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Národní úložiště šedé literatury Nalezeno 3 záznamů.  Hledání trvalo 0.00 vteřin. 
Green approach for the preparation of biosourced ionic liquids and the study of their thermodynamic properties\n
 Souvenir Zafindrajaona, Mahasoa-Salina
This presentation will address a green approach to the synthesis of ionic liquids qualified as biosourced (monocatenar or bolaform systems) from specific agro-resources, according to several principles of green chemistry. As these solvents could be used to solubilize lignocellulosic biomass and/or extract bioactive compounds (from plant sourcing), the physicochemical characteristics (density, viscosity and heat capacity) of pure ILs or mixtures of IL/water must be determined. Preliminary results concerning this last point will be presented.
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Detailed Investigation of Human Galectins -1 and -3 by employing selectively deoxyfluorinated N-acetyllactosamines
 Kurfiřt, Martin
This work is focused on a detailed investigation of supramolecular recognition events between human galectins -1 and -3 and monodeoxyfluorinated N-acetyllactosamine probes, which were previously prepared in our laboratory. The recognition was studied using a combination of X-ray crystallography, isothermal titration calorimetry and several advanced NMR techniques, such as 19F T2-filter, 1H–1H STD, 1H–15N CSP or 19F EXSY. These techniques provided insight into the thermodynamics and kinetics of recognition and enabled us to uncover of subtle differences between both investigated galectins. Such differences could be potentially exploited in the selective targeting of individual galectins with important implications for the galectins-focused\npharmaceutic industry.
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Organoruthenium glycomimetics as selective galectin-1 inhibitors
 Hamala, Vojtěch
The prepared organoruthenium glycomimetics demonstrated sin gle unit nanomolar affinity to Gal-1 and over four orders of magnitude\nhigher selectivity to Gal-1 in comparison to Gal-3. The organoruthe nium galectin inhibitors were found to be nontoxic to both cancer and\nnoncancerous cell lines. Selected complexes showed an in vitro an timigratory effect against invasive cancer cell lines MDA-MB-231 and\nSK-OV-3.
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