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Drying and preheating in potting process of epoxides
Matoušová, Klára ; Novák, Vítězslav (referee) ; Kazelle, Jiří (advisor)
The bachelor's thesis is dealing with the defects in epoxy resin flooded transformer devices. Since these can be damaged severely in terms of quality by numerous forces, the main focus is dedicated to the impact of moisture. The thesis describes the manufacturing technology including the methods applied and materials used. It further encompasses the composition of epoxy resin and the mechanisms used for their hardening processes. Additionally, the description of the moisture, the impact of adverse forces and the method of their elimination using drying is presented. In the experimental part of the paper, a moisture of the banding materials was measured. On the basis of the results acquired, the paper reaches a conclusion on the ideal time frame of drying, the sufficiency of materials in terms of drying and in two cases two substitutes for contemporary uneasily dryable samples were considered.
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Development of resistant composite containing secondary raw materials for reconstruction of objects from cast basalt
Čtvrtečková, Anna ; Jakubík, Aleš (referee) ; Drochytka, Rostislav (advisor)
The diploma thesis is focused on the development of the resistant repair composite material using, secondary raw materials for the rehabilitation of objects made off the cast basalt with the highest possible filling of secondary raw materials. The resistant composite shall show the parameters approaching to the properties of cast basalt. The work is also focused at physical and mechanical properties of the composite material and its resistance to chemically aggressive conditions, and it is also aimed at the rehabilitation technology, especially the appropriate pre-treatment of the substrate to provide sufficient cohesion between the substrate and the repair composite.
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Preparation and properties of building blocks of specialty polymers
Šichová, Kristýna
This Diploma Thesis presents results obtained by solution of two partial projects: a) Preparation of monomers from renewable sources using metathesis and tandem hydrogenation catalyzed with ruthenium compounds - project solved during my Erasmus stay at the Université de Rennes 1 in France; b) Preparation and properties of ,-bis(tpy)quarterthiophene oligomers carrying ionic side groups as oligomonomers for polyelectrolyte conjugated dynamers - project solved at the Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague. Project a): Self-metathesis of 1,2-epoxyhex-5-ene (but-3-enyloxirane) and its cross-metathesis with methyl acrylate and acrylonitrile catalyzed with ruthenium compounds as well as tandem design of these metatheses and consecutive hydrogenation of their products by gaseous hydrogen have been optimized. The following influences have been studied and tuned: (i) type of the catalyst (Grubbs, Hoveyda, Zhan) and its concentration and method of dosing, (ii) concentration of reactants and additives, (iii) type of solvent, and (iv) reaction temperature. Reactions were monitored by the GC, GC and MS methods and the products were characterized by the NMR method. Methyl 6,7-epoxyheptanoate (methyl 5-oxiranylpentanoate) obtained by the tandem...
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Preparation and properties of building blocks of specialty polymers
Šichová, Kristýna
This Diploma Thesis presents results obtained by solution of two partial projects: a) Preparation of monomers from renewable sources using metathesis and tandem hydrogenation catalyzed with ruthenium compounds - project solved during my Erasmus stay at the Université de Rennes 1 in France; b) Preparation and properties of ,-bis(tpy)quarterthiophene oligomers carrying ionic side groups as oligomonomers for polyelectrolyte conjugated dynamers - project solved at the Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague. Project a): Self-metathesis of 1,2-epoxyhex-5-ene (but-3-enyloxirane) and its cross-metathesis with methyl acrylate and acrylonitrile catalyzed with ruthenium compounds as well as tandem design of these metatheses and consecutive hydrogenation of their products by gaseous hydrogen have been optimized. The following influences have been studied and tuned: (i) type of the catalyst (Grubbs, Hoveyda, Zhan) and its concentration and method of dosing, (ii) concentration of reactants and additives, (iii) type of solvent, and (iv) reaction temperature. Reactions were monitored by the GC, GC and MS methods and the products were characterized by the NMR method. Methyl 6,7-epoxyheptanoate (methyl 5-oxiranylpentanoate) obtained by the tandem...
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Preparation and properties of building blocks of specialty polymers
Šichová, Kristýna ; Svoboda, Jan (advisor) ; Sedláček, Jan (referee)
This Diploma Thesis presents results obtained by solution of two partial projects: a) Preparation of monomers from renewable sources using metathesis and tandem hydrogenation catalyzed with ruthenium compounds - project solved during my Erasmus stay at the Université de Rennes 1 in France; b) Preparation and properties of ,-bis(tpy)quarterthiophene oligomers carrying ionic side groups as oligomonomers for polyelectrolyte conjugated dynamers - project solved at the Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague. Project a): Self-metathesis of 1,2-epoxyhex-5-ene (but-3-enyloxirane) and its cross-metathesis with methyl acrylate and acrylonitrile catalyzed with ruthenium compounds as well as tandem design of these metatheses and consecutive hydrogenation of their products by gaseous hydrogen have been optimized. The following influences have been studied and tuned: (i) type of the catalyst (Grubbs, Hoveyda, Zhan) and its concentration and method of dosing, (ii) concentration of reactants and additives, (iii) type of solvent, and (iv) reaction temperature. Reactions were monitored by the GC, GC and MS methods and the products were characterized by the NMR method. Methyl 6,7-epoxyheptanoate (methyl 5-oxiranylpentanoate) obtained by the tandem...
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Drying and preheating in potting process of epoxides
Matoušová, Klára ; Novák, Vítězslav (referee) ; Kazelle, Jiří (advisor)
The bachelor's thesis is dealing with the defects in epoxy resin flooded transformer devices. Since these can be damaged severely in terms of quality by numerous forces, the main focus is dedicated to the impact of moisture. The thesis describes the manufacturing technology including the methods applied and materials used. It further encompasses the composition of epoxy resin and the mechanisms used for their hardening processes. Additionally, the description of the moisture, the impact of adverse forces and the method of their elimination using drying is presented. In the experimental part of the paper, a moisture of the banding materials was measured. On the basis of the results acquired, the paper reaches a conclusion on the ideal time frame of drying, the sufficiency of materials in terms of drying and in two cases two substitutes for contemporary uneasily dryable samples were considered.
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