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National Repository of Grey Literature

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(Spectro) Electrochemical Study of Cibalackrot Derivatives – Potential Chromophores for Singlet Fission\n Šimková, Ludmila ; Lušpai, Karol ; Klíma, Jiří ; Ludvík, Jiří Recently, substantial attention has been paid to the search for suitable chromophores for singlet fission. This photophysical effect promises to increase the maximum of theoretical efficiency of solar cells. One type of candidates are derivatives of cibalackrot. Redox properties are critical for their use. Our electrochemical work is focused on the study of oxidation and reduction of a series of substituted cibalackrot derivatives using classic voltammetric techniques and their combination with in situ UV-vis and EPR spectroscopy. The results show the reversible formation of the radical anion (cation) in the first reduction (oxidation) step enabling determination of ´´electrochemical´´ HOMO-LUMO gap. Detailed record

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