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Capsule-free Hot Isostatic Pressing of transparent structural and functional ceramic materials
Krupa, Filip ; Drdlík, Daniel (referee) ; Maca, Karel (advisor)
The presented work focused on evaluating the suitability of several types of cubic zirconia powders for preparing suspension with a high solid content (over 40 vol.%). The suspensions were doped with TiO2 nanopowder (0,1 – 0,5 at. %). The influence of the shaping method (casting the suspension and drying the suspension by spray drying, followed by shaping through pressinng) and subsequent pre-sintering to the closed porosity stage was investigated, focusing on comparing two sintering regimes (long – 1300 °C/120 min and short – 1560 °C/2 min). The microstructure of both the pre-sintered samples and the samples after hot isostatic pressing was then observed using an electron microscope. The presented work assessed the influence of TiO2 on relative density, average grain size, and pore size, as well as the optimal amount of TiO2 to achieve maximum photoluminescent properties.
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Preparation and characterization of optically active nanorods
Gaizura, Filip ; Liška, Petr (referee) ; Dvořák, Petr (advisor)
This work focuses on the qualitative study of the preparation and optical characterization of CsPbBr3 perovskite nanorods. The first part contains a brief description of 3D, 2D and 0D perovskite nanostructures, and then focuses on the description of the 1D structure - perovskite nanorods, their possible crystal structures, stability, possible preparation methods, optical properties and use in various optoelectronic devices. The practical part discusses in detail the preparation of CsPbBr3 perovskite nanorods using colloidal synthesis based on ligand-assisted reprecipitation and chemical division at room temperature. Furthermore, the synthesized nanorods are analyzed for morphology and their absorption and photoluminescence spectra are measured with the aim of verifying the dependence of optical properties on the mentioned morphology.
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Reversible interactions of pyrazines and photoluminescent dihydropyrazines
Coufal, Radek
This thesis deals with two independent topics. The first is focused on the study of reversible covalent interactions of a carbonyl group with alcohols and water forming hemiacetals (respectively hydrate) derived from pyrazine trifluormethylketone. The main research method in this part is the NMR spectroscopy and experimental results are also supported by quantum chemical calculations. The second topic aims to the preparation and the study of photochemical properties of three dihydropyrazines which exhibit fluorescence both in solution and solid phase. The fluorescence can be influenced by means of complexation by various metal ions. Prepared dihydropyrazines also show interesting values of the Stokes shift. The structure of these new compounds was confirmed by X-ray analysis.
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Analyse of photovoltaic solar cells by the photoluminescence method
Baura, Tomáš ; Bača, Petr (referee) ; Vaněk, Jiří (advisor)
This thesis deals with the analysis of solar cells by photoluminescence method. Photoluminescence method is based on the excitation of luminescence radiation of the solar cell material by an external excitation light source. This method can detect various types of defects in the material solar cells. The main objective is the design and realization of a measuring system defects of solar cells, which is based on this method. For excitation of luminescence is used LED array. For the detection of luminescence is used CCD camera with IR optical filter. To filter out the excitation light radiation is used disc screen and optical interrupter. The parameters and options of this measuring system are verified and characterized by test measuring for example the achievable rotation speed of screen and response of optical interrupter. At the end is tested detection of luminescence radiation of solar cells in the measuring system. The measured images are compared with the method of electroluminescence.
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The photoluminescence properties measurement of ultrathin films
Metelka, Ondřej ; Mach, Jindřich (referee) ; Šamořil, Tomáš (advisor)
The thesis briefly describes the principles and types of luminescence. In the first following research of study is also discussed the equipment which is applicable to photoluminescence experiments, including the arrangement. The second research focuses on the influence of the properties of gallium nitride (GaN) (ultra) thin films and other structures prepared by various ways on shape of photoluminescence spectra. The paperwork also describes the further optimization of photoluminescent apparatus used for the measurement of photoluminescence spectrum in the UV light radiation which is located at the Institute of Physical Engineering at the Technical University. The extension of measurements at low temperatures (design and construction of its own cryostat) is added. The conclusion concernes the test measurements to determine the effect of various settings of the apparatus on the resulting measured photoluminescence spectrum.
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Inovation of measurement equipment used for analyzing of photovoltaick cells
Otépka, Jakub ; Bača, Petr (referee) ; Vaněk, Jiří (advisor)
This bachelor thesis deals with the design of a tachometer which is used to measure and display of mechanical aperture speed of a measuring equipment for the defect analysis of solar cells using the photoluminescence method. This work is divided into three parts. The first section describes the principle of solar cells, the principle of luminescence radiation and its types. Next the defects of solar cells are analyzed. The second part discusses the theory of tachometers, the principles and methods of loading pulses. The third part is then analyzed the design and construction of the selected type tachometer.
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Plasmon enhanced photoluminescence
Édes, Zoltán ; Kůsová,, Kateřina (referee) ; Šikola, Tomáš (advisor)
Diplomová práce se zabývá fotoluminiscencí polovodičových materiálů zesílené plazmonovými polaritony. Je popsána základní teorie interakce mezi lokalizovanými povrchovými plazmonovými polaritony a fotoluminiscenčními látkami. Dva mechanismy, které mohou vést k fotoluminiscenci zesílené plazmonovými polaritony jsou diskutovány. Následně je popsán návrh aparatury pro měření fotoluminiscence a způsob její realizace. Funkčnost aparatury je ověřena měřením fotoluminiscenčních spekter objemového GaN, nanokrystalického Si a CdTe kvantových teček. Nakonec je zkoumána metoda přípravy vzorků sestávajících z kovových nanokuliček a fotoluminiscenčně aktívních CdTe kvantových teček.
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Photoluminiscence study of thin layers of MoS2
Kuba, Jakub ; Kunc,, Jan (referee) ; Bartoš, Miroslav (advisor)
The thesis deals with study of thin layers of transition metal dichalcogenides, especially of molybdenum disulfide. Nanostructures were fabricated on two-dimensional crystals of MoS2 and WSe2. Within followed analysis attention was paid to the photoluminescence properties. In the thesis transition metal dichalcogenides are reviewed and description of the modified process of preparation by micromechanical exfoliation is given.
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Analyse of photovoltaic solar cells by the photoluminescence method
Richter, Vladimír ; Bača, Petr (referee) ; Vaněk, Jiří (advisor)
This diploma thesis deals with the issues of photovoltaic cells. The main aim of this thesis is to introduce the principles of operation of solar cells and methods of detection of defects affecting their quality. The first part is about the functional properties of silicon cells and it also examines the possibilities of detecting the defects of these structures. It also describes the most commonly used modern diagnostic methods. In the next part, practical tests of photovoltaic cells using the methods electroluminescence and photoluminescence are performed. These methods are based on the excitation of luminescence radiation of the silicon material by the external light source.
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Diagnostic method of solar cells operating at very low temperatures
Bartoň, Jiří ; Stojan, Radek (referee) ; Veselý, Aleš (advisor)
This work deals with the modern diagnostic methods of defects detection of solar cells. Defects are detected by electroluminescence and photoluminescence methods. The main focus of this work is an innovation workplace for measuring solar cell defects at very low temperatures using photoluminescence. Liquid nitrogen is used to cooling solar cells. By using low temperatures can be detection methods to obtain more objektive results of diagnostic defects.
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