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Synthesis of gold(I) carbene complexes from isocyanoferrocene
Harmach, Petr ; Štěpnička, Petr (advisor) ; Gyepes, Róbert (referee)
Title: Synthesis of gold(I) carbene complexes from isocyanoferrocene Author: Petr Harmach Department: Katedra anorganické chemie Supervisor: prof. RNDr. Petr Štěpnička, Ph.D., DSc. Abstract: The objective of this bachelor thesis was the synthesis of gold(I) carbene complexes. These complexes were synthetised from a newly prepared gold(I)-isocyanoferrocene complex and also directly from isocyanoferrocene. Carbene complexes were obtained from primary and secondary amines, and therefore complexes contain disubstituted or trisubstituted diaminocarbene moieties. All newly prepared complexes were characterized by NMR spectroscopy, mass spectrometry, elemental analysis and infrared spectroscopy. The structures of the majority of the prepared complexes were confirmed by single-crystal X-ray diffraction analysis. Key words: isocyanides, ferrocene, carbenes, gold(I) complexes
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