National Repository of Grey Literature 8 records found  Search took 0.00 seconds. 
Membrane Separation of Racemic Mixtures
Kačírková, Marie ; Žitka, Jan ; Sysel, P. ; Storch, Jan ; Izák, Pavel
There were chosen three types of membranes with immobilizing chiral selector (AN-VImEt+L-Lactate40, SNCB6KIL5% and AN-VBCI-TPh(+)+L-Lactate(-)33). With these types is desirable to continue the investigation.
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Molecular Simulations of Chemical Reaction Equilibrium and Space-Dependent Self-Diffusion of Dimerization Reactions in Carbon-like Slit and Cylindrical Nanopores
Lísal, Martin ; Předota, Milan ; Aim, Karel
We present results of a molecular-level study of the effects of confinement on chemical reaction equilibrium and self-diffusion of dimerization reactions in slit and cylindrical nanopores.
Sorption Characteristics of PDMS in Ternary Systems Benzene (1) + Alcohols (2) + Ionic Liquid (3) and Corresponding Binary Subsystems
Randová, A. ; Bartovská, L. ; Hovorka, Š. ; Friess, K. ; Izák, Pavel
In this work the study of sorption characteristics of PDMS in ternary system benzene (1) + methanol or butanol (2) + ionic liquid (3) and corresponding binary subsystems at the temperature of 20°C is presented. The experimental data on total sorption were determined gravimetrically [3], the experimental data on preferential sorption were evaluated from the concentration change induced by an immersion of the membrane into the liquid mixture [3]. The volume changes of swollen membrane immersed in the studied liquid systems were determined from the dimensional changes of the membrane samples changes in X and Y axis dimensions were monitored directly in liquid by an optical method [1, 3] and membrane sheet thickness was measured by an Inductive Dial Indicator (Mahr, Germany).
Pervaporation as a Tool for Higher Effectiveness of Reaction Process
Izák, Pavel ; Kohoutová, Marie ; Afonso, C. A. M. ; Crespo, J.G.
This work is focused on the study of a catalyzed esterification reaction, taking place in the ionic liquid ([bmim] [BF4]), while one of the reaction products (water) is removed by pervaporation.
Sorpční a permeační vlastnosti membrány ze silikonu a iontové kapaliny v butanolových párách
Vopička, O. ; Hynek, V. ; Zgažar, M. ; Friess, K. ; Izák, Pavel
This contribution deals with properties of ionic liquid-silicone blends for butanol vapours.
Vliv obsahu iontových kapalin na vlastnosti neporézních polymerních membrán
Kohoutová, Marie ; Sikora, Antonín ; Hovorka, Š. ; Randová, A. ; Schauer, Jan ; Izák, Pavel
The polydimethylsiloxane membranes containing 0, 10, 20 or 30 wt. % of ionic liquid (benzyl-3-butylimidazolium tetrafluoroborate) were used for separation of butan-1-ol from water. Pervaporation selectivity increased and the butan-1-ol flux through the membrane raised with the increased content of [BBIM][BF4] in the PDMS-[BBIM][BF4] membranes. The PDMS-[BBIM][BF4] membrane showed high stability as well as selectivity (the separation factor raised up to 37, if 30 weight % of ionic liquid was accommodated in PDMS) during all experiments.
Botnání Nafionové membrány a její předpověď skupinově-příspěvkovou metodou
Randová, A. ; Bartovská, L. ; Hovorka, Š. ; Izák, Pavel ; Poloncarzová, M. ; Kolská, Z.
The anisotropic swelling of Nafion 112 membrane in pure organic liquids was monitored by an optical method. The results were used as the input for application of the group contribution method to the relative expansion in equilibrium. Value of plus minus 1.5 % in relative expansions was determined to be the experimental error. Maximum differences between the experimental and calculated relative expansions did not exceed the value of plus minus 3 %.
Sorpce kapalné směsi metanol-benzen v polymerních membránách
Randová, A. ; Bartovská, L. ; Izák, Pavel ; Hovorka, Š. ; Friess, K.
The solubility of single mixture components in the membrane is important for the effectivity of membrane separation processes. This information is accessible from the experimental data on the preferential sorption in combination with the experimental data on the total amount of the sorbed liquid. The sorption from binary liquid solutions methanol-benzene in Nafion and low density polyethylene membranes has been studied in the whole concentration range at constant temperature of 25°C.

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