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critical Evaluation of metrhods for determination of Sulphates in waters
Havelková, Ludmila ; Řezáčová, Veronika (referee) ; Sommer, Lumír (advisor)
The aim of this work was the evaluation and method optimalization for determination of sulfates in aqueous solutions with application on different kinds of waters. For determination of sulfates were used two different procedures, turbidimetric and volumetric. In turbidimetric procedure was use optimized conditions applicable determination of sulfates in range from 0 – 20 mg.l-1. For stabilization of the colloid was use glycerine, himself sulfates sedimentation is discharged in BaSO4 form. By volumetric methods are used titration on the dithizone like indicator while using Pb(NO3)2 like volumetric reagent. Other indicator bromsulfonazo III, whitch are used for determination of sulfates by the help of volumetric solutions Ba(ClO4)2 and BaCl2. All volumetric determinations proceeded in acidic medium. During research of interferences ions on the individual titraction was detected substantial effect Ca2+, Mg2+ and Fe3+, which was needing divide off on the exchanger resin. Ions aforementioned don't interfere turbidimetric determination of sulfates.
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critical Evaluation of metrhods for determination of Sulphates in waters
Havelková, Ludmila ; Řezáčová, Veronika (referee) ; Sommer, Lumír (advisor)
The aim of this work was the evaluation and method optimalization for determination of sulfates in aqueous solutions with application on different kinds of waters. For determination of sulfates were used two different procedures, turbidimetric and volumetric. In turbidimetric procedure was use optimized conditions applicable determination of sulfates in range from 0 – 20 mg.l-1. For stabilization of the colloid was use glycerine, himself sulfates sedimentation is discharged in BaSO4 form. By volumetric methods are used titration on the dithizone like indicator while using Pb(NO3)2 like volumetric reagent. Other indicator bromsulfonazo III, whitch are used for determination of sulfates by the help of volumetric solutions Ba(ClO4)2 and BaCl2. All volumetric determinations proceeded in acidic medium. During research of interferences ions on the individual titraction was detected substantial effect Ca2+, Mg2+ and Fe3+, which was needing divide off on the exchanger resin. Ions aforementioned don't interfere turbidimetric determination of sulfates.
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