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Use of iron nanoparticles for post-treatment of metal finishing wastewater
Matysíková, J. ; Sukopová, M. ; Škvoran, O. ; Holba, Marek
This study evaluated the efficiency of copper, nickel and zinc removal from industrial metal finishing wastewater using nZVI material in lab and pilot scale conditions. Initial concentrations of Cu, Ni and Zn in raw wastewater were 3.16 mg/L, 0.38 mg/L and 0.56 mg/L, respectively. All metals were presented in residual concentrations and difficult to remove. Copper concentration was lowered by 77.2% in lab scale and 85.2% in pilot scale test for nZVI dose of 400 mg/L after 3 hours of reaction. Removal efficiency of nickel was 51% in the lab scale and 85.2 % at the pilot scale. Decrease of zinc concentration was less significant and reached 35.4% and 40% in lab and pilot scale experiment, respectively. Increase of efficiency in pilot scale testing was caused by the application of nZVI under inert atmosphere which ensured the preservation of high iron reactivity. pH adjustment before the nZVI dosing had also significant influence for efficiency of reaction. No changes and fluctuations of temperature and conductivity were observed. Pilot-scale test with lower dose of nZVI was performed to reveal the surpluses of previous dose of iron. The dose of 300 mg nZVI/L was applied into the reactor under inert atmosphere with pH adjustment before iron dosing. Efficiency of metals removal dropped to the 70% and 70.1% for copper and nickel. Efficiency of zinc removal increased to the 60.5%. nZVI dose of 300 mg/L was sufficient for reaching of limits for wastewater discharge.
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Phosphorus Removal from Wastewater via Environmentally Friendly Technologies
Holba, Marek ; Škvoran, O. ; Maršálková, Eliška ; Maršálek, Blahoslav
Our research is recently focused on the phosphorus removal from wastewater treatment plant outlets. We chose two municipal wastewater treatment plants (with and without phosphorus removal) and tested zerovalent and hexavalent nanoiron for phosphorus removal. Ferrates showed promising results even for smaller dosages, whilst NZVI showed not satisfactorily results for full-scale application. Next work will include phosphorus fractionation and fate of different phosphorus fractions at the tertiary treatment. Increasing interest on xenobiotics, hormons, endocrine disruptors, heavy metals and PPCPs and their removal from the plant outlets will extend our testing in the future.
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Application of Iron Nanoparticles for Industrial Wastewater Treatment
Sukopová, M. ; Matysíková, J. ; Škvoran, O. ; Holba, Marek
Our study evaluated copper and nickel removal from metal finishing industry by using of nZVI. Lab-scale tests were performed with processing wastewater. Concentration of metals in raw wastewater was 22.4 mg/L for copper and 1.3 mg/L for nickel. 99 % of copper was removed by nZVI dose 3 g/L in 73 hours, likewise the highest removal efficiency of nickel was up to 80 % for the same nZVI dose in 6 hours. The removal efficiency 80 % for nickel was sufficient. The reaction seems to be relatively fast, high removal efficiencies were observed after 30 minutes. Further time of exposure was beneficial only for copper removal, nickel concentration become stable after 2 hours. Reaction conditions were monitored only but no effect of pH, temperature or conductivity was investigated. The results showed possibility to remove heavy metals from industrial wastewater in environmentally friendly way. Further research with real wastewater is necessary to get more reliable results.
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Phosphorus recycling - need or urgency
Holba, Marek ; Došek, M. ; Škvoran, O. ; Matysíková, J. ; Plotěný, K. ; Maršálek, Blahoslav
Phosphate policy is tightly connected with effective solutions in agriculture, but also with its removal from water environment where excessive concentration of phosphorus is not welcomed since it causes water bloom and worsening og surface water quality. Phosphate ores will be depleted soon and therefore recacling technologies should be introduced into practice in near future. Struvite - slow-release fertilizer seems to be good commodity for farmers. Struvite is usually responsible for clogged pipes in the wastewater treatment area. Therefore, several technologies of its recycling is recently being developed, esp. from reject water stream. Struvite crystallization, its production control and scale-up of technology from lab-scale through pilot-sclae to full-scale is technological challenge in the near future.
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