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Ferrocene stibane ligands
Antala, Jakub ; Štěpnička, Petr (advisor) ; Gyepes, Róbert (referee)
5 Title: Ferrocene stibane ligands Author: Jakub Antala Department: Department of Inorganic Chemistry Supervisor: prof. RNDr. Petr Štěpnička, Ph.D., DSc. Abstract: This diploma thesis reports a study into the coordination properties of ferrocene phosphino-stibine Cy2PfcSbPh2 (LCy, Cy = cyclohexyl, fc = ferrocene-1,1'-diyl). Complexes with various transition metals were prepared (RuII , RhIII , PtII , PdII , AuI ), where the ligand binds in monodentate, bridging or chelating mode. Ruthenium(II) and rhodium(III) complexes were prepared from precursors with π-coordinated arene ligands, whereas [MCl2(η2 :η2 cod)] (M = Pd, Pt; cod = 1,5-cyclooctadiene) precursors were used to prepare palladium(II) and platinum(II) complexes and synthesis of gold(I) complexes started from [AuCl(tht)] (tht = tetrahydro- thiophene). In addition, the thesis describes the reactivity of ferrocene phosphino-stibine Ph2PfcSbPh2 (LPh). Specifically, it focuses on the preparation of chalcogenides Ph2P(E)fcSbPh2 (E = O, S, Se) and the corresponding stiborane derivatives Ph2P(E)fcSbPh2(O2C6Cl4) (E = void, O, S, Se), in which the stiborane center bears tetrachloropyrocatechol substituent, which makes it Lewis acidic and potentially prone to behave as an acceptor of electron pair from the Ph2P(E) moiety. The presence of this interaction was...
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