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National Repository of Grey Literature

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Transport of cadmium ions across model supported phospholipid membranes Navrátil, Tomáš ; Šestáková, Ivana ; Mareček, Vladimír ; Štulík, Karel These results report on experiments focussed on the formation of supported model phospholipid membranes, formed from phosphatidyl choline in the micrometric pores of hydrophilic polycarbonate supports, their chatacterization using voltammetry and electrochemical impendance spectrometry (EIS). Attention was paid transport of heavy metal ions (ions of cadmium, etc.) across these membranes in the presence or absence of ionophores (valinomysing and calciomycin) or in the presence of oxalic acid. The impact of some parameters on these systems and processes was investigated. Detailed record

Electrochemistry of selected radiosenzitizer-etanidazole Gál, Miroslav ; Híveš, J. ; Sokolová, Romana ; Hromadová, Magdaléna ; Kocábová, Jana ; Kolivoška, Viliam ; Pospíšil, Lubomír The first electron transfer to radiosensitizer etanidazole (ETN) and ETN radical anion formation in buffered aqueous media was studied by means of voltammetric techniques and Electrochemical Impendance Spectroscopy (EIS). The heterogeneous electron transfer rate constant for the first reduction of ETN (radical anion production) k0 for the redox couple and so called E1,7 potential were calculated. The obtained values of k0 and E1,7 potential indicate that ETN compared to some other possible chemical radiosensitizers requires lower energy to accept the first electron during metabolic pathway. Detailed record

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