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DEVELOPMENT OF SPECIAL REHABILITATION MATERIALS FOR CONCRETE FOR EXTREME STRESS WITH USE OF SECONDARY RAW MATERIALS
Hodul, Jakub ; Klečka,, Tomáš (referee) ; Ďurica,, Tibor (referee) ; Bydžovský, Jiří (referee) ; Drochytka, Rostislav (advisor)
The doctoral thesis deals with finding the use of some waste and secondary raw materials in the production of special polymer remediation materials for concrete, which could be applied even in constructions, where extreme mechanical and chemical load is occurred. The aim of this doctoral thesis is experimental examination of the possibility of using selected types of waste, including hazardous waste which represent the highest risk to environment, and secondary raw materials as a substitute for the currently used primary fillers in order to reduce the ecological footprint of the product itself. Some types of secondary raw materials, such as filter fly ash contaminated by flue gas denitrification process, are no longer used as a concrete admixture or partial cement substitution due to unwanted release of toxic ammonia (NH3). Mainly for this reason, the thesis deals with the progressive utilization of such types of secondary raw materials as well as with another currently unused waste into polymeric patching, grouting and anchoring materials while preserving or improving the final properties compared to reference materials using only primary raw materials. The result of this thesis is to find out suitable formulations for efficient preparation of special polymeric remediation materials for concrete containing waste and secondary raw materials as fillers. The partial aim of the thesis and a the scientific contribution is an observation of the developed materials internal structure using a modern device, CT tomography, an influence of the filler type on the long-term durability, and last but not least the observation of the rate of pollutants incorporation, found in hazardous waste, into the polymeric matric with the aid of EDX and FTIR analysis.
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Development of chemically resistant sprayed mixture
Hermann, Radek ; Dohnálek,, Pavel (referee) ; Drochytka, Rostislav (advisor)
Production wastes for which a direct use in another production is found become secondary raw materials. There are several institutions in Czech Republic and in the world, which are currently dealing with the issue. This thesis deals with the issue of cementitious spray concrete mixtures and deals with the possibilities of using secondary raw materials and waste from production as partial replacement of binder and filler in these mixtures. The aim of this theses is to optimize the composition of additives in the recipe of the commercially produced pray mixture and to verify the influence of the degree of substitution of binder or filler by secondary raw materials on its physical-mechanical properties. The aim is to maintain or increase these properties while substituting the binder and filler as much as possible. After the evaluation of results, it is possible to say, by suitable optimization of the additives it is possible to achieve a significant improvement of the physical-mechanical properties of the mass and furthermore, from the results of this thesis follows, that by substitution of 100% fine filler in combination with substitution of 30% binder it is possible to maintain or increase the physical-mechanical properties after 28 days of curing and to significantly increase these properties after 90 days of curing. The results of this thesis are also related to the reduction of economic impact on production of the spray mixture, mainly due to the use of secondary raw materials.
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Design of grout joint for chemical exposure using secondary raw materials
Matušková, Veronika ; Hodná, Jana (referee) ; Drochytka, Rostislav (advisor)
The aim of the bachelor’s thesis is the design of a high-quality polymeric grout joint using secondary raw materials and hazardous waste for increased chemical exposure. The main use assumed of the proposed grout joint is grouting of the cast basalt elements in building objects that are systematically exposure due to the highly aggressive chemical load. The use of input materials produced by progressive technologies should be another benefit of this grout joint to enhance the ecological aspects of the grout joint production.
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Development of industrial adhesive material for deposition of nonabsorbent components
Bergerová, Kamila ; Černý, Vít (referee) ; Drochytka, Rostislav (advisor)
The thesis deals with the development of industrial adhesive material for deposition of nonabsorbent components in environments exposed to aggressive chemicals and high temperatures. The theoretical part is mainly focused on summarizing knowledge about adhesive materials. The study also includes description of bonded components, describes theory of adhesion and introduces the used materials. The primary aim of this work is to present new design of material composition of a new adhesive of polymer and silicate base material. The work also investigates the possibility of using the industrial waste in the form of secondary raw material. The final part is dedicated to laboratory testing of new developed materials, summarization and discussion of the obtained results.
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Development of special protective materials for hygienically clean areas
Seják, František ; Vyhnánková, Michaela (referee) ; Drochytka, Rostislav (advisor)
The diploma thesis deals with the development of special protective materials for hygienically clean plants. The main aim of the thesis is to develop a special protective material on a polymer base usable for hygienically clean industrial plants in two quality levels (economy and premium). The first of the developed polymer protective materials is physiologically harmless (economy) – suitable for contact with eatables. Second, premium material is antibacterial, especially suitable as a floor coating in hospitals, kitchens, sanitary facilities, schools and kindergarten etc. A partial aim is the replacement currently used primary raw materials as fillers by suitable secondary raw material.
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Effect of acidic influence on the refractory castable with different cement content.
Mátl, Daniel ; Henek,, Milan (referee) ; Nevřivová, Lenka (advisor)
There are applications of refractory concretes for places where these are exposed to corrosive environments. This diploma thesis deals with both description the corrosive effects and methodology of their testing. One of the most important properties of materials, affecting the chemical corrosion resistance, is their density. The practical part of the thesis is focused on testing the refractory concretes which are currently used for applications. The aggregates were tested for the resistance to sulfuric acid.
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The development of composites based on inorganic binders designed for the extreme applications
Janoušek, Petr ; Šácha, Libor (referee) ; Dufka, Amos (advisor)
The topic of this master's thesis is the development of composite materials based on inorganic binders for use in extreme conditions. It means especially geopolymeric or alkali activated materials (AAM) based composites. The theoretical part of this thesis summarizes knowledges about the development and use of alkali-activated materials, their structure and mechanisms of their formation. It also deals with the applicable raw materials for AAM and their exciters, which are in particular water glass and sodium hydroxide. There also have been a summary of the effects of high temperatures and chemicals on the mechanical properties of AAM and the requirements of standard EN 1504-3 for repairing materials. The task of the practical part was to develop a repair mortar for concrete structures based on AAM so that its production was as simple as possible, ie one-component materials. Gradually six recipes have been develeoped. Test specimens made from these recipes have been putted to selected tests according to the requirements of ČSN EN 1504-3.
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Assessment of resistance castables to chemically aggressive environments.
Mátl, Daniel ; Henek,, Milan (referee) ; Nevřivová, Lenka (advisor)
There are applications of refractory concretes for places where these are exposed to corrosive environments. This bachelor thesis deals with both description the corrosive effects and methodology of their testing. One of the most important properties of materials, affecting the chemical corrosion resistance, is their density. The practical part of the thesis is focused on testing the grogs which are currently used for production of refractory concrete. The aggregates were tested for the resistance to sulfuric acid.
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Mechanical and Chemical Surface Endurance of polymers materials, testing and posibilities fro improvements
Vaníček, Štěpán ; Seidlová, Michaela (referee) ; Petránek, Vít (advisor)
Mechanical and chemical resistant multilayer polymeric floors are the most important characteristics of classification in the evaluation of surface and texture. Mentioned as organic binders which are used for the realization of the matrix. Further discussion on how to get fillers forming the supporting folder. Created a summary of the key test of mechanical and chemical characteristics according to current standards. The theoretical part is concluded with a reflection on the possibilities of improving the surface resistance of synthetic floors. The practical part was focused on testing the strength, resistance to impact and adhesion to the base layer. Finally, the overall evaluation of the test results in accordance with the theoretical part.
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