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Purification of Flue Gas by Means of Membranes.
Bobák, M. ; Žitková, Andrea ; Vejražka, Jiří ; Červenka, Vojtěch ; Maršálek, J. ; Izák, Pavel
The aim of this work is to test our new patented method of water condensing membrane for flue gas purification. Moreover, our objective is also to compare our unique separation method with polymeric membranes being nowadays developed primarily for carbon capture (CC). Nevertheless, these membranes and whole CC technology have also solve the problem of the other pollutants like SO2, NOx and HX. We would like to find out whether the new separation method could be as efficient as the current polymeric membranes represented by the results of several academic investigations and pilot tests performed by membrane producers. It seems that it would be very advantageous and reasonable to develop the process combining efficient SO2, NOx, HX removal and water recovery but not necessarily with CO2 removal as CC will be possible only on sites where it could be further processed. Thus, there could be also a demand for the efficient technology without CC to be combined with current flue gas purification systems especially on smaller scales.
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New Membranes with Immobilizing Chiral Selector for Racemic Micture Separation.
Gaálová, Jana ; Cuřínová, Petra ; Stibor, Ivan ; Izák, Pavel
Enantiomers exhibit identical properties in the achiral environment, however, they often differ in effectiveness, pharmacological activity and pharmacokinetic profile since the modules with which they interact in biological systems are also optically active [1,2]. Racemic immobilizing chiral selector is present. Five types of membranes with different amount of chiral selector were used. During the pertraction experiments the membranes were subsequently placed between the feed and receiving phase of the pertraction cell. During pertraction experiments we find out, that kinetics of the pertraction significantly influence the enantiomer resolution what indicated that facilitated transport is employed; while enantioselective sorption activity of the membranes reached up to 100%.
Plný tet: SKMBT_C22018060513580 - PDF
Plný text: content.csg - PDF
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Separation of Gasses by Supported Liquid Membranes.
Izák, Pavel ; Žitková, Andrea ; Žák, Michal ; Vejražka, Jiří ; Kárászová, Magda ; Petrusová, Zuzana
Two swollen polyamide thin-film composite membranes were tested for effective CO2/CH4 separation. It was found that the water wettability has a key role for the separation of binary mixture representing a raw biogas, i.e. containing CO2 and CH4. The transport properties were analyzed by means of a mathematical model simulating gas permeation. A new modification of the mass transport coefficient model provided the concentration profiles of individual components on both sides of the membrane (inaccessible in experiments). Furthermore, the model enabled the evaluation of the mass transport coefficients of the gases in the mixture under varying stream flow rates and arrangements with respect to the membrane separation cell size. Therefore, the possibility of scale-up was discussed for both membranes and flow cell arrangement. Although the mathematical model was developed for a flat sheet membrane configuration, the results can be applied for a real spiral wound module with a wider surface.
Plný tet: SKMBT_C22017112810150 - PDF
Plný text: content.csg - PDF
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