SRM NIST 2711a (1,1079 - 1,1284). Key words: lead isotopic...
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