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Catalytic Cycloaddition Reactions of Tribenzocyclyne
Jacko, Jaroslav ; Kotora, Martin (advisor) ; Schulz, Jiří (referee)
The main aim of the bachelor thesis was to investigate the reactivity of tribenzocyclyne, a triangular molecule, undergoing reactions with antiaromatic biphenylenes and their heteroanalogues. Those reactions consist of C-C activations of strained bond mediated by the complexes of the group 9 elements, followed by migratory insertion of present alkyne which leads to the formation of a substituted aromatic ring. Presented method facilitated the setting of a experiment as well as cutting down on reaction steps. These investigations will subsequently serve for further progress in the chemistry of cyclic hexa- ortho-phenylenes. Key words: catalysis, cycloaddition, tribenzocyclyne, the C-C bond cleavage

See also: similar author names
1 Jacko, Jan
4 Jacko, Jerguš
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