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Historical records of Hg emissions in the Prague city using dendrochronology
Miller, Zbyněk ; Dočkalová, Kateřina (advisor) ; Mihaljevič, Martin (referee)
The primary aim of this work was to estimate whether tree rings of Norway spruce (Picea abies L.) can be used as a geochemical archive for the purposes of historical and recent pollution of atmosphere by Mercury (Hg). The research was realized during the year of 2013 (January to June) in the the capital city of Prague. Šumava National Park was selected as a reference site. In total, forty eight cores of Norway spruce were sourced from five locations for the Hg analysis. Three cores were obtained from each tree from the following cardinal points: the north, east and south-west. The investigated sites have been significantly different in amount of Hg measured (ANOVA, p < 0,001). There was found also negative correlation among the amount of Hg and phosphorus (P) (r = - 0,66; p < 0,002). The highest concentrations of Hg were measured at "Krematorium Motol" site (up to 14,2 ng.g-1 ). On the contrary, the lowest concentration of Hg was recorded both near the former incineration plant at the site "Pod Spalovnou - Vysočany" (1,1 ng.g-1 ) and at the reference site in the Šumava (1,2 ng.g-1 ). Increased values of Hg in the investigated tree rings in the 50's up to the late 70's of the 20th century is probably caused by the former industrial era connected with coal-fired power plants and ore processing. The...
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Historical records of Hg emissions in the Prague city using dendrochronology
Miller, Zbyněk ; Dočkalová, Kateřina (advisor) ; Mihaljevič, Martin (referee)
The primary aim of this work was to estimate whether tree rings of Norway spruce (Picea abies L.) can be used as a geochemical archive for the purposes of historical and recent pollution of atmosphere by Mercury (Hg). The research was realized during the year of 2013 (January to June) in the the capital city of Prague. Šumava National Park was selected as a reference site. In total, forty eight cores of Norway spruce were sourced from five locations for the Hg analysis. Three cores were obtained from each tree from the following cardinal points: the north, east and south-west. The investigated sites have been significantly different in amount of Hg measured (ANOVA, p < 0,001). There was found also negative correlation among the amount of Hg and phosphorus (P) (r = - 0,66; p < 0,002). The highest concentrations of Hg were measured at "Krematorium Motol" site (up to 14,2 ng.g-1 ). On the contrary, the lowest concentration of Hg was recorded both near the former incineration plant at the site "Pod Spalovnou - Vysočany" (1,1 ng.g-1 ) and at the reference site in the Šumava (1,2 ng.g-1 ). Increased values of Hg in the investigated tree rings in the 50's up to the late 70's of the 20th century is probably caused by the former industrial era connected with coal-fired power plants and ore processing. The...
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Occurrence of mercury in the soil around upper stream Ohře
MILLER, Zbyněk
The aim of this study was to summarize information about the behavior of mercury in soils, particularly the assessment of its mobility and bioavailability, and to verify the extent of contamination of alluvial soils under the reservoir Skalka. This research was aimed to evaluate the contamination of mercury floodplain soils with mercury belong the upper river Ohře near the town of Chvoječná, near 230th river kilometer. River sediments of the upper river Ohře and the surrounding alluvial soils in floodplains contain high mercury levels. The site has been sampled for mercury analysis of soil samples taken from farmed areas, which are expected enrichment of mercury deposits of the inserted river Ohře. There were two main types of land-use, permanent grassland and arable land. The observed results can be concluded that the river floodplain sediments enrich the soil with mercury. Analytical method (atomic absorption spectrometry, CV-AAS) showed that almost all surface soil samples from the flooded area exceeds the maximum allowed value (for light soils 0.6 mg.kg-1 and other land 0.8 mg.kg-1 ) that are designated for agricultural land. Indicative of mercury was determined by mobility, which was up to 2.18%. Levels of organic forms of mercury were also measured in the soils that reached the area of grassland 2 maximum 0.147 mg.kg-1; the subsidiary surface S1 had the relative distribution of organic mercury 10.98% at a depth of 101-140 cm.
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The Mobility and bioavailability of thallium from natural and antropogenic origin.
MILLER, Zbyněk
The aims of this study were to precisely describe information about Tl behaviour in soils especially mobility and bioavailability and at given locality to provide analyses of fungi samples to prove found information. This research continues in early findings concerning Tl geochemical position at the locality of Kluky, Czech Republic where an anomaly in Tl concentration in soil is. From the results in can be concluded that Tl is at given locality distributed unevenly and the Tl concentration in almost all the fungi samples was below the detection limit of analytical method used (inductively coupled plasma mass spectrometry, ICP-MS) with the only exception of Macrolepiota procera, Russula claroflava Grove, Hygrophoropsis aurantiaca, Lycoperdon perlatum. In these fungi samples the found bioconcentration factor, BCF (ratio of Tl concentration in fungi and soil) was relatively higher compared to other plant samples at the locality. Therefore the consumption of the fungi from studied locality can not be recommended.
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