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Dating of radioactive mineral springs of the Krkonoše-Jizera crystalline by 230Th/234U method
Fanta, Martin ; Goliáš, Viktor (advisor) ; Mizera, Jiří (referee)
The isotopes 238 U, 234 U and 230 Th, as members of the uranium-radium decay chain, are fractionated in the environment by changes of geochemical conditions, and they can be used for dating of recent or past geochemical processes in the Quaternary. Samples of water with uranium and of water-activated solids were taken of radioactive mineral water springs at two study sites in the area of Krkonoše-Jizera crystalline complex: Svatý Vojtěch (St. Adalbert) in Horní Malá Úpa, and Bukový Pramen in the Těsný důl valley in Janské Lázně. Uranium was co-precipitated in field conditions with hydroxides of FeIII+ in 50-liter water samples of the radioactive springs. In the lab, uranium and thorium were separated from water precipitates, as well as from solid samples after their chemical decomposition, using chromatographic extraction agent UTEVA. All the three isotopes of interest emit alpha particles, and so their activities were measured by alpha spectrometry and expressed as 234 U/238 U and 230 Th/234 U ratios. As an internal standard, 232 U/228 Th was used. The resulting 234 U/238 U activity ratios of four water samples measured ranged from 1.0747 to 1.423. In twelve samples of solid phases activity ratios 234 U/238 U from 0.861 to 1.129 were determined. The 230 Th/234 U activity ratios form two distinct...
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Radioactivity of granitoids of the Krkonoše-Jizera pluton
Černík, Tomáš ; Goliáš, Viktor (advisor) ; Matolín, Milan (referee)
2. SUMMARY This thesis is focused on the natural radioactivity of the Krkonoše pluton, which is divided in 6 particular types of granite: the Jizera, the Liberec, the Fojtka, the Tanvald, the Harrachov, the Krkonoše ones. The goal of the thesis was to compare these values and find out whether there was an unlike element (U, Th, K) content difference. Based on literature data about the Czech and Polish part of pluton, there was assigned data of the analysed samples (of contents of K, U, Th) to each type of granite. The literature data was refined on the base of the current knowledge. The localized collection points were assigned to the particular types of the Krkonoše - Jizera granitoids. The analytic data collection was statistically evaluated. On the base of the statistic data evaluation significant differences of the radioactive element content of the particular types of granite was proved. The most radioactive one is the Harrachov granite. The Tanvald one has a distinctively anomalous ratio of U to Th higher than 1. The other types of granite have only an average level of radioactivity. There was also checked a significant aerial gamaspectrometric anomaly in the south - west direction of Hejnice. There was made a field gamaspectrometric measurement, which did not prove the significant increase in an...
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The content and binding of silver in galena
Němec, Matěj ; Goliáš, Viktor (advisor) ; Zachariáš, Jiří (referee)
Galena as the most important silverbearing ore is found in almost every Ag deposit. If the content of Ag is higher than 0,5 wt. % then is called galena solid solution - PbSss. The galena Ag has two forms of occurrence - inclusions and isomorphic silver. Aboat ninety percent of galena Ag is product of retrograde proces of PbSss cooling. These are matildite (AgBiS2), miargyrite (AgSbS2), diaforite (PbAg3Sb3S8), freislebenite (AgPbSbS3), pyrargyrite (Ag3SbS3) aramayoite (Ag(Sb,Bi)S2), freibergite (Ag12Sb4S13), gustavite (AgPbBi3S6) etc. The smaller amounth of isomorphic Ag is substituted as 2Ag+ = PbII+ . Under the usual conditions of deposition (200 - 300řC) , the solubility of Ag2S is to low. The content of Ag in galena under these conditions is not higher then 0,4 mol. % at 615řC. Most of the isomorphic Ag is bound in coupled substitution Ag+ + Bi III+ /Sb III+ = 2 PbII+ . In this case the content of Ag in PbS can be as high as 9 wt. % at 350 - 400řC. At the deposites where wasn't activated this Bi/Sb - Pb coupled substitution the content of Ag in galena is very low. The content of trace elements of Ag, Bi and Sb can also influence the galena crystal habit. Galena rich on Bi ususaly creates octahedral crystals. Galena with a higher content of Ag and Sb usualy creates cubic crystals.
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Radon-in-waters measurement methods
Hrušková, Lenka ; Goliáš, Viktor (advisor) ; Třískala, Zdeněk (referee)
Higher concentrations of radon are probably harmful to our health, on the other side its lower concentrations have terapeutical effect, which is used in a spa. Its characteristical properties are suitable for mineralogical research, hydrological and environmental studies and for an earthquake and vulcanic prognosis. In this work, there are explained methods of ray measuring, scintilation detektor and ionization chamber and there are compared devices like radon-in-air monitor, device with a hydrphobical membrane and device with a method using olive-oil. dtto cz.
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The vitrification methods used for the high active waste from spent nuclear fuel reprocessing.
Machová, Pavlína ; Goliáš, Viktor (advisor) ; Jelínek, Emil (referee)
This thesis summarizes the general concepts regarding the High-level waste vitrification. It describes the one-stage and two-stage principles of vitrification and special method "cold crucible". There are summarized advantages and disadvantages of these methods. In this thesis are specific of vitrification facilities around the world. There are the general characteristics of glass used for immobilization High- level waste. Most countries use borosilicate glass, but only in Russia are used phosphate glass. There is shown the composition range of glass and compare their typical properties. This thesis ends with an example of the chemical composition of certain ending vitrification products.
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Radioactive medicinal springs in the Skalná - Bad Brambach area
Turnová, Štěpánka ; Goliáš, Viktor (advisor) ; Vylita, Tomáš (referee)
Radiohydrochemical exploration took place in east part of the "smrčinský" pluton between "Skalná-Plesná-Bad Brambach in years 2016-2018. The main aim of the exploration was location and thorough research of possible occurrence of waters with radioactive concretation higher than 1500 Bq/l. That is a value for radioactive mineral waters given by the "lázeňským" law number 164/2001 Sb. Most important area is Plesná-south where was discovered several springs with values exceeding 5000 Bq/l. Eminent spring is called "Břetislav-Radonka" and lies one kilometre southwest from the train station Plesná-Šneky with an activity of about 12.5 kBq / l 222 Rn and a flow rate of about 2.5 l / min. It is the most active surface discharge of radon mineral water in the Czech Republic Another significant source area is north of Skalna - north. These springs were discovered almost 60 years ago, Dr. Marie Zukriegelová. The main source of this area was named after its discoverer - the "Marie Z" spring with an activity of 5800 Bq / l 222 Rn.Further the research focused on historical radioactive conduit which were used to supply village Skalné with water. The conduit was separated on two "branches" and the younger one was built ten years after the first one. In both pipes were found radioactive waters and the most important...
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